pH/ION 3310: Operating Manual
pH/ION 3310: Operating Manual
pH/ION 3310: Operating Manual
pH ba77052d01 03/2014
6.09
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25.0 3 °C
15.0
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08:3.2014
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pH/ION 3310
METER FOR pH/ORP/ISE
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pH/ION 3310 Contents
1 Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
1.1 pH/ION 3310 meter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
1.2 Sensors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
2 Safety instructions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
2.1 Safety information . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
2.1.1 Safety information in the operating manual . . . . . 7
2.1.2 Safety signs on the meter . . . . . . . . . . . . . . . . . . 7
2.1.3 Further documents providing safety information . 7
2.2 Safe operation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
2.2.1 Authorized use . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
2.2.2 Requirements for safe operation . . . . . . . . . . . . . 8
2.2.3 Unauthorized use . . . . . . . . . . . . . . . . . . . . . . . . . 8
3 Commissioning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
3.1 Scope of delivery. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
3.2 Power supply. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
3.3 Initial commissioning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
3.3.1 Inserting the batteries. . . . . . . . . . . . . . . . . . . . . 10
4 Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
4.1 General operating principles . . . . . . . . . . . . . . . . . . . . . . 11
4.1.1 Keypad . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
4.1.2 Display . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
4.1.3 Status information (meter) . . . . . . . . . . . . . . . . . 12
4.1.4 Socket field. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
4.2 Switching on the meter . . . . . . . . . . . . . . . . . . . . . . . . . . 13
4.3 Switching off . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
4.4 Navigation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
4.4.1 Operating modes . . . . . . . . . . . . . . . . . . . . . . . . 14
4.4.2 Measured value display . . . . . . . . . . . . . . . . . . . 15
4.4.3 Menus and dialogs . . . . . . . . . . . . . . . . . . . . . . . 15
4.4.4 Elements in menus and dialogs . . . . . . . . . . . . . 15
4.4.5 Example 1 on navigation: Setting the language. 16
4.4.6 Example 2 on navigation: Setting the date and time
18
5 pH value . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
5.1 Measuring . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
5.1.1 Measuring the pH value . . . . . . . . . . . . . . . . . . . 20
5.1.2 Measuring the temperature . . . . . . . . . . . . . . . . 22
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Contents pH/ION 3310
5.2 Calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
5.2.1 Why calibrate? . . . . . . . . . . . . . . . . . . . . . . . . . . 23
5.2.2 When do you have to calibrate? . . . . . . . . . . . . . 23
5.2.3 Automatic calibration (AutoCal) . . . . . . . . . . . . . 23
5.2.4 Manual calibration (ConCal) . . . . . . . . . . . . . . . . 26
5.2.5 Calibration points . . . . . . . . . . . . . . . . . . . . . . . . 29
5.2.6 Calibration data. . . . . . . . . . . . . . . . . . . . . . . . . . 30
5.2.7 Continuous measurement control (CMC
function) ............................. 32
6 ORP voltage. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
6.1 Measuring . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
6.1.1 Measuring the ORP . . . . . . . . . . . . . . . . . . . . . . 34
6.1.2 Measuring the temperature. . . . . . . . . . . . . . . . . 36
6.2 ORP calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
7 Ion concentration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37
7.1 Measuring . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37
7.1.1 Measuring the ion concentration . . . . . . . . . . . . 37
7.1.2 Measuring the temperature. . . . . . . . . . . . . . . . . 39
7.2 Calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40
7.2.1 Why calibrate? . . . . . . . . . . . . . . . . . . . . . . . . . . 40
7.2.2 When to calibrate? . . . . . . . . . . . . . . . . . . . . . . . 40
7.2.3 Calibration (ISE Cal) . . . . . . . . . . . . . . . . . . . . . . 40
7.2.4 Calibration standards . . . . . . . . . . . . . . . . . . . . . 43
7.2.5 Calibration data. . . . . . . . . . . . . . . . . . . . . . . . . . 43
8 Settings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45
8.1 Measurement settings . . . . . . . . . . . . . . . . . . . . . . . . . . . 45
8.1.1 Settings for pH measurements . . . . . . . . . . . . . . 45
8.1.2 Buffer sets for calibration . . . . . . . . . . . . . . . . . . 46
8.1.3 Calibration interval . . . . . . . . . . . . . . . . . . . . . . . 48
8.1.4 Settings for ORP measurements . . . . . . . . . . . . 49
8.1.5 Settings for ISE measurements . . . . . . . . . . . . . 50
8.2 Sensor-independent settings . . . . . . . . . . . . . . . . . . . . . . 52
8.2.1 System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52
8.2.2 Data storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53
8.3 Reset . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53
8.3.1 Resetting the measurement settings . . . . . . . . . 53
8.3.2 Resetting the system settings . . . . . . . . . . . . . . . 54
9 Data storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55
9.1 Manual storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55
9.2 Automatic data storage at intervals .............. 56
9.3 Measurement data storage . . . . . . . . . . . . . . . . . . . . . . . 58
9.3.1 Editing the measured value storage . . . . . . . . . . 58
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pH/ION 3310 Contents
12 What to do if... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65
12.1 pH/ORP. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65
12.2 ISE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67
12.3 General information. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 68
13 Technical data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
13.1 Measuring ranges, resolution, accuracy . . . . . . . . . . . . . 69
13.1.1 pH/ORP . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
13.1.2 ISE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70
13.2 General data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71
14 Firmware update . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72
15 Glossary. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73
16 Index. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75
ba77052d01 03/2014 5
Overview pH/ION 3310
1 Overview
1.1 pH/ION 3310 meter
The pH/ION 3310 meter enables you to perform measurements (pH, U, ISE)
quickly and reliably.
The pH/ION 3310 provides the maximum degree of operating comfort, reliabil-
ity and measuring certainty for all applications.
1 Keypad
2 Display
3 Socket field
1.2 Sensors
A measuring system ready to measure consists of the pH/ION 3310 meter and
a suitable sensor.
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pH/ION 3310 Safety instructions
2 Safety instructions
2.1 Safety information
WARNING
indicates a possibly dangerous situation that can lead to seri-
ous (irreversible) injury or death if the safety instruction is not
followed.
CAUTION
indicates a possibly dangerous situation that can lead to
slight (reversible) injury if the safety instruction is not fol-
lowed.
NOTE
indicates a possibly dangerous situation where goods might be damaged
if the actions mentioned are not taken.
Note all labels, information signs and safety symbols on the meter and in the
battery compartment. A warning symbol (triangle) without text refers to safety
information in this operating manual.
ba77052d01 03/2014 7
Safety instructions pH/ION 3310
Only the operation and running of the meter according to the instructions and
technical specifications given in this operating manual is authorized (see
section 13 TECHNICAL DATA, page 69).
Any other use is considered unauthorized.
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pH/ION 3310 Commissioning
3 Commissioning
3.1 Scope of delivery
MeterpH/ION 3310
4 batteries 1.5 V Mignon type AA
Short instructions
CD-ROM with
– USB drivers
– detailed operating manual
– Software MultiLab Importer
ba77052d01 03/2014 9
Commissioning pH/ION 3310
You can operate the meter either with normal batteries or with
rechargeable batteries (Ni-MH). In order to charge the batteries, an
external charging device is required.
1 Screws
2 Battery compartment
CAUTION
Make sure that the poles of the batteries are positioned cor-
rectly.
The ± signs on the batteries must correspond to the ± signs in
the battery compartment.
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pH/ION 3310 Operation
4 Operation
4.1 General operating principles
4.1.1 Keypad
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Operation pH/ION 3310
4.1.2 Display
3 4
pH
2
6.093 25.0 °C 5
1 HOLD AR 6
7
Menu
15.02.2014
08:00
USB output 8
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pH/ION 3310 Operation
5 1 2 3 4
1 pH electrode
2 Reference electrode
3 Temperature sensor
4 Mini USB-B interface
5 Service interface
CAUTION
Only connect sensors to the meter that cannot return any volt-
ages or currents that are not allowed (> SELV and > current
circuit with current limiting).
Almost all customary sensors fulfill these conditions.
pH
6.949
25.0 °C
15.02.2014
Menu 14:15 USB output
ba77052d01 03/2014 13
Operation pH/ION 3310
Automatic switch-off The instrument has an automatic switch-off function in order to save the
batteries (see section 8.2.1 SYSTEM, page 52). The automatic switchoff function
switches off the meter if no key is pressed for an adjustable period.
The automatic switchoff function is not active
if the communication cable is connected
if the Automatic data storage function is active, or with automatic data trans-
mission
Display illumination The meter automatically switches off the display illumination if no key is
pressed for 30 seconds. The illumination is switched on with the next keystroke
again.
You can also generally switch the display illumination on or off (see section
8.2.1 SYSTEM, page 52).
4.4 Navigation
The principles of navigation in menus and dialogs are explained in the following
sections.
Operating Description
mode
Measuring The measurement data of the connected sensor are shown
in the measured value display
Calibration The course of a calibration with calibration information, func-
tions and settings is displayed
Storage in The meter stores measuring data automatically or manually
memory
Transmit- The meter transmits measuring data and calibration records
ting data to a USB-B interface automatically or manually.
Setting The system menu or a sensor menu with submenus, set-
tings and functions is displayed
Only those displays and functions are available in the active operating mode
that are currently being required.
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pH/ION 3310 Operation
In the measured value display, open the setting menus with <ENTER>. The
current functions of the softkeys are shown on the display.
Use <ENTER> (short pressure) to open the menu for calibration and mea-
surement settings for the displayed measured parameter.
Use <ENTER__> (long keystroke (approx. 2 s) to open the Storage & config
menu with the sensor-independent settings.
Use the keys of the keypad to carry out further functions such as storage or cali-
bration (see section 4.1.1 KEYPAD, page 11). These functions are not available
in other operating situations.
The menus for settings and dialogs in procedures contain further subelements.
To select a subelement, use the <><> keys. The current selection is dis-
played with a frame.
To make further settings, switch to the next higher menu level with
<F1>[Back].
Use <M> to return to the measured value display.
Submenus
The name of the submenu is displayed at the upper edge of the frame. Sub-
menus are opened by confirming with <ENTER>. Example:
System
General
Interface
Clock
Service information
Reset
15.02.2014
Back
14:15
Settings
Settings are indicated by a colon. The current setting is displayed on the
right-hand side. The setting mode is opened with <ENTER>. Subsequently,
the setting can be changed with <><> and <ENTER>. Example:
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Operation pH/ION 3310
General
Language: Deutsch
Beep: Off
Illumination: On
Contrast: 50 %
Switchoff time: 1h
Temperature unit: °C
Stability control: On
15.02.2014
Back
14:15
Functions
Functions are designated by the name of the function. They are immediately
carried out by confirming with <ENTER>.
Example: Display the Calibration record function.
pH
Calibration record
Calibration data storage
Buffer: TEC
One point calibration: Yes
Calibration interval: 7d
Unit for slope: mV/pH
Messages
Information is marked by the i symbol. It cannot be selected. Example:
pH
Calibration record
Calibration data storage
Buffer: TEC
One point calibration: Yes
Calibration interval: 7d
Unit for slope: mV/pH
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pH/ION 3310 Operation
pH
6.949
25.0 °C
15.02.2014
Menu 14:15 USB output
15.02.2014
Back
14:15
System
General
Interface
Clock
Service information
Reset
Back 15.02.2014
14:15
ba77052d01 03/2014 17
Operation pH/ION 3310
General
Language: Deutsch
Beep: Off
Illumination: On
Contrast: 50 %
Switchoff time: 1h
Temperature unit: °C
Stability control: On
15.02.2014
Back
14:15
General
Language: Deutsch
Beep: Off
Illumination: On
Contrast: 50 %
Switchoff time: 1h
Temperature unit: °C
Stability control: On
15.02.2014
Back
14:15
The meter has a clock with a date function. The date and time are shown in the
measured value display.
When storing measured values and calibrating, the current date and time are
automatically stored as well.
The correct setting of the date and time and date format is important for the fol-
lowing functions and displays:
Current date and time
Calibration date
Identification of stored measured values.
After a fall of the supply voltage (empty batteries), the date and time
are reset to 01.01.2011 00, 00:00 hours.
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pH/ION 3310 Operation
The date format can be switched from the display of day, month, year
(dd.mm.yyyy) to the display of month, day, year (mm/dd/yyyy or mm.dd.yyyy).
Clock
Date format: dd.mm.yyyy
Date: 15.02.2014
Time: 14:15:25
15.02.2014
Back
14:15
ba77052d01 03/2014 19
pH value pH/ION 3310
5 pH value
5.1 Measuring
NOTE
When connecting an earthed PC/printer, measurements cannot be
performed in earthed media as the values would be incorrect.
The USB interface is not galvanically isolated.
pH
6.949
24.8 °C
15.02.2014
Menu 14:15 USB output
Stability control The stability control function (AutoRead) continually checks the stability of the
(AutoRead) measurement signal. The stability has a considerable impact on the reproduc-
& HOLD function ibility of measured values.
The measured parameter flashes on the display
as soon as the measured value is outside the stability range
when the automatic Stability control is switched off.
You can activate or switch off the automatic Stability control function (see
section 8.2.1 SYSTEM, page 52).
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pH/ION 3310 pH value
You can terminate the Stability control function and the HOLD func-
tion with <AR> or <M> at any time.
Criteria for a stable The Stability control function checks whether the measured values are stable
measured value within the monitored time interval.
ba77052d01 03/2014 21
pH value pH/ION 3310
Resolution of
Tempera- the temp. dis-
ture sensor play Temp. measurement
- 1 °C Manual
22 ba77052d01 03/2014
pH/ION 3310 pH value
5.2 Calibration
pH electrodes age. This changes the zero point (asymmetry) and slope of the
pH electrode. As a result, an inexact measured value is displayed. Calibration
determines and stores the current values of the zero point and slope of the
electrode.
Thus, you should calibrate at regular intervals.
Make sure that in the sensor menu, Buffer menu, the buffer set is correctly
selected (see 8.1.1 SETTINGS FOR PH MEASUREMENTS, PAGE 45).
Use any one to five buffer solutions of the selected buffer set in ascending or
descending order.
Below, calibration with Technical buffers (TEC) is described. When other buffer
sets are used, other nominal buffer values are displayed. Apart from that, the
procedure is identical.
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pH value pH/ION 3310
pH Buffer 1
-180.0 mV
24.8 °C
AutoCal TEC
15.02.2014
14:15
pH Buffer 10.011
-180.0 mV
24.8 °C
AutoCal TEC
AR
15.02.2014
14:15
9. Wait for the end of the measurement with stability control or accept the
calibration value with <ENTER>.
The calibration display for the next buffer appears (voltage display).
10. If necessary, finish the calibration procedure as a single-point calibration
with <M>.
The calibration record is displayed.
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pH/ION 3310 pH value
pH Buffer 7.000
0.0 mV
24.8 °C
AutoCal TEC
AR
15.02.2014
14:15
15. Wait for the measurement with stability control to be completed or termi-
nate the stability control and take over the calibration value with
<ENTER>.
The calibration display for the next buffer appears (voltage display).
16. If necessary, finish the calibration procedure as a two-point calibration
with <M>.
The calibration record is displayed.
ba77052d01 03/2014 25
pH value pH/ION 3310
pH Buffer 4.010
180.0 mV
24.8 °C
AutoCal TEC
AR
15.02.2014
14:15
21. Wait for the measurement with stability control to be completed or termi-
nate the stability control and take over the calibration value with
<ENTER>.
The calibration display for the next buffer appears (voltage display).
22. If necessary, use <M> to finish calibration or
Continue calibrating using the next buffer with <ENTER>.
Make sure that in the sensor menu, Buffer menu, the ConCal buffer set is
selected (see section 8.1.1 SETTINGS FOR PH MEASUREMENTS, page 45).
Use any one to five buffer solutions in ascending or descending order.
26 ba77052d01 03/2014
pH/ION 3310 pH value
pH Buffer 1
0.0 mV
24.8 °C
ConCal
15.02.2014
14:15
pH Buffer 7.000
0.0 mV
24.8 °C
ConCal
AR
15.02.2014
14:15
9. Wait for the end of the measurement with stability control or accept the
calibration value with <ENTER>.
The calibration display for the setting of the nominal buffer value appears.
pH Buffer 1
7.000
24.8 °C
ConCal
15.02.2014
14:15
10. Set the nominal buffer value for the measured temperature with
<><>.
ba77052d01 03/2014 27
pH value pH/ION 3310
pH Buffer 2
4.035
24.8 °C
ConCal
15.02.2014
14:15
18. Set the nominal buffer value for the measured temperature with
<><>.
19. Accept the set calibration value with <ENTER>.
The calibration display for the next buffer appears (voltage display).
20. Finish the calibration procedure as a two-point calibration with <M>.
The calibration record is displayed.
28 ba77052d01 03/2014
pH/ION 3310 pH value
Continuing with
21. Thoroughly rinse the electrode with deionized water.
three- to five-point
calibration 22. Immerse the electrode in the next buffer solution.
23. When measuring without temperature sensor:
– Temper the buffer solution, or measure the current temperature.
– Enter the temperature value with <> <>.
24. Start the measurement with <ENTER>.
The measured value is checked for stability (stability control). The [AR]
status indicator is displayed. A progress bar is displayed and the display
of the measured parameter flashes.
25. Wait for the measurement with stability control to be completed or termi-
nate the stability control and take over the calibration value with
<ENTER>.
The calibration display for the setting of the nominal buffer value appears.
pH Buffer 3
9.958
24.8 °C
ConCal
15.02.2014
14:15
26. Set the nominal buffer value for the measured temperature with
<><>.
27. Accept the set calibration value with <ENTER>.
The calibration display for the next buffer appears (voltage display).
28. Use <M> to finish calibration or
Continue calibrating using the next buffer with <ENTER>.
After the fifth buffer has been measured the calibration is automat-
ically finished. Then the calibration record is displayed.
The calibration line is determined by linear regression.
Calibration can be performed using one to five buffer solutions in any order
(single-point to five-point calibration). The meter determines the following
values and calculates the calibration line as follows:
ba77052d01 03/2014 29
pH value pH/ION 3310
You can display the slope in the units, mV/pH or % (see section
8.1.1 SETTINGS FOR PH MEASUREMENTS, page 45).
Displaying the cali- The calibration record of the last calibration is to be found under the menu item,
bration data <ENTER> / Calibration / Calibration record. To open it, press the <CAL__> key
in the measured value display.
Subsequently, you can transmit the displayed calibration data to the interface,
e.g. to a PC, with the <F2>[USB output] key.
Displaying the cali- The calibration records of the last calibrations (up to 10) are given in the menu,
bration data storage <ENTER>/Calibration / Calibration data storage.
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pH/ION 3310 pH value
Calibration evalua- After calibrating, the meter automatically evaluates the calibration. The zero
tion point and slope are evaluated separately. The worse evaluation of both is taken
into account. The evaluation appears on the display and in the calibration
record.
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pH value pH/ION 3310
Calibration record
pH/ION 3310
(example) Ser. no. 11292113
CALIBRATIONpH
15.02.2014 15:55
AutoCal TEC
Buffer 1 4.01
Buffer 2 7.00
Buffer 3 10.01
Voltage 1 184.0 mV
Voltage 2 3.0 mV
Voltage 3 -177.0 mV
Temperature 1 24.0 °C
Temperature 2 24.0 °C
Temperature 3 24.0 °C
Slope -60.2 mV/pH
Asymmetry 4.0 mV
Sensor +++
etc...
32 ba77052d01 03/2014
pH/ION 3310 pH value
1
2
pH 0 14
6.093
3
4
25.0 °C
15.02.2014
Menu USB output
14:15
The limits of the calibrated range are determined by the buffers used for cali-
bration:
ba77052d01 03/2014 33
ORP voltage pH/ION 3310
6 ORP voltage
6.1 Measuring
NOTE
When connecting an earthed PC/printer, measurements cannot be
performed in earthed media as the values would be incorrect.
The USB interface is not galvanically isolated.
U
157.0 mV
24.8 °C
15.02.2014
Menu 14:15 USB output
Stability control The stability control function (AutoRead) continually checks the stability of the
(AutoRead ) measurement signal. The stability has a considerable impact on the reproduc-
ibility of measured values.
You can activate or switch off the automatic Stability control function (see
section 8.2.1 SYSTEM, page 52).
The measured parameter flashes on the display
as soon as the measured value is outside the stability range
when you switch over between the measured parameters with <M>.
when the automatic Stability control is switched off.
Criteria for a stable The Stability control function checks whether the measured values are stable
measured value within the monitored time interval.
34 ba77052d01 03/2014
pH/ION 3310 ORP voltage
Manually starting Irrespective of the setting for automatic Stability control (see section 8.2.1 SYS-
the stability control TEM, page 52) in the System menu, you can start the Stability control function
manually at any time.
Freezing the mea- With the HOLD function, you can freeze the current measured value. The dis-
sured value (HOLD played measured value stops changing until you switch the HOLD function off.
function)
If the HOLD function is active, you can, e.g. start a manual mea-
surement with stability control.
ba77052d01 03/2014 35
ORP voltage pH/ION 3310
Resolution of
Temperature the temp. dis-
sensor play Temp. measurement
- 1 °C Manual
ORP electrodes are not calibrated. You can, however, check ORP
electrodes by measuring the ORP of a test solution and comparing
the value with the nominal value.
36 ba77052d01 03/2014
pH/ION 3310 Ion concentration
7 Ion concentration
7.1 Measuring
NOTE
When connecting an earthed PC/printer, measurements cannot be
performed in earthed media as the values would be incorrect.
The USB interface is not galvanically isolated.
ISE
0.157 mg/l
25.0 °C
Ag
15.02.2014
Menu 12:12 USB output
ba77052d01 03/2014 37
Ion concentration pH/ION 3310
Stability control The stability control function (AutoRead) continually checks the stability of the
(AutoRead) measurement signal. The stability has a considerable impact on the reproduc-
& HOLD function ibility of measured values.
The measured parameter flashes on the display
as soon as the measured value is outside the stability range
when the automatic Stability control is switched off.
You can activate or switch off the automatic Stability control function (see
section 8.2.1 SYSTEM, page 52).
You can terminate the Stability control function and the HOLD func-
tion with <AR> or <M> at any time.
Criteria The AutoRead criteria affect the reproducibility of the measured values. The
following criteria can be adjusted:
high: highest reproducibility
medium: medium reproducibility
low: lowest reproducibility
38 ba77052d01 03/2014
pH/ION 3310 Ion concentration
Resolution of
Tempera- the temp. dis-
ture sensor play Temp. measurement
- 1 °C Manual
ba77052d01 03/2014 39
Ion concentration pH/ION 3310
7.2 Calibration
ISE Standard 1
0.0 mV
24.8 °C
Ag 0.010 mg/l
15.02.2014
12:12
40 ba77052d01 03/2014
pH/ION 3310 Ion concentration
0.0 mV
24.8 °C
AR
15.02.2014
12:12
11. Wait for the end of the AutoRead measurement or accept the calibration
value with <ENTER>.
The calibration display for the next standard solution appears.
ISE Standard 2
0.0 mV
24.8 °C
Ag 0.020 mg/l
15.02.2014
12:12
ba77052d01 03/2014 41
Ion concentration pH/ION 3310
8.9 mV
24.8 °C
AR
15.02.2014
12:12
16. Wait for the end of the AutoRead measurement or accept the calibra-
tion value with <ENTER>.
The calibration display for the next standard solution appears.
ISE Standard 3
20.5 mV
24.8 °C
Ag 0.050 mg/l
15.02.2014
12:12
Continuing with Repeat the steps 12 to 17 in the same way with the third and further standard
three- to seven-point solutions as necessary. The new calibration values are displayed after the last
calibration calibration step was completed.
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pH/ION 3310 Ion concentration
Use two to seven different standard solutions. The standard solutions have to
be selected in either increasing or decreasing order.
Select the unit of the standard solution and measurement result in
the ISE setup/Unit menu.
Displaying the cali- The calibration record of the last calibration is to be found under the menu item,
bration data <ENTER> / Calibration / Calibration record. To open it, press the <CAL__> key
in the measured value display.
Subsequently, you can transmit the displayed calibration data to the interface,
e.g. to a PC, with the <F2>[USB output] key.
Displaying the cali- The calibration records of the last calibrations (up to 10) are given in the menu,
bration data storage <ENTER>/Calibration / Calibration data storage.
ba77052d01 03/2014 43
Ion concentration pH/ION 3310
Calibration evalua- After calibrating, the meter automatically evaluates the calibration.
tion
Display Calibration Magnitude of the slope [mV]
record
+++ 50.0 ... 70.0 or 25.0 ... 35.0
CALIBRATIONISE
15.02.2014 08:09:10
44 ba77052d01 03/2014
pH/ION 3310 Settings
8 Settings
8.1 Measurement settings
The settings for pH measurements are made in the menu for calibration and
measurement settings of the pH/ORP measurement. To open the settings, dis-
play the required measured parameter in the measured value display and
press the <ENTER> (or <F1>/[Menu]) key. After completing the settings, switch
to the measured value display with <M>.
In the following table, only those settings are listed that concern the pH mea-
surement.
Default settings are printed in bold.
ba77052d01 03/2014 45
Settings pH/ION 3310
You can use the buffer sets quoted in the table for an automatic calibration. The
pH values are valid for the specified temperature values. The temperature
dependence of the pH values is taken into consideration during the calibration.
46 ba77052d01 03/2014
pH/ION 3310 Settings
ba77052d01 03/2014 47
Settings pH/ION 3310
Brand names or trade names are trademarks of their respective owners protected
by law.
48 ba77052d01 03/2014
pH/ION 3310 Settings
Setting the calibra- The calibration interval is set to 7 days in the factory.
tion interval You can change the interval (1 ... 999 days):
1. Using <ENTER> (or <F1>/[Menu]), open the menu for the measurement
settings.
2. In the Calibration / Calibration interval menu, set the calibration interval
with <><>.
3. Confirm the setting with <ENTER>.
4. Quit the menu with <M>.
The settings for ORP measurements are made in the menu for calibration and
measurement settings of the pH/ORP measurement. To open the settings, dis-
play the required measured parameter in the measured value display and
press the <ENTER> (or <F1>/[Menu]) key. After completing the settings, switch
to the measured value display with <M>.
In the following table, only those settings are listed that influence the ORP mea-
surement.
Default settings are printed in bold.
ba77052d01 03/2014 49
Settings pH/ION 3310
The settings for ISE measurements are made in the menu for calibration and
measurement settings of the ISE measurement.
To open the settings, display the required measured parameter in the mea-
sured value display and press the <ENTER> (or <F1>/[Menu]) key. After com-
pleting the settings, switch to the measured value display with <M>.
In the following table, only those settings are listed that influence the ISE mea-
surement:
50 ba77052d01 03/2014
pH/ION 3310 Settings
ba77052d01 03/2014 51
Settings pH/ION 3310
8.2.1 System
To open the Storage & config menu in the measured value display, press the
<ENTER__> (or <F1__>/[Menu]) key. After completing the settings, switch to
the measured value display with <M>.
Default settings are printed in bold.
52 ba77052d01 03/2014
pH/ION 3310 Settings
This menu contains all functions to display, edit and erase stored measured
values and calibration records (see section 9 DATA STORAGE, page 55).
8.3 Reset
You can reset (initialize) all sensor settings and sensor-independent settings
separately from each other.
The calibration data are reset to the default settings together with
the measuring parameters. Recalibrate after performing a reset.
The following settings for pH measurements are reset to the default settings
with the Reset function:
ba77052d01 03/2014 53
Settings pH/ION 3310
The sensor settings are reset under the Reset menu item in the menu for cali-
bration and measurement settings. To open it in the measured value display,
press the <ENTER> (or <F1>/[Menu]) key.
The system settings are reset in the menu, Storage & config / System / Reset.
To open the Storage & config menu in the measured value display, press the
<ENTER__> (or <F1__>/[Menu]) key.
54 ba77052d01 03/2014
pH/ION 3310 Data storage
9 Data storage
You can transmit measured values (datasets) to the data storage:
Manual data storage (see section 9.1 MANUAL STORAGE, page 55)
Automatic storage at intervals (see section 9.2 AUTOMATIC DATA STORAGE AT
INTERVALS, page 56)
With each data storage process, the current datasets of the sen-
sors indicated on the display are transmitted to the interface at the
same time.
15.02.2014 11:24:16
pH 7.000 24.8 °C AR +++
ID number: 1
Continue
15.02.2014
Back USB output
14:15
ba77052d01 03/2014 55
Data storage pH/ION 3310
If the storage is full The following window appears if all 500 storage locations are occupied:
Warning
Yes
No
Back 15.02.2014
14:15
Configuring the
1. Press the <STO__> key.
automatic storage
The menu for automatic data storage appears.
function
ID number 1
1
Interval 30 s
Duration 180 min
Continue
0d03h00min 2
0 1d17h33min
15.02.2014
Back 14:15
3
56 ba77052d01 03/2014
pH/ION 3310 Data storage
Settings You can configure the automatic data storage function with the following
settings:
Starting the auto- To start the automatic storage function, select Continue with <><> and
matic storage func- confirm with <ENTER>. The meter switches to the measured value display.
tion
pH 0 14
1
6.949
25.0 °C
0d03h00min
2
15.02.2014
Eco mode 14:15
The active automatic storage function can be recognized by the progress bar
in the function display. The progress bar indicates the remaining storage dura-
tion.
Energy saving mode If the automatic storing function is active, the meter provides an energy saving
([Eco mode]) mode ([Eco mode]) to avoid unnecessary energy consumption. The energy
ba77052d01 03/2014 57
Data storage pH/ION 3310
saving mode switches off functions of the meter that are not required for the
automatic storage of measurement data (such as the display). By pressing any
key the energy saving mode is switched off again.
Terminating the Proceed as follows to switch off the automatic data storage function before the
automatic storage adjusted storage duration has expired:
function prema-
turely
1. Press the <STO__> key.
The following window appears.
Warning
Yes
No
Back 15.02.2014
14:15
The settings are explained here using the manual data storage as
an example. The same settings and functions are available for the
automatic data storage.
58 ba77052d01 03/2014
pH/ION 3310 Data storage
15.02.2014
Back USB output
14:15
15.02.2014 10:56:20
pH/ION 3310
Ser. no. 08502113
ID number 2
________________________________________
etc...
Quitting the display To quit the display of stored measurement datasets, you have the following
ba77052d01 03/2014 59
Data storage pH/ION 3310
options:
Switch directly to the measured value display with <M>.
Quit the display and move to the next higher menu level with <F1>/[Back].
Erasing the measurement data storage (see section 9.3.1 EDITING THE
MEASURED VALUE STORAGE, page 58).
The pH/ION 3310 meter has two measurement data storages. The measured
values recorded either manually or automatic are stored separately in indi-
vidual measurement data storages.
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pH/ION 3310 Transmitting data (USB interface)
The following rule applies: With the exception of the menus, shortly
pressing the <F2>[USB output] key generally outputs the display
contents to the interface (displayed measured values, measure-
ment datasets, calibration records).
ba77052d01 03/2014 61
Transmitting data (USB interface) pH/ION 3310
10.2 Connecting a PC
Connect the pH/ION 3310 to the PC via the USB interface.
NOTE
When connecting an earthed PC/printer, measurements cannot be
performed in earthed media as the values would be incorrect.
The USB interface is not galvanically isolated.
Installation of the System requirements of the PC for installation of the USB driver:
USB driver on the
PC PC with Pentium processor or higher with at least one free USB connection
and CD-ROM drive
Windows XP, Windows 7.
62 ba77052d01 03/2014
pH/ION 3310 Maintenance, cleaning, disposal
You can operate the meter either with normal batteries or with
rechargeable batteries (Ni-MH). In order to charge the batteries, an
external charging device is required.
1 Screws
2 Battery compartment
CAUTION
Make sure that the poles of the batteries are positioned cor-
rectly. The ± signs on the batteries must correspond to the ±
signs in the battery compartment.
ba77052d01 03/2014 63
Maintenance, cleaning, disposal pH/ION 3310
5. Close the battery compartment (2) and tighten the screws (1).
6. Set the date and time (see section 4.4.6 EXAMPLE 2 ON NAVIGATION:
SETTING THE DATE AND TIME, page 18)
11.2 Cleaning
Occasionally wipe the outside of the measuring instrument with a damp, lint-
free cloth. Disinfect the housing with isopropanol as required.
CAUTION
The housing is made of synthetic material (ABS). Thus, avoid
contact with acetone or similar detergents that contain sol-
vents. Remove any splashes immediately.
11.3 Packing
This meter is sent out in a protective transport packing.
We recommend: Keep the packing material. The original packing protects the
meter against damage during transport.
11.4 Disposal
At the end of its operational lifetime, the meter must be returned to the
disposal or return system statutory in your country. If you have any questions,
please contact your supplier.
64 ba77052d01 03/2014
pH/ION 3310 What to do if...
12 What to do if...
12.1 pH/ORP
ba77052d01 03/2014 65
What to do if... pH/ION 3310
Test sample:
– pH value not stable – Measure with air excluded if
necessary
– Temperature not stable – Temper if necessary
66 ba77052d01 03/2014
pH/ION 3310 What to do if...
12.2 ISE
ba77052d01 03/2014 67
What to do if... pH/ION 3310
Cause Remedy
– Batteries almost empty – Replace the batteries (see
Display section 11.1 MAINTENANCE,
page 63)
68 ba77052d01 03/2014
pH/ION 3310 Technical data
13 Technical data
13.1 Measuring ranges, resolution, accuracy
13.1.1 pH/ORP
ba77052d01 03/2014 69
Technical data pH/ION 3310
13.1.2 ISE
70 ba77052d01 03/2014
pH/ION 3310 Technical data
ba77052d01 03/2014 71
Firmware update pH/ION 3310
14 Firmware update
Available firmware updates are provided on the Internet.
With the firmware update program and a PC you can update the firmware of the
pH/ION 3310 to the newest version.
For the update you have to connect the meter to a PC.
For the update via the USB interface, the following is required:
a free USB interface (virtual COM port) on the PC
the driver for the USB interface (on the enclosed CD-ROM)
the USB cable (included in the scope of delivery of the pH/ION 3310).
After switching the meter off and on you can check whether the meter has taken
over the new software version (see YOU WANT TO KNOW WHICH SOFTWARE
VERSION IS IN THE METER, PAGE 68).
72 ba77052d01 03/2014
pH/ION 3310 Glossary
15 Glossary
pH/ORP/ISE
General information
Resolution Smallest difference between two measured values that can be dis-
played by a meter.
AutoRange Name of the automatic selection of the measuring range.
Adjusting To manipulate a measuring system so that the relevant value (e.g. the
displayed value) differs as little as possible from the correct value or a
value that is regarded as correct, or that the difference remains within
the tolerance.
Calibration Comparing the value from a measuring system (e.g. the displayed
value) to the correct value or a value that is regarded as correct. Often,
this expression is also used when the measuring system is adjusted at
the same time (see adjusting).
Measured variable The measured parameter is the physical dimension determined by
measuring, e.g. pH, conductivity or D.O. concentration.
ba77052d01 03/2014 73
Glossary pH/ION 3310
Test sample Designation of the test sample ready to be measured. Normally, a test
sample is made by processing the original sample. The test sample and
original sample are identical if the test sample was not processed.
Measured value The measured value is the special value of a measured parameter to be
determined. It is given as a combination of the numerical value and unit
(e.g. 3 m; 0.5 s; 5.2 A; 373.15 K).
Molality Molality is the quantity (in Mol) of a dissolved substance in 1000 g sol-
vent.
Reset Restoring the original condition of all settings of a measuring system.
Stability control (Au- Function to control the measured value stability.
toRead )
Standard solution The standard solution is a solution where the measured value is known
by definition. It is used to calibrate a measuring system.
Temperature function Name of a mathematical function expressing the temperature behavior
of a test sample, a sensor or part of a sensor.
74 ba77052d01 03/2014
pH/ION 3310 Index
16 Index
ba77052d01 03/2014 75
Index pH/ION 3310
76 ba77052d01 03/2014
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