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1. Search for Pressure Vs. Volume plot for perfect gas and compare the graph for Isotherm ( p= ) and
v
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adiabatic ( p= ). An adiabatic depicts the variation of pressure with volume when a gas expands
v
reversibly and adiabatically. Why is it that pressure decreases more steeply for an adiabatic than it
does for an isotherm?

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2. Calculate the final temperature of a sample of argon ( C p=¿20.786 ) of mass 12.0g that I
K ∙ mol
expanded reversibly and adiabatically from 1.0 L at 273.15K to 3.0 L

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3. A sample of carbon dioxide (C p=¿37.11 ) of mass 2.45 g at 27 ℃ is allowed to expand
K ∙ mol
reversibly arid adiabatically from 500mL to 3.00L. What is the work done by the gas?

4. Calculate the final pressure of a sample of carbon dioxide that expands reversibly and adiabatically
from 57.4 kPa and 1.0L to a final volume of 2.0 L take γ =¿ 1.4
5. When 3.0 mol O 2 is heated at a constant pressure of 1.25 atm, its temperature increases from 260 K to
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285 K. Given that the molar heat capacity of O 2 at constant pressure is 29.4 , calculate q, ΔH
K ∙ mol
, and ΔU .
6. Eight grams of O 2 at 27°C and under a pressure of 10 atm are permitted to expand adiabatically and
reversibly until the final pressure is 1 atm.Find the final temperature and the work done in the
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process. Assume that C p= R for O 2
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7. Ten grams of N2 at 17°C are compressed adiabatically and reversibly from 8 to 5 liters. Calculate the
final temperature and the work done on the gas. What are ΔU and ΔH for the process? Assume that
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C p= R .
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8. For a certain ideal gas C p= 8.58 cal mole- 1 degree-1. What will be the final volume and temperature
when 2 moles of the gas at 20°C and 15 atm are allowed to expand adiabatically and reversibly to 5
atm pressure?
 
 

 
 
 

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