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    Stoich and Thermo Practice Problems

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    Doom Refuge
    1. The document provides 10 practice chemistry problems involving stoichiometry calculations, thermochemistry, and determining empirical formulas. It includes relevant thermochemical data in tables for calculating enthalpy changes. 2. Problem 15 asks to determine the empirical formula of a compound that produced a specific amount of CO2 and H2O upon combustion, using the amounts of C, H, N, O and compound reacted. 3. Problem 16 provides the mass of CO2 and H2O produced from burning a sample of an unknown organic compound containing C, H and O, and asks for the empirical and molecular formulas given the molecular weight.

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    Stoich and Thermo Practice Problems

    Uploaded by

    Doom Refuge
    86 views3 pages
    1. The document provides 10 practice chemistry problems involving stoichiometry calculations, thermochemistry, and determining empirical formulas. It includes relevant thermochemical data in tables for calculating enthalpy changes. 2. Problem 15 asks to determine the empirical formula of a compound that produced a specific amount of CO2 and H2O upon combustion, using the amounts of C, H, N, O and compound reacted. 3. Problem 16 provides the mass of CO2 and H2O produced from burning a sample of an unknown organic compound containing C, H and O, and asks for the empirical and molecular formulas given the molecular weight.

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    Chem 16 Stoich and Thermo Practice Problems

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    1. The document provides 10 practice chemistry problems involving stoichiometry calculations, thermochemistry, and determining empirical formulas. It includes relevant thermochemical data in tables for calculating enthalpy changes. 2. Problem 15 asks to determine the empirical formula of a compound that produced a specific amount of CO2 and H2O upon combustion, using the amounts of C, H, N, O and compound reacted. 3. Problem 16 provides the mass of CO2 and H2O produced from burning a sample of an unknown organic compound containing C, H and O, and asks for the empirical and molecular formulas given the molecular weight.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    86 views3 pages

    Stoich and Thermo Practice Problems

    Uploaded by

    Doom Refuge
    1. The document provides 10 practice chemistry problems involving stoichiometry calculations, thermochemistry, and determining empirical formulas. It includes relevant thermochemical data in tables for calculating enthalpy changes. 2. Problem 15 asks to determine the empirical formula of a compound that produced a specific amount of CO2 and H2O upon combustion, using the amounts of C, H, N, O and compound reacted. 3. Problem 16 provides the mass of CO2 and H2O produced from burning a sample of an unknown organic compound containing C, H and O, and asks for the empirical and molecular formulas given the molecular weight.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 3

    CHEM 16 Practice Problems:

    1. Automotive air bags inflate when sodium azide, NaN3, rapidly decomposes to its component
    elements.
    (a) How many moles of nitrogen gas are produced by the decomposition of 1.50 moles of
    NaN3?
    (b) How many grams of NaN3 are required to form 5.00 g of nitrogen gas?
    2. One of the steps in the commercial process for converting ammonia to nitric acid involves the
    conversion of NH3 to NO:
    NH3(g) + O2(g) → NO(g) + H2O(g)

    (a) In a certain experiment 2.50 g NH3 reacts with 2.85 g of O2. How many grams of NO
    form?

    m
    (b) How much of the excess reactants remains after the limiting reactant is completely
    consumed?
    3.
    he
    (a) How many milliliters of stock solution of 12.0 M HNO 3 would you have to use to
    prepare 0.500 L of 0.200 M HNO3?
    (b) If you dilute 20.0 mL of the stock solution to a final volume of 1.00 L, what will be the
    C
    concentration of the diluted solution?
    (c) Calculate the concentration of the ions formed when 3.50 g of KCl in 60.0 mL of 0.500
    M CaCl2 solution (assume that the volumes are additive) are mixed.
    PD

    4. How many milliliters of 2.50 M H2SO4 are needed to neutralize 75.0 g of NaOH?
    5. Calculate the ∆U, and determine whether the process is endothermic or exothermic for the
    U

    following cases:
    (a) a system releases 113 kJ of heat to the surroundings and does 39 kJ of work on the
    surroundings.
    (b) the system absorbs 77.5 kJ of heat while doing 63.5 kJ of work on the surroundings.
    6. Using the table below, write thermochemical equations for the following:
    (a) mercury thawing
    (b) bromine vaporizing
    7. Consider the following reaction:
    CH3OH (g) → CO (g) + 2 H2 (g) ∆H = +90.7

    (a) Is the reaction exothermic or endothermic?

    ||lslico||03.30.2019||
    (b) Calculate the amount of heat transferred when 45.0 g of CH3OH(g) are decomposed
    by this reaction at constant pressure.
    (c) If the enthalpy change is 16.5 kJ, how many grams of hydrogen gas are produced?
    (d) How many kilojoules of heat are released when 10.0 g of CO (g) reacts completely
    with H2(g) to form CH3OH (g) at constant pressure?
    8. The specific heat of copper metal is 0.0385 J/g-K. How many joules of heat are necessary to
    raise the temperature of a 1.42 kg block of copper from 25.0°C to 88.5°C?
    9. A 1.800 g sample of octane (C8H18), was burned in a bomb calorimeter whose total heat
    capacity is 11.66 kJ/°C. The temperature of the calorimeter plus contents increases from 21.36°C
    to 28.78°C. What is the heat of combustion per gram of octane? Per mole of octane?
    10. From the following enthalpies of reaction:
    H2 (g) + F2 (g) → 2 HF (g) ∆H = -537 kJ

    m
    C (s) + 2 F2 (g) → CF4 (g) ∆H = -680 kJ

    2 C (s) + 2 H2 (g) → C2H4 (g) ∆H = +52.3 kJ


    he
    Use Hess’s law to calculate the ∆H for the reaction of ethylene (C2H4) with F2:
    C2H4 (g) + 6F2 (g) → 2 CF4 (g) + 4 HF (g)
    C
    11. Consider the combustion of one mole of acetylene (C 2H2) which yields carbon dioxide and
    liquid water. Calculate ∆H using the table below.
    PD

    12. Use bond enthalpies to estimate the enthalpy change for each of the following reactions:
    (a) HCN (g) + 2 H2 (g) → CH3NH2 (g)

    (b) N2H4 (g) + H2O (g) → NH2OH (g) + NH3 (g)


    U

    13. For which of the following processes given below does the entropy of the system increase?
    (a) the melting of the ice cubes at -5°C and 1 atm pressure
    (b) dissolution of sugar in a cup of hot coffee
    (c) the reaction of nitrogen atoms to form N2 molecules at 25°C and 1 atm
    (d) alignment of the iron fillings in a magnetic field
    (e) CO (g) + 2 H2 (g) → CH3OH (l)
    (f) FeCl2 (s) + H2 (g) → Fe (s) + 2 HCl (g)

    14. Describe and discuss the ∆G values and spontaneity conditions for each of the following
    reactions.
    (a) N2 (g) + 3 F2 (g) → 2 NF3 (g) ∆H° = -249 kJ ∆S° = -278 J/K
    (b) N2 (g) + 3 Cl2 (g) → 2 NCl3 (g) ∆H° = +460 kJ ∆S° = -275 J/K
    (c) N2F4 (g) → 2 NF2 (g) ∆H° = +85 kJ ∆S° = +198 J/K

    ||lslico||03.30.2019||
    15. In the course of the combustion analysis of an unknown compound containing only carbon,
    hydrogen, and nitrogen, 12.923 g of carbon dioxide and 6.608 g of water were measured.
    Treatment of the nitrogen with H2 gas resulted in 2.501g NH3. The complete combustion of 11.014
    g of the compound needed 10.573 g of oxygen. What the compound’s empirical formula?
    16. Compound X, commonly used in the dye industry and in photography, is an organic compound
    containing only C, H, and O. What is the empirical formula of the compound if you find that 0.105
    g of the compound gives 0.257 g of CO2 and 0.0350 g of H2O when burned completely? Given a
    molecular weight of approximately 108 g/mol, what is its molecular formula?
    17. Determine the simplest formula for each of the following compounds:
    (a) copper(II) tartrate: 30.03% Cu; 22.70% C;1.91% H; 45.37% O.
    (b) nitrosyl fluoroborate: 11.99% N; 13.70% O; 9.25% B; 65.06% F.

    Table:

    m
    Substance ∆H0f (kJ/ mol)
    Br (g) +111.8
    Br – (aq) -120.9
    he
    Br2 (g)
    Br2 (l)
    HBr (g)
    +30.71
    0
    -36.23
    C
    CaCl2 (s) -795.8
    Ca(OH)2 (s) -986.2
    C2H2 (g) +226.7
    C6H6 (g) +82.9
    PD

    C6H6 (l) +49.0


    H2O (g) -241.82
    H2O (l) -285.83
    Hg(g) +60.83
    Hg (l) 0
    U

    HgCl2 (s) -230.1


    Hg2Cl2 (s) -264.9
    O (g) +247.5
    O2 (g) 0
    O3 (g) +142.3

    Bonds Bond N-N 163 C≡N 891


    Enthalpy N-O 201 C=N 615
    (kJ/mol) O-H 463 C=O 799
    C-H 413 O-O 146 C≡O 1072
    C-C 348 H-H 436 N=N 418
    C-N 293 C=C 614 N≡N 941
    N-H 391 C≡C 839 N=O 607

    ||lslico||03.30.2019||

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