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DCH215 1

This document appears to be an exam for a chemistry course. It contains 9 questions covering various topics in spectroscopy: 1. Question 1 asks students to define basic spectroscopy terms like absorbance and Beer-Lambert's law, and give examples of infrared active and inactive molecules. 2. Questions 2-5 cover topics in different units, including rotational spectra, isotopic effects, the Frank-Condon principle, and vibrational structure. 3. Questions 6-9 focus on infrared spectroscopy, defining terms, discussing what happens when a molecule absorbs IR radiation, and applications of IR spectroscopy like fingerprint regions.

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Vishal Tanwar
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© © All Rights Reserved
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Download as PDF, TXT or read online on Scribd
39 views

DCH215 1

This document appears to be an exam for a chemistry course. It contains 9 questions covering various topics in spectroscopy: 1. Question 1 asks students to define basic spectroscopy terms like absorbance and Beer-Lambert's law, and give examples of infrared active and inactive molecules. 2. Questions 2-5 cover topics in different units, including rotational spectra, isotopic effects, the Frank-Condon principle, and vibrational structure. 3. Questions 6-9 focus on infrared spectroscopy, defining terms, discussing what happens when a molecule absorbs IR radiation, and applications of IR spectroscopy like fingerprint regions.

Uploaded by

Vishal Tanwar
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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Unit III No. of Printed Pages : 05 Roll No. .......................

6. Define the following terms : 15


C513
(a) Absorbance
(b) Bathochromic Shift Dual Degree B. Sc. (Hons.) M. Sc.
(c) Molar Extinction coefficient (Bio-technology) EXAMINATION,
(d) Hypsochromic Shift Dec. 2018
(e) Beer-Lambert's Law
(Third Semester)
(f) Woodward-Fieser Rules.
(Main Only)
7. (a) What do you understand by the terms
Phy & BT
Chromophores and Auxochrome ?
Describe with suitable example. 5 DCH215
(b) What are the different electronic CHEMISTRY–III
transitions possible in electronic
spectroscopy ? 5 Time : 3 Hours] [Maximum Marks : 75
(c) 1, 3-Butadiene Absorbs at longer
Before answering the question-paper candidates
wavelength, in comparison to ethylene.
Give reason. 5 should ensure that they have been supplied to correct
and complete question-paper. No complaint, in this
Unit IV
regard, will be entertained after the examination.
8. (a) Describe the effect of conjugation and
Note : The question paper comprises of nine
hydrogen boding on vibrational
frequencies in the IR spectra. 8 questions. The candidates will be required

M-C513 4 (1-06/11) M-C513 P.T.O.


to attempt five question in all. Q. No. 1 is (b) Discuss pure rotational spectra of
compulsory. The candidates shall attempt diatomic molecules. How can it be used
four more questions selecting at least one to determine bond length ? 7
from each Unit. All questions carry equal
marks. 3. (a) What is Isotopic Effect ? Explain with
suitable examples. 5
1. (a) What are the basic features of
(b) Use Maxwell-Boltzman distribution law
Spectroscopy ?
for relative intensities of rotational spectra
(b) What do you understand by degree of
freedom ? Calculate the degree of lines. 5
freedom of C2H2. (c) Write short notes on the following :
(c) What type of molecule show vibrational (i) Resolving Power
spectra ? Give two examples each of (ii) Selection Rules. 5
infrared active and infrared inactive
molecule. Unit II
(d) Explain the effect of increase of polarity
4. Define and explain Frank-Condon Principle.
of solvent on n-* transition.
How can we calculate dissociation energy using
(e) Explain Fermi resonance with suitable
Frank-Condon Principle. 15
examples.

Unit I 5. (a) Give a note on Vibrational Course


Structure. 7
2. (a) What do you mean by intensity of spectral
(b) Explain rotational fine structure of
lines ? Explain factors affecting the
electronic band. 8
intensity of spectral lines. 7

M-C513 2 (1-06/12) M-C513 3 P.T.O.


(b) What happen when a molecule absorbs (b) What happen when a molecule absorbs
IR radiation ? What are fundamental IR radiation ? What are fundamental
vibrations and overtones ? 5 vibrations and overtones ? 5
(c) What do you mean by Finger Print and (c) What do you mean by Finger Print and
Functional Group Region ? 2 Functional Group Region ? 2

9. (a) Define and explain the following terms 9. (a) Define and explain the following terms
used in IR spectroscopy. 6 used in IR spectroscopy. 6
(i) Overtone and Combination Band (i) Overtone and Combination Band
(ii) Scissoring and Rocking (ii) Scissoring and Rocking
(iii) Wagging and Rocking. (iii) Wagging and Rocking.
(b) Discuss the application of IR (b) Discuss the application of IR
spectroscopy. 6 spectroscopy. 6
(c) Why C-H stretching virations move to (c) Why C-H stretching virations move to
higher frequency in the sequence : 3 higher frequency in the sequence : 3
Alkane < Alkene < Alkyne. Alkane < Alkene < Alkyne.

M-C413 5 130 (1-06/13) M-C413 5 130

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