SAFETY DATA SHEET

DEFOAMER

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product name PETROPATH DEFOAMER

Product number C036 EV

Internal identification Janitorial

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses De-foaming silicone emulsion for extraction machines.

1.3. Details of the supplier of the safety data sheet

PetroPath Fluids India Pvt.Ltd

#9,Naik Business House, 1st Main, Brindavan Extension,
Arekere Mico Layout, Bannerghatta Road, Bangalore-560076
MOB: +91-9901274500/ +91-9901260100
Mail: [email protected]
Classification of the substance or mixtureClassification (EC 1272/2008)

Physical hazards Not Classified

SECTION 2: Hazards identification

Health hazards Elicitation - EUH208

Environmental hazards Not Classified

2.1. Label elements

Hazard statements EUH208 Contains METHYL-2H or METHYL-4 (3:1) Mixture of EC NO 220-239-6. May
produce an allergic reaction.

Precautionary statements P102 Keep out of reach of children.

P301 IF SWALLOWED:
P313 Get medical advice/ attention.
P501 Dispose of contents/ container in accordance with local regulations.

2.2. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

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 METHYL-2H or METHYL-4 (3:1) Mixture of EC NO 220-239- <0.1%
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CAS number: 55965-84-9
M factor (Acute) = 1 M factor (Chronic) = 1
Mixture of 5-Chloro-2-methyl-2H-isothiazol-3-one and 2-Methyl-2H-isothiazol-3-one.
.Spec Conc Limits :- Skin Sens. 1; H317 ≥ 0.0015%, EUH208 ≥ 0.00015%

Classification
Acute Tox. 3 - H301
Acute Tox. 3 - H311
Acute Tox. 3 - H331
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Skin Sens. 1 - H317
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition comments The product contains a small amount of sensitising substance.

SECTION 4: First aid measures

4.1. Description of first aid measures
Inhalation Unlikely route of exposure as the product does not contain volatile substances. If spray/mist
has been inhaled, proceed as follows. Move affected person to fresh air and keep warm and
at rest in a position comfortable for breathing.

Ingestion Do not induce vomiting. Give plenty of water to drink. Get medical attention if any discomfort
continues.

Skin contact Wash with plenty of water.

Eye contact Rinse with water. Get medical attention promptly if symptoms occur after washing.

4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

Inhalation No specific symptoms known.

Ingestion No specific symptoms known. But - May cause discomfort if swallowed.

Skin contact The product contains a small amount of sensitising substance. Prolonged or repeated
exposure may cause the following adverse effects: May cause sensitisation by skin contact.

Eye contact No specific symptoms known. But prolonged eye contact may lead to the product affecting the
natural lubrication provided by the mucous membranes.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire.

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Specific hazards Thermal decomposition or combustion products may include the following substances:
Irritating gases or vapours.

5.3. Advice for firefighters

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Avoid contact with skin. No special protective clothing. (See Sec 8)

6.2. Environmental precautions

Environmental precautions Spillages or uncontrolled discharges into watercourses must be reported immediately to the
Environmental Agency or other appropriate regulatory body.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Small Spillages: Flush away spillage with plenty of water. Large Spillages: Contain spillage
with sand, earth or other suitable non-combustible material. Collect and place in suitable
waste disposal containers and seal securely.

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Usage precautions Avoid contact with skin.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Keep only in the original container in a cool, well-ventilated place. Store away from the
following materials: Oxidising materials.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

Usage description See Product Information Sheet & Label for detailed use of this product.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Ingredient comments No exposure limits known for ingredient(s).

8.2. Exposure controls

Appropriate engineering Not relevant.
controls

Eye/face protection None required.

Hand protection No specific hand protection recommended. For prolonged or repeated skin contact use
suitable protective gloves.

Other skin and body Wear appropriate clothing to prevent repeated or prolonged skin contact.
protection

Respiratory protection Respiratory protection not required.

SECTION 9: Physical and chemical properties

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9.1. Information on basic physical and chemical properties
Appearance Emulsion.

Colour White.

Odour Faint

pH pH (concentrated solution): 6.50

Melting point 0°C

Initial boiling point and range 100°C @ 760 mm Hg

Flash point Boils without flashing.

Relative density 1.006 @ 20°C

Solubility(ies) Dispersible in water.

9.2. Other information

Other information None.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stability No particular stability concerns.

10.3. Possibility of hazardous reactions

Possibility of hazardous See sections 10.1,10.4 & 10.5
reactions

10.4. Conditions to avoid

Conditions to avoid There are no known conditions that are likely to result in a hazardous situation.

10.5. Incompatible materials

Materials to avoid No specific material or group of materials is likely to react with the product to produce a
hazardous situation.

10.6. Hazardous decomposition products

Hazardous decomposition No known hazardous decomposition products.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Toxicological effects We have not carried out any animal testing for this product. Any ATE figures quoted below are
from Toxicity Classifications that have been carried out using ATE (Acute Toxicity Estimate)
Calculation Method using LD50 or ATE figures provided by the Raw Material Manufacturer.

Other health effects Low oral toxicity, but ingestion may cause irritation of the gastro-intestinal tract.

SECTION 12: Ecological information

Ecotoxicity Not regarded as dangerous for the environment.

12.1. Toxicity

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Toxicity We have not carried out any Aquatic testing, therefore we have no Aquatic Toxicity Data
specifically for this product. The Aquatic Toxicity Data, where provided by the raw material
manufacturer for ingredients with aquatic toxicity, can be made available on request.

12.2. Persistence and degradability

Persistence and degradability This product, at use dilutions, is readily broken down in biological effluent treatment plants.

12.3. Bioaccumulative potential

Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating.

12.4. Mobility in soil

Mobility Not known.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects Not known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Disposal methods Discharge used solutions to drain. Small amounts (less than 5 Litres) of unwanted product
may be flushed with water to sewer. Larger volumes must be sent for disposal by approved
waste contractor. Consign empty container to normal waste.

SECTION 14: Transport information

General Not classified for Transport.

14.1. UN number

14.2. UN proper shipping name

14.3. Transport hazard class(es)

14.4. Packing group

14.5. Environmental hazards

14.6. Special precautions for user

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation Safety Data Sheet prepared in accordance with REACH Commission Regulation (EU) No
2015/830 (which amends Regulation (EC) No 453/2010 & 1907/2006).
The product is as classified under GHS/CLP- Regulation (EC) No 1272/2008 classification,
labelling & packaging of substances & mixtures.
Ingredients are listed with classification under GHS/CLP - Regulation (EC) No 1272/2008
classification, labelling & packaging of substances & mixtures.

15.2. Chemical safety assessment

No chemical safety assessment has been carried out as not applicable as this product is a mixture.

SECTION 16: Other information

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Abbreviations and acronyms PBT: Persistent, Bioaccumulative and Toxic substance.
used in the safety data sheet vPvB: Very Persistent and Very Bioaccumulative.
ATE: Acute Toxicity Estimate.
REACH: Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation
(EC) No 1907/2006.
GHS: Globally Harmonized System.
Spec Conc Limits = Specific Concentration Limits.

Classification abbreviations Acute Tox. = Acute toxicity

and acronyms Aquatic Acute = Hazardous to the aquatic environment (acute)
Aquatic Chronic = Hazardous to the aquatic environment (chronic)
Eye Dam. = Serious eye damage
Skin Corr. = Skin corrosion
Skin Sens. = Skin sensitisation

Key literature references and Material Safety Data Sheet, Miscellaneous manufacturers. CLP Class - Table 3.1 List of
sources for data harmonised classification and labelling of hazardous substances. ECHA - C&L Inventory
database.

Classification procedures Calculation Method.

according to Regulation (EC)
1272/2008

Revision comments Safety Data Sheet amended in accordance with REACH Commission Regulation (EU) No
2015/830 amendment. (Changes to Sections 2,3,15&16)

Revision date 01/08/2017

Revision 5

Hazard statements in full EUH208 Contains METHYL-2H or METHYL-4 (3:1) Mixture of EC NO 220-239-6. May
produce an allergic reaction.
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H331 Toxic if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

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