CHEM-Types of Solid

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Types of Solid

1) Crystalline solids- solids in which the atoms, ions, or molecules are


arranged in a definite repeating pattern. It is also possible for a liquid to
freeze before its molecules become arranged in an orderly pattern.
2) Amorphous solids or non-crystalline solids (or, sometimes, glasses). The
particles of such solids lack an ordered internal structure and are randomly
arranged.

SOLIDS
Amorphous Solids Crystalline Solids
Particles are arranged randomly and Particles are arranged in an ordered
have no ordered pattern. repeating pattern.

Ex. Quartz glass, rubber, plastics Ex. Sodium chloride, Quartz

Soften over a range of temperature Sharp melting point

Isotropic in nature (Isotropic means the Anisotropic in nature (Anisotropic


value of any physical property would be means the value of same physical
same along any direction) property is found to be different along
each direction)
Do not have definite heat of fusion.
Definite and characteristics heat of
fusion.
MAJOR TYPES OF CRYSTALLINE SOLIDS

Ionic solids- such as sodium chloride and nickel


oxide, are composed of positive and negative ions
that are held together by electrostatic attractions,
which can be quite strong. Many ionic crystals also
have high melting points.

Sodium chloride is an ionic solid

Metallic solids- such as crystals of copper,


aluminum, and iron are formed by metal atoms. The
structure of metallic crystals is often described as a
uniform distribution of atomic nuclei within a “sea” of
delocalized electrons.

Copper is a metallic solid.

Covalent network solids- include crystals of diamond, silicon, some other non-
metals, and some covalent compounds such as silicon dioxide (sand) and silicon
carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of
covalent bonds. The atoms in these solids are held together by a network of
covalent bonds.

covalent crystal contains a three-dimensional network of covalent bonds, as


illustrated by the structures of diamond, silicon dioxide, silicon carbide, and graphite.
Molecular solids- such as ice, sucrose (table sugar), and iodine, are composed of
neutral molecules. The strengths of the attractive forces between the units present
in different crystals vary widely, as indicated by the melting points of the crystals.
Small symmetrical molecules (nonpolar molecules), such as H 2, N2, O2, and F2, have
weak attractive forces and form molecular solids with very low melting points (below
−200 °C).

Carbon dioxide (CO2) consists of small, nonpolar molecules and forms a molecular
solid with a melting point of −78 °C. Iodine (I2) consists of larger, nonpolar
molecules and forms a molecular solid that melts at 114 °C.

Types of Crystalline Solids and Their Properties


Types of solid Type of Types of Properties Examples
particles attraction
Ionic Ions ionic bonds hard, brittle, NaCl, Al2O3
conducts
electricity as a
liquid but not
as a solid,
high to very
high melting
points
Metallic atoms of metallic bonds shiny, Cu, Fe, Ti, Pb,
electropositive malleable, U
elements ductile,
conducts heat
and electricity
well, variable
hardness and
melting
temperature
Covalent atoms of covalent very hard, not C (diamond),
Network electronegative bonds conductive, SiO2, SiC
elements very high
melting points
Molecular molecules (or IMFs variable H2O, CO2, I2,
atoms) hardness, C12H22O11
variable
brittleness, not
conductive,
low melting
points

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