Gas Turbine Fuel Oils: Standard Specification For
Gas Turbine Fuel Oils: Standard Specification For
Gas Turbine Fuel Oils: Standard Specification For
for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D2880 − 20
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D2880 − 20
TABLE 1 Detailed Requirements for Gas Turbine Fuel Oils at Time and Place of Custody Transfer to UserA,B,C
ASTM GradeE
Property Test
F
MethodD No. 0-GT No. 1-GT No. 2-GTF No. 3-GT No. 4-GT
G
Flash point D93 38 (100) 38 (100) 55 (130) 66 (150)
°C (°F) min
Water and sediment D2709 0.05 0.05 0.05 ... ...
% vol max D1796 ... ... ... 1.0 1.0
Distillation
Temperature D86
°C (°F)
90 % volume recovered
min ... ... 282 ... ...
max ... 288 338 ... ...
Kinematic viscosity
2 mm/sH D445
G
AT 40 °C (104 °F) min 1.3 1.9 5.5 5.5
max 2.4 4.1 ... ...
AT 100 °C (212 °F) max ... ... 50.0 50.0
Ramsbottom
Carbon residue D524 0.15 0.15 0.35 ... ...
on
10 % distillation
Residue
% mass, max
Ash
% mass, max D482 0.01 0.01 0.01 0.03 ...
Density at D1298
15 °C kg/m3
max ... 850 876 ... ...
H
Pour point D97 ... −18 −6 ... ...
°C (°F) max
A
To meet special operating conditions, modifications of individual limiting requirements may be agreed upon between purchaser, seller, and manufacturer.
B
Gas turbines with waste heat recovery equipment may require fuel sulfur limits to prevent cold end corrosion. Environmental limits may also apply to fuel sulfur in selected
areas in the United States and in other countries.
C
See Section 4 and 5 for further statements on gas turbine fuel oil requirements.
D
The test methods indicated are the approved referee methods. Other acceptable methods are indicated in 6.1.
E
No. 0-GT includes naphtha, Jet B fuel and other volatile hydrocarbon liquids. No. 1-GT corresponds in general to specification D396 Grade No. 1 fuel and D975 Grade
1-D diesel fuel in physical properties. No. 2-GT corresponds in general to Specification D396 No. 2 fuel and D975 Grade 2-D diesel fuel in physical properties. No. 3-GT
and No. 4-GT viscosity range brackets specification D396 Grades No. 4, No. 5 (light), No. 5 (heavy), and No. 6, and D975 Grade No. 4-D diesel fuel in physical properties.
F
Under United States regulations, Grades No. 1-GT and No. 2-GT are required by 40 CFR Part 80 to contain a sufficient amount of dye Solvent Red 164 so its presence
is visually apparent. At or beyond terminal storage tanks, they are required by 26 CFR Part 48 to contain the dye Solvent Red 164 at a concentration spectrally equivalent
to 3.9 lb per thousand barrels of the solid dye standard Solvent Red 26.
G
When the flash point is below 38 °C (100 °F) or when kinematic viscosity is below 1.3 mm2/s at 40 °C (104 °F) or when both conditions exist, the turbine manufacturer
should be consulted with respect to safe handling and fuel system design.
H
For cold weather operation, the pour point should be specified 6 °C below the ambient temperature at which the turbine is to be operated except where fuel heating
facilities are provided. When a pour point less than −18 °C is specified for Grade No. 2-GT, the minimum viscosity shall be 1.7 mm2/s and the minimum 90 % recovered
temperature shall be waived.
Specification D975. It is the intent that fuels meeting Specifi- therefore, require on-site clean-up, quality control procedures,
cation D396 and D975 requirements may also be supplied special handling, or other arrangements.
under these specifications provided they meet the requirements
listed in Table 1. 6. Test Methods
5.2 Modifications of limiting requirements and the inclusion 6.1 The requirements enumerated in this specification shall
of fuel additives to meet special operating conditions may be be determined in accordance with the following ASTM meth-
agreed upon between the interested parties. ods except as noted:
5.3 The properties listed in this specification are those of 6.1.1 Flash Point—Test Methods D93, except where other
greatest significance in obtaining acceptable performance of methods are prescribed by law. For all grades, Test Method
the turbine. However, trace metals, even in fractional parts per D3828 and D7094 may be used as an alternative with the same
million, are detrimental to gas turbine service life. Information limits. For Grades No. 1-GT and No. 2-GT, Test Method D564
on the maximum concentration of critical metallic elements in may be used as an alternative with the same limits provided the
the fuel as it enters the turbine combustor(s) is provided in flash point is below 93 °C and the viscosity is below 5.5 mm2/s
Appendix X2. Distillate fuels are usually of satisfactory purity at 40 °C. This test method will give slightly lower values. In
as refined, but suppliers rarely have control over possible case of dispute, Test Method D93 shall be used as the referee
contamination by trace metals in distribution and storage. The method.
limits in Appendix X2, although required as the fuel enters the
combustor(s), do not apply to the fuel as delivered unless
mutually agreed upon by the interested parties. Fuels may, 4
Other mutually acceptable methods may be used.
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6.1.2 Pour Point—Test Method D97. For all grades, the Test Method D7042 may be used as alternative results for Test
automatic Test Methods D5949, D5950, D5985 or D7346 may Method D445. Section 15, Precision and Bias, of Test Method
be used as alternates with the same limits. In case of dispute, D7042 contains bias-correction information. In case of dispute,
Test Method D97 shall be used as the referee method. Test Method D445 shall be used as the referee method.
6.1.3 Water and Sediment—Test Method D2709 is used for 6.1.8 Density—Test Method D1298 or D4052.
Grades 0-GT, 1-GT, and 2-GT. Test Method D1796 is used for 6.1.9 Sulfur—Test Method D129, Test Methods
Grades 3-GT and 4-GT. D1552,5 D2622, and D4294 can also be used for all grades. In
6.1.4 Carbon Residue—Test Method D524. addition, Test Method D1266 can be used for Grades No. 0 and
6.1.5 Ash—Test Method D482. No. 1, but only with samples having sulfur contents of 0.4 %
by mass and less (down to 0.01 %). Test Method D5453 can be
6.1.6 Distillation—Distillation of grades No. 0-GT, No.
used for Grades 0, 1, and 2 GT oils, but only with samples
1-GT, and No.2-GT fuels oils shall be determined in accor-
having sulfur contents of 0.8 % by mass and less (down to
dance with Test Methods D86, D7344, or D7345. Results from
0.001 %). Test Method D7220 may be used for Grades 0, 1,
Test Method D7344 shall be reported as “Predicted D86”
and 2 GT oils, but only with samples having sulfur contents of
results by application of the corrections described in Test
0.942 % by mass and less (down to 0.0003 %). Test Method
Method D7344 to improve agreement with D86 values. Results
D129 is the referee sulfur test method for Specification D2880.
from Test Method D7345 shall be reported as “Predicted D86”
results by application of the corrections described in Test 7. Keywords
Method D7345 to improve agreement with D86 values. In case
7.1 fuel oils; gas turbine; petroleum and petroleum products
of dispute, Test Method D86 shall be used as the referee test
method.
5
For information on the precision of the ASTM methods of test for fuel oils refer
6.1.7 Viscosity—Test Methods D445, D7042, or D7945 may
to “An Evaluation of Methods for Determination of Sulfur in Fuel Oils” by A. R.
be used. Test method D7945 may be used with the same limits Crawford and G. V. Dyroff (1969). This document is available from the Publications
as D445 for grades 1-GT and 2-GT. Bias-corrected values from Section, American Petroleum Institute, 1220 L St., N.W., Washington, DC 20005.
APPENDIXES
(Nonmandatory Information)
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Specification D2880. However, specification tests would normally have to X1.4.1.5 Ash is the noncombustible material in an oil.
be run to ensure compliance with the requirements of Specification D2880 Ash-forming materials may be present in fuel oil in two forms:
as other fuels are not necessarily interchangeable with D2880 fuels
throughout the range permitted by the other specifications. (1) solid particles and (2) oil- or water-soluble metallic
compounds. The solid particles are for the most part the same
X1.3 Selection of Particular Grade material that is designated as sediment in the water and
X1.3.1 The selection of a particular gas turbine fuel oil from sediment test. Depending on their size, these particles can
one of these five ASTM grades for use in a given gas turbine contribute to wear in the fuel system and to plugging of the fuel
requires consideration of the following factors: filter and the fuel nozzle. The soluble metallic compounds have
X1.3.1.1 Availability of the fuel, little or no effect on wear or plugging, but they can contain
X1.3.1.2 Design of the gas turbine and fuel handling elements that produce turbine corrosion and deposits as de-
system, scribed subsequently.
X1.3.1.3 Maintenance of the gas turbine, and
X1.4.1.6 Distillation—The distillation test shows the vola-
X1.3.1.4 Operating requirements for the gas turbine.
tility of a fuel and the ease with which it can be vaporized.
X1.4 Significance of Test Methods Distillation temperature is not directly significant to operation
X1.4.1 The significance of the properties of fuel oil on of gas turbines designed for Grades 3-GT and 4-GT. In other
which limitations are placed by the specifications is as follows: gas turbines that are most susceptible to carbon deposition and
X1.4.1.1 Flash point is an indication of the maximum smoke formation, the more volatile fuels may provide better
temperature at which a fuel oil can be stored and handled performance.
without serious fire hazard. The minimum permissible flash X1.4.1.7 Viscosity of a fluid is a measure of its resistance to
point is usually regulated by federal, state, or municipal laws flow. In fuel oil it is highly significant since it indicates both the
and is based on accepted practice in handling and use. relative ease with which the oil will flow or may be pumped,
X1.4.1.2 Pour point is an indication of the lowest tempera- and the ease of atomization by the fuel nozzles. Minimum
ture at which a fuel oil can be stored and still be capable of viscosity is limited because some fuel pumps will not perform
flowing under gravitational forces. The pour point is prescribed satisfactorily if the viscosity reaches too low a value. Maxi-
in accordance with the conditions of storage and use. Fuels mum viscosity is limited since too high a viscosity can cause
with higher pour point are permissible where heated storage excessive pressure losses in the piping system, and poor fuel
and adequate piping facilities are provided.
atomization.
X1.4.1.3 Water and Sediments—Appreciable amounts of
water and sediment in a fuel oil tend to cause fouling of the X1.4.1.8 Density alone is of little significance as an indica-
fuel-handling facilities and to give trouble in the fuel system of tion of the burning characteristics of fuel oil. However, when
the gas turbine. An accumulation of sediment in storage tanks used in conjunction with other properties, it is of value in
and on filter screens may obstruct the flow of oil from the tank weight-volume relationships and in calculating the specific
to the combustor of the gas turbine. Water in distillate fuels energy heating value of an oil.
may cause corrosion of tanks and equipment, and water in X1.4.1.9 Sulfur normally burning to sulfur dioxide, also can
residual fuel may cause emulsions. be oxidized partially to sulfur trioxide which then can combine
X1.4.1.4 Carbon residue is a measure of the carbonaceous with sodium and potassium compounds from the ash in the fuel
material left in a fuel after all the volatile components are to form sulfates, pyrosulfates, and such compounds as sodium
vaporized in the absence of air. It is a rough approximation of or potassium iron trisulfate. The pyrosulfates, and the trisul-
the tendency of a fuel to form carbon deposits in the combustor fates have melting points in the operating range of the gas
of the gas turbine. Combustion systems designed for use on turbine. Hence, the compounds produce severe corrosion of the
Grades 3-GT and 4-GT are insensitive to this property, but turbine blading. In general, it has been found impractical to
other gas turbines may require a limit on the carbon residue. To prevent corrosion by limiting the sulfur content of the fuel, so
obtain measurable values of carbon residue in the lighter
corrosion of this type is controlled by limiting the sodium and
distillate fuel oils, it is necessary to remove 90 % of the oil by
potassium. Gas turbines with waste heat recovery equipment
distillation in accordance with Test Method D86, and then
may require additional sulfur control to prevent cold-end
determine the carbon residue concentrated in the remaining
10 % bottoms. corrosion.
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D2880 − 20
X2. SIGNIFICANCE OF FUEL CONTAMINANTS AND TRACE METALS IN FUEL SYSTEMS AND IN FUEL ENTERING TUR-
BINE COMBUSTOR(S)
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D2880 − 20
metals that would probably yield satisfactory service. gas turbine blades. If there is sufficient magnesium in the fuel,
X2.3.6 Sodium and potassium can combine with vanadium it will combine with the vanadium to form compounds with
to form eutectics which melt at temperatures as low as 566 °C higher melting points and thus reduce the corrosion rate to an
and can combine with sulfur in the fuel to yield sulfates with acceptable level. The resulting ash will form deposits in the
melting points in the operating range of the gas turbine. These turbine and will require appropriate cleaning procedures.
compounds produce severe corrosion, and for turbines operat- X2.3.8.1 When vanadium is present in more than trace
ing at gas inlet temperatures above 650 °C additives are not yet amounts either in excess of 0.5 mg ⁄kg or a level recommended
in general use which control such corrosion. Accordingly, the by the turbine manufacturer, it is necessary to maintain a
sodium-plus-potassium level must be limited, but each element weight ratio of magnesium to vanadium in the fuel of not less
is measured separately. Some gas turbine installations incor- than 3.0 in order to control corrosion.
porate systems for washing oil with water to reduce the X2.3.8.2 An upper limit of 3.5 is suggested since larger
sodium-plus-potassium level. In installations where the fuel is ratios will lead to unnecessarily high rates of ash deposition. In
moved by sea transport, the sodium-plus-potassium level most cases, the required magnesium-to-vanadium ratio will be
should be checked prior to use to ensure that the oil has not
obtained by additions of magnesium-containing compounds to
become contaminated with sea salt. For gas turbines operating
the fuel oil. The special requirements covering the addition of
at turbine inlet gas temperatures below 650 °C (1200 °F), the
and type of magnesium-containing additive, or equivalent,
corrosion due to sodium compounds is of minor importance
shall be specified by mutual agreement between the various
and can be further reduced by silicon-base additives. A
high-sodium content is even beneficial in these turbines be- interested parties. The additive will vary depending on the
cause it increases the water-solubility of the deposits and application, but it is always essential that there is a fine and
thereby increases the ease with which gas turbines can be uniform dispersion of the additive in the fuel at the point of
water-washed to obtain recovery of the operating performance. combustion.
X2.3.8.3 For gas turbines operating at turbine inlet gas
X2.3.7 Calcium is not harmful from a corrosion standpoint;
in fact, it serves to inhibit the corrosive action of vanadium. temperatures below 650 °C, the corrosion of the high-
However, calcium can lead to hardbonded deposits that are not temperature alloys is of minor importance, and the use of a
self-spalling when the gas turbine is shut down, and that are not silicon-base additive will further reduce the corrosion rate by
readily removed by water washing of the turbine. The fuel absorption and dilution of the vanadium compounds.
washing systems used at some gas turbine installations to X2.3.9 Lead can cause corrosion and in addition it can spoil
reduce the sodium and potassium level will also significantly the beneficial inhibiting effect of magnesium additives on
lower the calcium content of fuel oil. vanadium corrosion. Since lead is only rarely found in signifi-
X2.3.8 Vanadium can form low melting compounds such as cant quantities in crude oils, its appearance in the fuel oil is
vanadium pentoxide that melts at 691 °C, and causes severe primarily the result of contamination during processing or
corrosive attack on all of the high temperature alloys used for transportation.
X3. GUIDANCE ON EVALUATION OF NEW MATERIALS FOR No. 0-GT, No. 1-GT, AND No. 2-GT GRADES OF GAS TUR-
BINE FUEL OILS
X3.1 The purpose of this appendix is to provide some stakeholders, including that fuels perform appropriately in the
general guidance from Subcommittee D02.E0 on evaluation of specified application.
new materials or blends containing new materials intended to
meet Specification D2880, Grades No. 0-GT, No. 1-GT and X3.3 Historically, gas turbine fuel has been hydrocarbon
No. 2-GT type fuels. molecules refined from petroleum. As a result, Specification
D2880 has evolved to define performance requirements (and
X3.2 ASTM International is an organization made up of tests to determine if those requirements were met) for gas
volunteers and open to all stakeholders and interested entities turbine fuels composed of conventional hydrocarbon oils
including users of fuels, producers of fuels, and general refined from petroleum. Because the specification evolved to
interests, including members of the public, and governmental describe this type of fuel, some of the properties necessary for
and nongovernmental organizations. Technical committees and use in a gas turbines which are inherent in petroleum derived
subcommittees of ASTM International do not certify, approve, oils may not be addressed in Specification D2880.
reject, or endorse specific fuels. Rather, ASTM International
Committee D02 on Petroleum Products, Liquid Fuels, and X3.4 Specification D2880, however, does not require that
Lubricants and its Subcommittee D02.E0 on Burner, Diesel, fuels be derived from petroleum. Subsection 4.1 reads, “The
Non-Aviation Gas Turbine, and Marine Fuels develop fuel grades of gas turbine fuel herein specified shall be hydrocarbon
specifications and, with other subcommittees, test methods for oils with the use of additives to enhance performance
gas turbine fuel oils. These fuel specifications and test methods properties, if required.”
provide minimum requirements for properties of fuels covered
by these documents in commerce and address the concerns of X3.5 It should be noted that fuel specifications other than
7
D2880 − 20
Specification D2880 may be developed for fuel for gas not in the test method’s scope. Chemical and physical limits set
turbines. Other new specifications are under development. in existing standards may or may not be appropriate to the new
Some new materials may require new standard specifications if fuel or components. The new material may also require
they are significantly different than current gas turbine fuels chemical or physical limits that are not appropriate to fuels in
and require different parameters to be controlled or different existing standards. These along with other considerations may
test methods to properly measure required parameters. indicate the need for separate new specifications. Although
each case will require a separate evaluation, logic suggests that
X3.6 Because the composition and properties of new fuels the fewer chemical and physical differences there are between
may vary, the particular path to a specification for a new fuel the new fuel and traditional petroleum-based gas turbine fuel,
may vary. Some current alternative fuels are similar to tradi- the fewer differences in test methods and chemical or physical
tional petroleum-refined fuel oil while others are chemically limits will be needed.
and physically different. Future fuels may vary more than
current fuels. X3.9 If the proponent of the new fuel desires to move
forward via the consensus process as described by ASTM
X3.7 Three areas for consideration when reviewing new bylaws and as implemented in Committee D02, then the
fuels alignment with existing standards or developing new proponent or a task force including the fuel manufacturer or
standards are: test methods, chemical and physical limitations proponent will bring forward ballot revisions to Specification
of fuels in existing specifications, and chemical and physical D2880 or a new specification appropriate for use of the new
limitations appropriate for new fuels. The test methods that fuel or blendstock. Because D02 specifications are established
have been developed for existing gas turbine fuels may or may based on technical data, such data should exist before the
not be appropriate for a new fuel. Guidance on materials used specification process moves forward. If such data does not
to develop a test method, and its applicability, can generally be exist, it needs to be developed.
found in a test method’s scope and precision statements. The
test method may also work for other materials. X3.10 This guidance is not all-encompassing and cannot
replace the judgment and process of a task force and subcom-
X3.8 Applicability of the test method to materials outside its mittee charged with evaluating a new fuel or blendstock.
scope may be established by the subcommittee responsible for However it may give some guidance to proponents or fuel
the method. Also, Subcommittee D02.E0, during the specifi- manufacturers who are considering participation in ASTM
cation development process, may determine that a test method Committee D02 and its subcommittees to promote the inclu-
is applicable for specification purposes, even if the material is sion of their new fuel or blendstock in ASTM standards.
SUMMARY OF CHANGES
Subcommittee D02.E0 has identified the location of selected changes to this standard since the last issue
(D2880 – 18a) that may impact the use of this standard. (Approved May 1, 2020.)
(1) Added Test Method D7945 to Section 2. (2) Revised subsection 6.1.7.
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