(Final Answer Keys With Solutions) AYJR 2024 (April) - Morning Shift
(Final Answer Keys With Solutions) AYJR 2024 (April) - Morning Shift
(Final Answer Keys With Solutions) AYJR 2024 (April) - Morning Shift
Q1
A heavy nucleus splits into two fragment nuclei whose surface area are in ratio 9 : 25, the ratio of speeds of the
two fragments is
(1) 25 : 9
(2) 125 : 27
(3) 5 : 3
(4) 625 : 81
Q2
(1) λ 1 = √ λ2
(2) λ 1 < λ2
(3) λ 1 = λ2
(4) λ 1 > λ2
Q3
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In the following circuit, if D and D are ideal diodes, then the value of i and i are respectively
1 2 1 2
(2) 5 mA, 5 mA
(3) 5 mA, Zero
(4) Zero, 5 mA
Q4
A ray of light travels from a medium of refractive index μ to air. Its angle of incidence in the medium is θ,
measured from the normal to the boundary and its angle of deviation is δ and the angle of refraction ϕ. A graph
is plotted between δ and θ which is shown in the figure. Choose the correct relation from the following-
(1) δ2
δ1
= μ
(2)
δ2
= 2
δ1
(3) sin ϕ = 1
(4) ϕ = π
2
− sin
−1
(
1
π
)
Q5
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If all meters are ideal and the reading of the voltmeter V is 6 V, then power supplied by the voltage source is
This question is a bonus. Regardless of whether you attempted it or not, you have been awarded +4 marks,
which reflects in both your Physics and overall scores of the paper.
(1) 10 W
(2) 38 W
(3) 54 W
(4) 30 W
Q6
A body is moving down a long inclined plane of inclination θ. The coefficient of friction between the body and
inclined plane varies as μ = 0.5x, where x is distance travelled down the plane. The body will have maximum
velocity, when it has travelled a distance x, given by (All quantities are in SI units)
(1) x = 2 tan θ
(2) x = 2
tan θ
(3) x = √2 cot θ
√2
(4) x = cot θ
Q7
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The escape velocity from a spherical planet is v . The escape velocity corresponding to another planet of twice
e
(1) v e
√2
(2) ve
√2
(3) 2v e
(4) 4v e
Q8
In a sample of hydrogen like atoms all of which are in ground state, a photon beam containing photons of
various energies is passed. In absorption spectrum, five dark lines, are observed. The number of bright lines in
the emission spectrum will be (assume that all transitions takes place).
(1) 5
(2) 10
(3) 15
Q9
A capacitor, an inductor and an electric bulb are connected in series to an AC supply of variable frequency. As
the frequency of supply is increased gradually, then the electric bulb is found to
Q10
In a cyclic process ABCA, V − T graph is shown in the figure. P − V graph corresponding to the given
process can be best depicted by
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(1)
(2)
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(3)
(4)
Q11
Two particles A and B are projected simultaneously from point O. Their maximum heights and ranges
achieved are shown. Find correct option :
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Q12
In the equation ∫ dv
3/2
= BCe
−2Ct
, where v is velocity, t is time, e is exponent. The dimensions of B are
v
1 3
(1) [L −
2 T 2 ]
(2) [L 2
T
−
2 ]
1 5
(3) [L −
2 T 2 ]
1 5
(4) [L −
2 T
−
2 ]
Q13
Two ideal gases, one monoatomic and another diatomic, are having same pressure P , volume V and
temperature T . Select the correct option
(1) The translational kinetic energy for monatomic gas is but for diatomic gas it is .
3 5
PV PV
2 2
(2) The translational kinetic energy for both monatomic and diatomic gas will be same.
(3) Average velocity of each molecule of any type of gas will be proportional to √T , where T is absolute 5
temperature.
(4) Average energy for one molecule per degree of freedom for monatomic gas is but that for diatomic it
1
kT
2
is 2 × .
1
kT
2
Q14
A ball of mass 20 g dropped over a large horizontal surface from a height of 5 m, collides elastically with the
surface. If the collision lasts for 10 −2
s , then which of the following statement is true? (g = 10 m/s 2
)
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Q15
A uniform rod of mass 6 kg is lying on a smooth horizontal surface. Its two ends are pulled by strings as
shown in figure. Force exerted by 40 cm part of the rod on 10 cm part of the rod is
(1) 30 N
(2) 16 N
(3) 24 N
(4) 22 N
Q16
(1) 5005 J
(2) 2750 J
(3) 3750 J
(4) 17.5 J
Q17
The 9 th
division of vernier scale coincides with 6 th
division of main scale in a vernier calliper. If one main
scale division is 0.01 mm, then the least count of instrument is
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(1) 0.01 mm
(2) 0.001 mm
(3) 0.0033 mm
(4) 0.0066 mm
Q18
40 g of ice at −10 ∘
C is dropped in a calorimeter having 50 g water at 40 ∘
C . The final temperature of mixture
and content of calorimeter are (Specific heat of ice 0.5calg −1 ∘
C
−1
, latent heat of fusion of ice 80calg ,−1
(1) 0 ∘
C, 40 g ice and 50 g water
(2) 0 ∘
C, 90 g water
(3) 0 ∘
C, 17.5 g ice and 72.5 g water
(4) 0 ∘
C, 20 g ice and 65 g water
Q19
2
from the centre of an uncharged conducting spherical shell as
shown in below figure. The electric field at a distance 3R from the point charge is
Q
(1)
1
2
4πε0 9R
Q
(2)
1
4πε0 2
5R
( )
2
Q
(3)
1
4πε0 2
7R
( )
2
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4πε0 2
9R
( )
2
Q20
Match List-I (Electromagnetic wave type) with List-II (Its Application) and select the correct option from the
choices given below the lists:
List-I List-II
Q21
A dog is barking at a power of 40πmW. Its intensity level of sound emitted at a distance 1 m from the dog is
(in dB)
Q22
A uniform circular disc of radius R placed on a rough horizontal surface has initially a velocity v and an
0
angular velocity ω as shown in the figure. If the disc comes to rest after moving some distance in direction of
0
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Q23
Two solid spheres of same metal but of mass M and 8M fall simultaneously on a viscous liquid and their
terminal velocities are v and nv, then find the value of n.
Q24
In an experiment four quantities a, b, c and d are measured with percentage error 2%, 3%, 1% and 0.5%
√
respectively. A quantity Q is defined as Q = . Maximum percentage error in the calculation of Q will be
a b
3/2 4
c d
Q25
Three blocks of masses 700 g, 500 g and 400 g suspended at the end of a spring as shown in the figure, are in
equilibrium.
When the 700 g block is removed, the system has a period of oscillations of 3 s. If both 700 g and 500 g blocks
are removed, the period of oscillation becomes (in seconds)
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Q26
A beam of plane polarized light falls normally on a polarizer of cross sectional area 3 × 10 −4
m
2
. Flux of
energy of incident ray is 10 −3
W . The polarizer rotates with an angular frequency of 31.4rad/sec. The average
Intensity is K watts. Find 6 K.
Q27
Two square shaped metal plates of A and B of same thickness ( t ) and of same material are connected as
shown in the figure. The side of B is twice that of A. If the resistance of A and B are R and R respectively
A B
RA
then RB
is
Q28
The primary and secondary coils of an ideal transformer have 100 and 500 turns respectively. The magnetic
flux linking the primary coil is given by ϕ = 40t + 5. The output voltage across the secondary coil is (all the
quantities are in SI units)
Q29
Two small spheres of each charge q, mass m and material density d are suspended from a fixed point with the
help of inextensible light thread. When the spheres are in air, the angle between the threads is 90 . When the ∘
3
d , the angle between the threads is 60 . The value of dielectric
∘
Q30
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→
point is E = ^
i + ^ ^
j + k . The magnetic field produced at the same point due to the same charged particle is
Kμ0 ε0 . Find the value of 10K. (All quantities are in S.I. units, take √2 = 1.4 and √3 = 1.7)
Q31
What is the correct mode of hybridization of the central atom in the following compounds : NO +
2
, SF4 , PF
−
(1) sp 2 3
, sp , d sp
2 3
(2) sp 3 3 2
, sp d , sp d
3 2
(3) sp, sp 3
d, sp d
3 2
(4) sp, sp 2
, sp
3
Q32
(1) NH 3
> PH3 > AsH3 > SbH3 (order of acidic strength)
Q33
An element with (Z = 69) emits 2α and 1β particles in succession. What will be the group number of new
element formed?
(1) Group 2
(2) Group 13
(3) Group 5
(4) Group 3
Q34
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Which of the following set of reagent(s) give cis-but-2-ene as a final major product starting with (+)-2-
chlorobutane.
(4) (i) Alc. KOH, (ii) Br 2 /CCl4 , (iii) Alc. KOH; NaNH , (iv) Na/ Liq. NH
2 3
Q35
is
Q36
(1) Statement 1 is True, Statement 2 is true; Statement 2 is a correct explanation for Statement 1
(2) Statement 1 is True, Statement 2 is true; Statement 2 is NOT a correct explanation for Statement 1
(3) Statement I is True, Statement 2 is False
(4) Statement 1 is False, Statement is True
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Q37
The first and second ionisation potential of helium atoms are 24.6eV and 54.4eV respectively. The energy
(1) 758.4
(2) 7584
(3) 7.584
(4) 75.84
Q38
Assertion : Azeotropic mixtures are formed only by nonideal solutions and they may have boiling points either
greater than both the components or less than both the components.
Reason : The composition of the vapour phase is same as that of the liquid phase of an azeotropic mixture.
(1) both assertion and reason are true and the reason is the correct explanation of the assertion.
(2) both assertion and reason are true but reason is not the correct explanation of the assertion.
(3) assertion is true but reason is false.
(4) the assertion and reason both are false.
Q39
Q40
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Which common factor is responsible for the regioselective nature of the following reactions.
Q41
Amongst TiF 2−
6
, CoF
3−
6
, Cu2 Cl2 and NiCl 2−
4
(Atomic number
T i = 22, Co = 27, Cu = 29, N i = 28) . The colourless species are
(1) CoF 3−
6
and NiCl 2−
(2) TiF 2−
6
and CoF 3−
(3) Cu 2
Cl2 and NiCl 2−
(4) TiF 2−
6
and Cu 2
Cl2
Q42
−2 +2
[PdCl4 ] [Ni(NH3 ) ]
4
(S) (T)
(1) P, T
(2) P, Q, T
(3) R, S, T
(4) P, S
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Q43
∘ ∘
E +3 = 1.50 V, E + = −3.03 V
Au /Au Li /Li
with increasing voltage, the sequence of deposition of metals on the cathode will be :
Q44
(1) 10
(2) 12
(3) 13
(4) 14
Q45
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Q46
(1) [Ni(CN) 4]
−2
and [Ni(CO) ] have the same magnetic moment
4
(2) [NiCl 4]
−2
and [PtCl 4]
−2
have different shape.
Q47
Product (A) is -
(1)
(2)
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(3)
(4)
Q48
How many hydrogen atoms are replaced by deuterium atoms in the major product?
(1) 1
(2) 0
(3) 4
(4) 3
Q49
Chromyl chloride vapours are dissolved in NaOH and acetic acid and lead acetate solution is added, then
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Q50
On performing a borax-bead test with a given inorganic mixture for qualitative analysis, the colour of the bead
was found to be emerald green both in oxidising and reducing flame. It indicates the possibility of the presence
of
(1) Co
(2) Ni
(3) Cr
(4) Cu
Q51
Find the total number of compounds which do not give Fehling's test.
Fructose, Sucrose, Glyoxal, HCHO, glyoxalic acid, CH 3 COCH3 ,N 2 H4 , benzaldehyde, HCOOH
Q52
4
, C2 O
−2
4
, H for the balanced reaction are respectively 2, a and b.
+
Find a + 2b.
Q53
Find the number of spectral lines in Paschen series emitted by atomic H, when electron is excited from ground
state to 7 th
energy level returns back.
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Q54
A weak base BOH was titrated against a strong acid. The pH at 1/4 th equivalence point was 8.0 . Enough
strong base was now added (7.5 millimole) to completely convert the salt. The total volume was 10ml. Find
the pOH at this point.
Q55
Total number of possible stereoisomers of the following co-ordinate compound Mabcdef where - a, b, c, d, e
and f are mono dentate ligands.
Q56
A tetrapeptide on hydrolysis produced glycine (gly), Leucine (Leu.), Alanine (Ala), Valine (Val.). Count
number of possible tetrapeptides (structural isomers only) which can produce above four amino acids with the
following both conditions.
(i) Glycine is not present at N-terminal
(ii) Alanine in present at C-terminal
Q57
Find the difference between the number of optically active and optically inactive isomers of
Q58
0.02M and in 0.25 millisecond when the concentration is 0.04M, what is the order of the reaction?
Q59
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major organic product will have Bromine at ______ position. (Mark carbon number where boron will be
attached as answer.)
Q60
−1 −1
400 kJ mol C − H C(g) 700 kJ mol
−1 −1
350 kJ mol C − C H(g) 200 kJ mol
−1 −1
700 kJ mol C = O O(g) 250 kJ mol
Q61
Let x be the 7 th
term from the beginning and y be the 7 th
term from the end in the expansion of
n
(1) 9
(2) 8
(3) 10
(4) 11
Q62
Let a and b are positive integers such that a < b < 2009. If a, b and 2009 form a geometric progression whose
common ratio is an integer then the sum of digits of a is
(1) 5
(2) 7
(3) 9
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(4) 11
Q63
−9
Suppose a parabola has vertex ( 1
4
,
8
) and equation y = a 2
+ bx + c (where a > 0 and a + b + c is integer).
Let 'a' takes its minimum possible value under given condition, then
Match List-I with List-II and select the correct answer using the code given below the list.
List-I List-II
2
(Q) If equation of directrix is 4y + λ = 0, then λ is (2) 81
p
(R) If the value of a is (where p & q are relatively prime), then p + q is (3) 11
q
2
1
(S) If (α, 0) lies on parabola, then 16(α − ) is (4) 36
4
P Q R S
(1)
1 2 3 4
P Q R S
(2)
3 1 2 4
P Q R S
(3)
1 2 3 2
P Q R S
(4)
4 1 2 3
Q64
24√3
(2) 13
16√3
(3) 13
48√3
(4) 13
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Q65
2 × 2 and B be a matrix such that B = f (A), then which of the following must be INCORRECT?
Q66
A light beam emanating from the point A(3, 10) reflects from the straight line 2x + y − 6 = 0 and then passes
through the point B(4, 3). The equation of the reflected beam is x + 3y − λ = 0, then find the value of λ.
(1) 22
(2) 11
(3) 9
(4) 13
Q67
→| = |→b| = 1 and |a
Given |a → + →b| = √3. If c→ be a vector such that c→ − a
→ − 2→b = 3(a
→ × →b), then c→ ⋅ →b is equal to
(1) − 1
(2)
1
(3) 3
(4)
5
Q68
6−3x x−1
The domain of f (x) = cos −1
(
4
) + cosec
−1
(
2
) is
(1) [3,
10
]
3
(2) [ 2
3
,
10
3
]
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Q69
In a right trapezium ABCD, the diagonals are perpendicular, and the ratio of the length of bases
(1) 3 : 2
(2) 1 : 3
(3) 2 : √3
(4) √3 : √2
Q70
The number of integers in the range of 'c' such that there exists a line which intersects the curve
y = x
4
− 6x
3
+ 12x
2
+ cx + 1 at four distinct points is equal to
(1) 2
(2) 3
(3) 1
(4) 0
Q71
|f (x)−x| 3 |f (y)−y| 3
4
, is
3f (4)
(1) 4
sq. units
f (4)
(2) 8
sq. units
f (4)
(3) 16
sq. units
3f (4)
(4) 16
sq. units
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Q72
48
⋅ cos
π
48
⋅ cos
π
24
cos
π
12
⋅ cos
π
6
.
(1) 6
(2) 18
(3) 12
(4) 9
Q73
8
and 1
12
respectively. Given that they obtain
the same answer after solving a problem and the probability of a common mistake by them is , then
1
1001
probability that their solution is correct is (Assuming that if they commit different mistake then their answers
will differ)
(1)
77
96
(2)
14
15
(3)
2
(4)
13
14
Q74
x
Let f (x) be continuous function satisfying f (x) = ∫ 0
e
x−y ′
f (y)dy − (x
2
− x + 1) e
x
. The value of x for
(1)
1
(2) 1
(3)
1
(4) 1
Q75
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If the equation of the perpendicular bisector of the line joining two complex numbers P (z 1) and Q (z 2) in the
complex plane is ᾱz + αz + r = 0 then α and r are respectively are
¯
¯¯
(1) z and |z
2 2
2 − z1 1| + |z2 |
(2) z 1 − z2 and |z 1|
2
− |z2 |
2
(3) z̄ and |z
2 2
2 − z̄ 1 1| + |z2 |
(4) z 2 − z1 and |z 1|
2
− |z2 |
2
Q76
Let f : R → R be a polynomial function satisfying f (f (x) − 2y) = 2x − 3y + f (f (y) − x), ∀x, y ∈ R then the
value of f (20) − f (14) is equal to
(1) 6
(2) 4
(3) 5
(4) 8
Q77
A be a square matrix of order 2 with |A| ≠ 0 such that |A| + |A adj(A)| = 0, where adj(A) is an adjoint of
(1) 6
(2) 4
(3) 5
(4) 8
Q78
⎧ x[x] + 1 , x ∈ (0, 1)
⎪
Let f (x) = ⎨ ax
2
+ x + b , x ∈ [1, 3)
⎪
⎩
sin(c(x − 3)) + d , x ∈ [3, ∞)
(where [.] denotes greatest integer function) be a continuous function in its domain.
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If f (x) is continuous but non-differentiable at exactly two points in its domain, then-
(1) a ≠ − 1
2
, c ≠ 2, a = −b =
d−3
(2) a ≠ −2, c ≠ −
1 d+3
, a = −b =
2 8
(3) a = − 1
2
, c ≠ −2, a = b =
d−3
(4) a ≠ −
1 d−3
, c ≠ −2, a = −b =
2 8
Q79
2 π
2 x sin x cos( cos x)dx
π/2
If I and I , then (I equals
cos xdx π 2
1
= ∫ x 2
= ∫ 1
+ I2 )
−π/2 1+3 0 (2x−π)
(1) π
4
+ 1
(2) π
(3) 3π
(4) π
4
+ 2
Q80
The distance from the point P whose position vector is −^i + 2^j + 6k
^ to the straight line through R(2, 3, −4)
(1) 6
(2) 7
(3) 5
(4) 8
Q81
If a point P (x, y) moves such that |x − y| + |x + y| = 2, then the area bounded by the locus of the point P is
equal to
Q82
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AB is a chord of x 2
+ y
2
= 4 and P (1, 1) trisects AB. If C is the centre of the circle then the length of the
chord AB is
Q83
A relation R is defined on set A = {a, b, c} such that R ≡ {(a, a), (b, b), (b, c), (c, b)}, then minimum
Q84
to be wrong and was replaced by the correct value 30 then the corrected variance is
Q85
5
.
.
.
5
Q86
The number of four digit numbers abcd where a, b, c, d ∈ {1, 2, 3, 4, 5, 6, 7, 8, 9} such that a > b, a > c and
c > d , is
Q87
A line with direction ratios (2, 1, 2) intersects the lines r→ = −^j + λ(^i + ^j + k) → = −^i + μ(2^i + ^j + k)
^ and r ^
Q88
If AM, GM and HM of the first and last terms of series 100, 101, 102, … … (n − 1), n are the terms of series
Q89
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2
) (x +
1
2
) +
1
αβ
) dx is √ a
b
+ c where a, b, c ∈ N , then the least value of
α β
(a − b + c) is
Q90
If the area bounded by y = f (x) and the curve y = where f is a continuous function satisfying the
2
2
1+x
3
) , then a =
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Answer Key
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Q1
2
S1 r1 9
= ( ) =
S2 r2 25
r1 3
⇒ =
r2 5
3
m1 A1 r1 27
⇒ = = ( ) =
m2 A2 r2 125
→
Now |p i | = ∣ ∣
∣p f ∣ →
⇒ m 1 v1 = m 2 v2
v1 m2 125
= =
v2 m1 27
Q2
hc
eV = − ψ
λ
hc
eV1 = − ψ
λ1
hc
eV2 = − ψ
λ2
∵ eV2 > V1
λ1 > λ2
Q3
i1 = 0
10
i2 = = 5 mA
3
2 × 10
Q4
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θ < C
δ = ϕ − θ
θ = C
π
δ = − C
2
π
δ =
2
θ > C
δ = π − 2θ
sin ϕ −1
μ = , ϕ = sin (μ sin θ)
sin θ
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∴δ2 = 2δ1
Q5
2 2
6 6 3 108
P = + = 36 × = = 54W
10 20 20 20
Q6
1 sin θ
x =
0.5 cos θ
x = 2 tan θ
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Q7
2Gm 8 2
ve = √ = √ πGR ρ
R 3
v e ∝ R√ ρ
ve R √ρ
=
v 2R ρ
√
2
v = ve √2.
Q8
Q9
Q10
Q11
HA = 2HB
& TA = √ 2 TB
2ux uy
Re = so R1 = R2 if
g
uxB = √2uxA
Q12
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dv
and = BC
3/2
v
1 −1
[L T ]
0 0 −1
= B [M L T ]
3/2
1 −1
[L T ]
1 3
−
B = [L 2 T2 ]
Q13
3
ETrans = PV
2
Q14
v = u
−3
= 2 × 20 × 10 √2 × 10 × 5
−3
= 400 × 10 = 0.4 N − s
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FΔt = 0.4
0.4
F = −2
= 40 N
10
Q15
F1 −F2
Acceleration a = M
=
30
6
= 5 m/s
2
Now,
T − F2 = ma
T = F2 + ma
= 10 + 1.2 × 5 = 16 N
Q16
2 2
(500) = (1000) − 2 × a × s
2 2
(1000) −(500) 375000
s = =
2a a
10 375000
= a ×
1000 a
= 3750 J
Q17
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2
⇒ 1VSD = MSD
3
2
⇒ 1VSD = (0.01 mm)
3
2
⇒ L.C. = 0.01 mm − (0.01)mm
3
0.01
= mm = 0.0033 mm
3
Q18
= 40 × 0.5 × 10 + 40 × 80
Minimum heat required > Maximum heat loss so whole ice will not
m × 80 = 1800
1800
m = = 22.5 g
80
Q19
The field at point P due to charge Q within the shell and charge induced on the inner surface of the shell is
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zero. The field at point P is only, due to the induced charge on the outer surface of shell.
1 Q 1 Q
∴ E = =
4πε0 2 4πε0 2
R 7R
[3R+ ] ( )
2 2
Q20
The correct match of application of EM waves as per NCERT IS a(I). b(II), c(III). d(IV)
Q21
−3
40π × 10 −2
I = = 10 W
2
4π × (1)
−2
I 10
L = 10 log( ) = 10 log10 ( )
−12
I0 10
L = 100 dB
Q22
Q23
3
M1 r1
= ( )
M2 r2
1/3
r1 M 1
= ( ) =
r2 8M 2
2 (ρ − σ)g
2
VT = r
9 η
2
VT ∝ r (ρ, σ, η = constant )
2
V1 r1
= ( )
V2 r2
2 2
V r1 1 1
= ( ) or = ( )
nV r2 n 2
n = 4
Q24
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3 3
= (2 + + + 2) %
2 2
= 7%
Q25
−3
(700 + 500 + 400 − 700) × 10
= 2π√
k
But T
′
= 3 s
0.9 2 0.9
∴ 3 = 2π√ ⇒ 9 = 4π ×
k k
⇒ k = 0.4π
2
...(i)
When both blocks of 700 g and 500 g are removed, then period of oscillation is given as
−3
(700+500+400−700−500)×10
′′
T = 2π√
k
0.4
= 2π√ 2
0.4π
2π
= = 2 s
π
Q26
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I0
On integration we get I av =
2
−3
Energy p
where I 0 =
Area × Time
= =
10
−4
=
10
3
Watt
2
A 3×10 m
1 10 5
∴ Iav = × = W att = K
2 3 3
6K = 10
Q27
LA = L and L B = 2 L then A A
= A and A B = 2A By the formula of resistance
ρL
R =
A
RA L A AB L 2A
= = × = 1
RB L B AA 2L A
Q28
dϕ d
|VP | = = (40t + 5) = 40 V
dt dt
VS NS
Now VP
=
NP
500
VS = 40 × = 200 V
100
Q29
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r = 2l cos θ
Fe
tan θ =
mg
[from Fig.]
So, for θ = 45 and ϕ = 45 ∘ ∘
2
2l Kq
r = = √2l ⇒ Fe =
v2 2l
2
kq
∘ ∘
tan 45 = (∵ tan 45 = 1)
2lmg
For, θ = 30 and ϕ = 60 ∘ ∘
1
r = 2l × = l
2
2 ′ 2
kq k q
So , F e
′
=
2
⇒ tan 30
∘
=
2 ′
l l −m g
3
d , then the observed weight of the body,
′ 2d m
m = V (d − ) = [∵ m = V ⋅ d]
3 3
⇒ εr = 6√3
Q30
→
q(v × r ) →
→
B =
μ0
4π r3
→ →
B = μ0 ε0 (v × E) = μ0 ε0 (−^
i + ^
^
j − k) × (^ →
i + ^
^
j + k)
→
B = 2(^
^
i − k)μ0 ε0
B = 2√2μ0 ε0
K = 2√2 = 2.80
Q31
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+
NO sp
2
3
SF4 sp d with one lone pair of electron
− 3 2
PF sp d
6
Q32
Q33
Atomic mass of Z decreases by 8 and atomic number decreases by 3 units. So new atomic number is 66 which
belongs to lanthanide series. So new group number = 3
Q34
Q35
Q36
When mercuric iodide is added to aqueous solution of KI the freezing point of the given solution increases.
Mercuric Iodide will react with Potassium Iodide to form a complex as follows:
2KI + Hgl2 → K2 HgI4
4 ions
3 ions
This will decrease the number of ions in the solution and so Van't Hoff factor decreases which depend on the
number of particles.
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Q37
IE1 ⟶ 24.6eV
IE2 ⟶ 54.4eV
He ⟶ (IE + IE2 )
1
2+
He
= 24.6 + 54.4eV
= 79.0eV
−22 23
In kJ → 79.0 × 1.6 × 10 × 6 × 10
= 7584 kJ
Q38
Non-ideal solutions with positive deviation i.e., having more vapour pressure than expected, boil at lower
temperature while those with negative deviation boil at higher temperature than those of the components.
Q39
Q40
Regioselective ⇒ Preference of a chemical reaction to form one positional isomer over another.
∴ +M effect of halogen is responsible in all reactions.
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Q41
2−
TiF and Cu2 Cl2 due to absence of unpaired electrons.
6
Q42
−2
[Ni(CN)4 ]
+2 0 8
Ni = [Ar]4 s 3 d
−2
[PdCl4 ]
2
dsp
Q43
Only Au +3
, Ag
+
and Cu +2
will deposit at cathode. Li will not deposit at cathode because SRP of H is 0.00 V,
2
so after Cu +2
, H2 will evolve at cathode.
Q44
Q45
Aniline is steam volatile and B.P. of aniline is 184C , So impurities are easily separated by steam distillation,
∘
Q46
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+3 0 6
Co = [Ar]4 s 3 d
Q47
Q48
Q49
NaOH CH3 COOH
CrO2 Cl2
yellow ppt.
Q50
Chromium ion gives in hot and cold. Oxidising and reducing flame green-colour.
Q51
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Q52
Q53
n = 7 → n = 1
↓ ↓ ↓ ↓
3 3 3 3
4 lines
Q54
1 3a a
At eq.
4 4 4
Basic buffer
[BCl]
pOH = pK + log
b
[BOH]
a/4
6 = pKb + log
3a/4
pKb = (6 + log 3)
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a/4 3a/4
Q55
Q56
V − G − L − A
L − G − V − A
L − V − G − A
Q57
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Q58
1 milli sec
= k(0.02)
n
...(i)
0.01 × 0.04 n
= k(0.04)
0.25 millisec
n
(1) 0.02 × 0.25 0.02
⇒ = ( ) ⇒ n = 3
(2) 0.04 0.04
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Q59
Q60
1
2C + 2H2 + O2 ⟶ CH3 CHO
2
1
= [(2 × 700) + (2 × 400) + ( × 500)] − [(4 × 400) + (250 × 1) + (700 × 1)]
2
= 2450 − 2650
= −200 kJ/mol
Q61
n−6 6
n 1/3 −1/3
x = T7 = C6 (3 ) ⋅ (4 )
6 n−6
n 1/3 −1/3
y = Tn−5 = Cn−6 (3 ) ⋅ (4 )
⇒ y = 12x
6 n−6
n 1/3 −1/3
Cn−6 (3 ) (4 )
n−6 6
n 1/3 −1/3
= 12. C6 (3 ) ⋅ (4 )
12−n
1/3
⇒ 12 = (12 ) ⇒ n = 9
Q62
2
b 2009 +
b = a.2009 ⇒ = = r ∈ I
a b
2
b 41 × 7
+
r = = ∈ I a, b > 0
a b
∴ r = 7, a = 41, b = 287
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Q63
b 1
− =
2a 4
a = −2b
2
b − 4ac 9
=
4a 8
2
a 9a
− 4ac =
4 2
a 9
− 4ac =
4 2
a = 18 + 16c
a a − 18 9a − 18
a + b + c = a − + =
2 16 16
2
a =
9
1
b = −
9
10
c = −
9
Hence parabola is
2
1 9 9
(x − ) = (y + )
4 2 8
Q64
2
We have x
4
+ y
2
= 1 ...(i)
⇒ y = √3x + 1 … (ii)
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2
⇒ 13x + 8√3x = 0
8 √3
⇒ x = 0 or x = −
13
8 √3
Putting x = − 13
in (ii), we get
2
x
2
+ (√3x + 1) = 1
4
2 2
⇒x + 4 (3x + 1 + 2√3x) = 4
2
⇒ 13x + 8√3x = 0
8√3
⇒ x = 0 or x = −
13
8
Putting x = − in (ii), we get
13
8√3 24 11
y = −√3 ( ) + 1 = 1 − = −
13 13 13
8 √3
Hence B ≡ (− 13
,−
11
13
)
8 √3 11
∴ C ≡ ( ,− )
13 13
16√3
∴ BC =
13
Q65
1 −10
If A = [ ] , then its
3 2
Charactertistic equation is
∣x − 1 −10 ∣
∣ ∣ = 0
∣ −3 x − 2∣
⇒⇒ x
2
− 3x + 33 = 0 , which is no real root.
Q66
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x − 3 y − 10 6 + 10 − 6
= = −2 ( )
2 2
2 1 2 + 1
x − 3 y − 10
= = −4
2 1
′
A = (−5, 6)
6−3
Equation of A B is y − 3 = ( ′
−5−4
) (x − 4)
1
⇒ y − 3 = − (x − 4)
3
3y − 9 = −x + 4
⇒ x + 3y − 13 = 0
Q67
→ →
|a + b| = √3, |a + b| → → 2
= 3
→ →
1
⇒ a ⋅ b =
2
→ − 2→b = 3(a
Now, c→ − a → × →b)
⇒ → → → →
(c − a − 2 b) ⋅ b = 3{(a × b) ⋅ b} → → →
⇒ → → → →
c ⋅ b − a ⋅ b − 2( b ⋅ b) = 0
→ →
→ →
1
⇒ c ⋅ b − − 2 × 1 = 0
2
→ →
5
⇒ c ⋅ b =
2
Q68
6−3x x−1
−1 −1
f (x) = cos ( ) + cosec ( )
4 2
6−3x
For cos −1
(
4
)
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⇒ −4 ≤ 6 − 3x ≤ 4
⇒ −10 ≤ −3x ≤ −2
x−1
For cosec −1
(
2
)
x − 1 x − 1
≤ −1 or ≥ 1
2 2
⇒ x ≤ −1 or x ≥ 3 … (ii)
10
From (i) and (ii), x ∈ [3, ]
3
Q69
−
−→ −
−→
AC ⋅ BD = 0
→ → → 2 →
⇒ ( c − a ) ⋅ ( a + c ) = 0
3
2 → 2 → 2 → →
⇒ | c | − | a | = 0 (∵ a ⋅ c = 0)
3
→ 2 2 → 2
⇒ | a | = | c |
3
−
−→ −
−→ → → ∣→ 2 →∣
Now |AC| : |BD| = | c − a | : ∣ a + c ∣
∣ 3 ∣
2 2 2
4 2
= √c + a : √a + c = √3 : √2
9
Q70
4 3 2
∵ y = x − 6x + 12x + cx + 1
dy
3 2
⇒ = 4x − 18x + 24x + c = g(x)
dx
2
d y
2
and = 12x − 36x + 24 = 12(x − 1)(x − 2)
2
dx
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∴ Number of integers = 1.
Q71
f (x + y) f (x − y)
2 2
− = (x + y) − (x − y)
x + y x − y
f (u) f (v)
2 2
− = u − v
u v
f (u) f (v)
2 2
⇒ − u = − v = c
u v
3
∴ f (u) = cu + u
f (1) = 2 ⇒ c = 1
3
⇒ f (x) = x + x
1 1
|f (x) − x| 3 |f (y) − y| 3 1
∴ + ≤
17 2 4
|x| |y| 1
becomes + ≤
17 2 4
1 17 1 17 f (4)
∴ Area = 4 ⋅ ( )( )( ) = =
2 4 2 4 16
Q72
2 3
π π 2π 2 π 2 π
96√3 sin ⋅ cos ⋅ cos ⋅ cos cos
48 48 48 48 48
4 π
sin 2
π 48
= 96√3 ⋅ sin
π
48 24 ⋅ sin
48
96√3 π 96√3 × √3
= × sin = = 9.
16 3 16 × 2
Q73
96
If E be the event of both getting correct solution and E be the event that both gets wrong solution
1 1
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Q74
1
∴ f (x) = 0 at x =
2
Q75
− z1 z̄ + z1 z̄ 1 = −zz̄ 2 − z2 z̄ + z2 z̄ 2
2 2
z (z̄ 2 − z̄ 1 ) + (z2 − z1 ) z̄ + |z1 | − |z2 | = 0
or ᾱz + αz̄ + r = 0
2 2
⇒ α = z2 − z1 and r = |z1 | − |z2 |
Q76
Let f (x) = a 0
x
n
+ a1 x
n−1
+ a2 x
n−2
+ an
Putting in given equation and comparing coefficients of powers of x, we get f (x) = x + b. where b is constant
∴ f (20) − f (14) = 6
Q77
a b a −b
Let A = [ ] and |A| = k⋅, adj(A) = [ ]
c d −c a
∣ a + kd b − kb ∣
Now |A + |A| adj(A)| = ∣ ∣ = 0
∣ c − kc d + ka ∣
2 2 2 2
⇒ ad + k ad + k (a + d ) − bc − k bc + 2kbc = 0
2 2
⇒ (ad − bc) (1 + k ) + k ((a + d) + 2bc − 2ad) = 0
2 2
⇒ (k) (1 + k ) + k ((a + d) − 2k) = 0
2 2
⇒ 1 + k + (a + d) − 2k = 0(∵ k ≠ 0)
2 2
⇒ (a + d) + (k − 1) = 0 ⇒ a + d = 0, k = 1
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2 2
= (adj − bc) (1 + k ) − k ((a + d) − 2k)
2 2
= (k) (1 + k ) − k ((a + d) − 2k)
= (1)(2) − (1)(−2) = 4
Q78
−
⇒ f (1 ) = 1
+
f (1 ) = f (1) = a + 1 + b
− +
f (3 ) = 9a + 3 + b; f (3 ) = d
a + b = 0; 9a + b + 3 = d
⇒ 8a + 3 = d
Also
′ − ′ +
f (1 ) = 0; f (1 ) = 2a + 1
′ − ′ +
f (3 ) = 6a + 1; f (3 ) = c
1
′ ′ +
f (1) ≠ f (1 ) ⇒ a ≠ − ⇒ 6a ≠ −3
2
& c ≠ 6a + 1
c ≠ −2
Q79
2 π
π x sin x cos( cos x)dx
2
I2 = ∫
0 (2x − π)
2 2
π π π π
⎡ ( − x) cos x cos( sin x) ( + x) cos x cos( sin x) ⎤
π/2
2 2 2 2
I2 = ∫ ⎢ + ⎥ dx
⎢ ⎥
0
−2x 2x
⎣ ⎦
π/2
π π
= 2∫ cos x cos( sin x)dx
0
2 2
π/2
π
= 2∫ cos θ ⋅ dθ = 2 [Let sin x = θ]
0
2
π/2
cos 2
I2 = ∫ xdx
x
−π/2
1 + 3
π/2 π/2
1 2 2
I2 = ∫ cos xdx = ∫ cos xdx
2 −π/2 0
π
I1 =
4
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Q80
−
−→
Given: OP = −^i + 2^j + 6k
^
−
−→
OR = 2^
i + 3^ ^
j − 4k
|(3^
i + ^ ^ × (6^
j − 10k) i + 3^ ^
j − 4k)|
=
^
|6^
i + 3^
j − 4k|
∣^i ^
j ^
k ∣
∣ ∣
∣3 1 −10 ∣
∣ ∣
∣6 3 −4 ∣
=
2
√62 + 32 + 4
2 2 2
26 + 48 + 3
= √
36 + 9 + 16
2989
= √ = √49 = 7
61
Q81
|x − y| + |x + y| = 2
Case-I: x ≥ y &x + y ≥ 0
⇒ x − y + x + y = 2 ⇒ x = 1
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⇒ 1 ≥ y & y ≥ −1 ⇒ −1 ≤ y ≤ 1
Since the graph is symmetric about x as well as y-axis, we will get a square as shown
∴ Area = 2 × 2 = 4
Q82
Given in AP : PB = 2 : 1
Let AP = 2r and BP = r
B = (1 + r cos θ, 1 + r sin θ)
2 2
⇒ (1 − 2r cos θ) + (1 − 2r sin θ) = 4
Q83
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Q84
2
∑ x = 60, ∑ x = 1000
′
Increase in ∑ x = 10, ⇒ ∑ x = 60 + 10 = 70
2 ′2
Increase in ∑ x = 900 − 400 = 500 ⇒ ∑ x = 1000 + 500 = 1500
2
1 ′2
1 ′
Variance = ∑x − ( ∑x )
n n
2
1 1
= × 1500 − ( × 70) = 150 − 49 = 101
10 10
Q85
5
.
.
.
5
Here, 5 5
(23 times 5) is an odd natural number.
…,
Let 5 5
(23 times 5)= 2m + 1
5
5w
Now, let x = 5 5
(24 times 5) = 5 2m+1
= 5 ⋅ 5
2m
, where m is a natural number.
m
2 m
∴ x = 5 ⋅ (5 ) = 5(24 + 1)
m m m m−1 m
= 5[ C0 (24) + C1 (24) + … + Cm−1 (24) + 1]
= 5(24k + 1) = 24(5k) + 5
x 5
∴ = 5k +
24 24
Q86
Q87
Hence any point on L and L can be (λ, λ − 1, λ) and (2μ − 1, μ, μ), respectively. According to the question,
1 2
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∴ A = (3, 2, 3) B = (1, 1, 1)
∴ AB = 3.
Q88
(100+n)
200n
AM = ; GM = 10√n; HM =
2 (100+n)
200n
HM =
2
(25+k )
2
100 < n < 500 ⇒ 25 < k ≤ 125
2
k = 50, 75, 100&125
2
k = 100 only solution
n = 400
Q89
2 2 2 2
α +β (α+β) −2αβ
So; and
t 1 1 1 1 1
2
= 2
= + 2
+ = 2
−
(αβ) (αβ) 4 t (αβ) αβ 4t 2t
2 2
Now I = ∫ 2
−1
((x +
1
2
) (x +
1
2
) +
1
) dx = ∫
2
−1
(x
2
+ (
t
4
+
1
t
)x + [
1
2
−
1
2t
]) dx =
3t
8
+
3
2
+ 3
α β αβ 4t 4t
9
∴ Imin = √ + 3
8
Q90
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f (x)
′
= ⋅ f (1)
x
′
2f (x) f (x) 2
′
∴ f (x) = or =
x f (x) x
So, f (x) = x 2
Now,
2 2 4 2
2
= x ⇒ x + x − 2 = 0
1+x
2
⇒ x = 1 ⇒ x = ±1
Required area = 2 [∫
1 2 2
( 2
− x ) dx]
0 1+x
1
3
−1 x π 1
= 2[2 tan x − ] = 2[ − ]
3 2 3
0
sq. units.
2
= (π − )
3
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