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Low-Rank Coal Applications in Agriculture
Low-Rank Coal Applications in Agriculture
L. Edwin Liem
This edition first published 2021
© 2021 John Wiley & Sons Ltd
All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted,
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http://www.wiley.com/go/permissions.
The right of L. Edwin Liem to be identified as the author of this work has been asserted in accordance
with law.
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10 9 8 7 6 5 4 3 2 1
v
Contents
List of Figures ix
List of Tables xi
Units xv
1 Introduction 1
Reference 7
2 Low-Rank Coal 9
2.1 Overview 9
2.2 Material Quality 13
2.3 Material Safety 17
2.4 Safety Documentation 27
2.5 Closure 29
Reference 31
3 Humic Analyses 37
3.1 Overview 37
3.2 Extraction and Analyses 41
3.2.1 Extraction 42
3.2.2 Physical Properties 45
3.2.3 Gravimetric 45
3.2.4 Colorimetric 48
3.2.5 Combined Colorimetric and Gravimetric 51
3.2.6 Organic Carbon 52
3.2.7 Reactive Functional Groups 53
3.2.8 Comparison Among Analytical Methods 55
3.2.9 Further Studies on Analytical Methods 57
vi Contents
7 Conclusion 299
Reference 307
Index 309
Biography 319
ix
List of Figures
L
ist of Tables
U
nits
# number
$ dollar
% percent
° degree
cfu colony forming unit
cm centimeter
cmol centimole
dm decimeter
g gram
ha hectare
kcal kilocalorie
kg kilogram
kJ kilojoule
kPa kilopascal
l liter
lm lumen
m meter
meq milliequivalent
mg milligram
ml milliliter
mm millimeter
xvi Uni
mM millimole/l
mmol millimole
mole 6.02 × 1023 atoms
mpn most probable number
mS millisiemens
nm nanometer
ppb part per billion
ppm part per million
ppt part per trillion
t tonne (= 1000 kg)
μg microgram
μm micrometer
1
Introduction
Coal is the most abundant type of fossil fuel, accounting for 64% of globally recov-
erable resources in the world, compared to oil (19%) and natural gas (17%). Coal is
traditionally used in the energy sector, generating about 40% of the world’s elec-
tricity. The demand for coal is expected to increase by over 60% from 2006 to 2030,
of which developing countries will account for over 90%. Coal-fired electricity
generation is still a major energy source in North America and Australia. In addi-
tion, coal is also used in the metallurgical sector, where 70% of the world’s steel
industry depends on it. The challenge here has been in how to maximize produc-
tivity, reduce energy consumption, and drastically reduce carbon dioxide (CO2)
emissions (Osborne and Gupta 2013). Efforts have been made to offer a more effi-
cient and cleaner use of coal, including its use in the production of electricity,
steel and its associated products, and energy-related chemicals, as well as increas-
ing the use of coal byproducts (Osborne et al. 2013). While significant progress
has been made, it is still worth seeking new environmentally friendly and efficient
usages of coal beyond these well-known applications. Such usages are not set to
immediately replace the existing applications of coal, however, but instead pro-
vide alternatives so that whenever the opportunity arises, new market sectors can
be generated and expanded as quickly and efficiently as possible.
Among different coal materials, low-rank coal has been one of the most dis-
cussed and has seen its popularity grow in recent years. This is in part because of
its unique yet challenging nature, and because of its versatile applications. Low-
rank coal contains lower calorific values than those of anthracite, bituminous,
and subbituminous. However, it is rich in organic matter (OM) and humic sub-
stances (HS, or “humic”) that have been proven to be beneficial for several differ-
ent purposes. Unfortunately, these purposes have so far been largely unrecognized
or misunderstood. This is chiefly because they fall outside of the scope of the
usages that people are more familiar with when it comes to coal materials. In the