Download as RTF, PDF, TXT or read online from Scribd
Download as rtf, pdf, or txt
You are on page 1/ 3
Addis Ababa Science & Technology University, College of Biological &
Chemical Engineering , Department of Chemical Engineering
Worksheet One on Chemical Engineering Thermodynamics II Date:
1. How much heat is required when 10000 kg of CaC03 is heated at atmospheric pressure from 323.15 to 1153.15 K? 2. For the following liquids, determine the heat of vaporization at its normal boiling point by application of the Clapeyron equation to the given vapor-pressure equation. Use generalized correlations from Chap. 3 to estimate ∆Vlv.
3. Handbook values for the latent heats of vaporization in J g -1 are given in the table for several pure liquids at 298.15 K and at Tn the normal boiling point (App. B).
(a) The value of the latent heat at Tn = 273.15 K. by [Eq. (4.13), see your text book] (b) The value of the latent heat at Tn, by [Eq. (4.12), see your text book]. By what percentages do these values differ from the one listed in the table?
4. Estimate for the following compounds as a liquid at 298.15 K
6. Determine the standard heat of the reactions of Pb. 4: Part (a) at 873.15 K (600°C), Part (b) at 773.15 K (500°C), Part (c) at 923.15 K (65PC), Part (d) at 973.15 K (700°C), Part (e) at 583.15 K (310°C), Part (f) at 683.15 K (410°C), Part (g) at 850 K.
7. Hydrocarbon fuels can be produced from methanol by reactions such as the following, which yields 1-hexene: 6CH3OH (g) C6H12(g) +6H2O(g) Compare the standard heat of combustion at 298.15 K of 6CH30H (g) with the standard heat of combustion at 298.15 K of C6H12 (g) for reaction products C02 (g) and H20 (g).
8. Calculate the theoretical flame temperature when ethylene at 298.15 K is burned with: (a) The theoretical amount of air at 298.15 K. (b) 25% excess air at 298.15 K (25°C). (c) 50% excess air at 298.15 K (25°C). (d) 100% excess air at 298.15 K (25°C). (e) 50% excess air preheated to 773.15 K (500°C).
9. For steady flow through a heat exchanger at approximately atmospheric pressure, what is the final temperature, (a) When heat in the amount of 800 W is added to 10 mol of ethylene initially at 473.15 K? (b) When heat in the amount of 2500 kJ is added to 15 mol of 1-butene initially at 533.15 K (c) When heat in the amount of 1055 GJ is added to 18.14 kmol of ethylene initially at 533.15 K?
10. For steady flow in a heat exchanger at approximately atmospheric pressure, what is the final temperature: (a) When 10 mol of SO2 is heated from 473.15 to 1373.15 K (200 to 1 100°C)? (b) When 12 mol of propane is heated from 523.15 to 1473.15 K (250 to 1200°C)?
11. A gas consisting only of CO and N2 is made by passing a mixture of flue gas and air through a bed of incandescent coke (assume pure carbon). The two reactions that occur both go to completion: C02 + C 2C0 and 2 C + O2 2C0 They yield a flue gas of composition: 12.8 mol-% CO, 3.7 mol-% C0 2, 5.4 mol-% 02, and 78.1 mol-% N2. The flue gas/air mixture is so proportioned that the heats of the two reactions cancel, and the temperature of the coke bed is therefore constant. If this temperature is 1148.15 K (875"C), if the feed stream is preheated to 1148.15 K (875"C), and if the process is adiabatic, what ratio of moles of flue gas to moles of air is required, and what is the composition of the gas produced?
