WEEKLY TEST - 8

CHEMISTRY (043)
CLASS : XII Max. Mark : 40
Time Allowed : 1 ½ hours
SOLUTIONS
General Instructions:
i. All Questions are Compulsory.
ii. This Question paper contains 22 Questions.
iii. Questions 1-12 in Section A are objective type Questions carrying 1 mark each.
iv. Questions 13-17 in Section B Very answer Questions carrying 2 marks each.
v. Questions 18-20 in Section C Short answer type Questions carrying 3 marks each.
vi. Question 21 in Section D Case Based Question carrying 4 marks.
vii. Question 22 in Section E long answer type Question carrying 5 marks.

SECTION - A
1. With increase of temperature, which of these Changes
(a) Molality (b) Weight fraction of solute
(c) Fraction of solute present in water (d) Mole fraction
2. A supersaturated solution is a metastable state of solution in which solute concentration
(a) is equal to the solubility of that substance in water (b) exceeds its solubility
(c) less than its solubility (d) continuously changes.
3. The solubility of gas in liquid increases with
(a) increase in temperature (b) reduction of gas pressure
(c) decrease in temperature (d) amount of liquid taken.
4. Which of the following does not show positive deviation from Raoult'sLaw?
(a) Benzene-chloroform (b) Benzene-acetone
(c) Benzene-ethanol (d) Benzene-carbon tetrachloride.
5. Value of Henry's constant KH is
(a) Increases with increase in temperature (b) Decreases with increase in temperature
(c) Remains constant (d) First increases then decreases.
6. KH value for Ar(g), CO2(g), HCHO(g) and CH4(g) are 4.039, 1.67, 1.83 × 10–5, and 0.143,
respectively. Arrange these gases in the order of their increasing solubility
(a) HCHO < CH4 < CO2 < Ar (b) HCHO < CO2< CH4 < Ar
(c) Ar < CO2< CH4< HCHO (d) Ar < CH4 < CO2< HCHO
7. If two liquids A and B form minimum boiling azeotrope at some specific composition, then.
(a) A–B interactions are stronger than those between A–A or B–B.
(b) vapour pressure of solution increases because more number of molecules of liquids A
and B can escape from the solution.
(c) vapour pressure of solution decreases because less number of molecules of only one of
the liquids escape from the solution.
(d) A–B interactions are weaker than those between A–A or B–B
8. The vapour pressure of two liquids “P” and “Q” are 80 and 60 torr, respectively. The total
vapour pressure of solution obtained by mixing 3 moles of P and 2 moles of Q would be
a) 72 torr b) 140 torr c) 68 torr d) 20 torr
In the following questions a statement of
Assertion (A) followed by a statement of Reason(R) is given. Choose the correct
option out of the choices given below each Questions.
(a) Assertion and reason are true, and reason is correct explanation of assertion.
(b) Assertion and reason both are true but reason is not the correct explanation of assertion.
(c) Assertion is true, reason is false.
(d) Assertion is false, reason is true
9. Assertion (A): Molarity of a solution changes with temperature.
Reason (R): Molarity is dependent on volume of solution.
10. Assertion : An ideal solution obeys Henry’s law
Reason: Raoult’s law is special case of Henry law.
11. Assertion : The solubility of a gas in a liquid increases with increase of pressure
Reason: The solubility of a gas is directly proportional to pressure of the gas.
12. Assertion : Raoult’s law is a special case of henry’s law
Reason: Higher the value of at a given pressure, the lower is the solubility of the gas in
the liquid.
SECTION-B
13. What happens when we place the blood cell in water (hypotonic solution)? Give reason.
14. A solution is prepared by dissolving 10g of non-volatile solute in 200g of water. It has a
vapour pressure of 31.84 mm Hg at 308K. Calculate the molar mass of the solute. (Vapour
pressure of pure water at 308K = 32mm Hg).
15. What is meant by positive deviations from Raoult’s law? Given an example? What is the sign
of Δ𝐦𝐢𝐱𝐇 for positive deviation?
16. 3.9 g of benzoic acid dissolved in 49 g of benzene shows a depression in freezing point of 1.62
K. Calculate the van’t Hoff factor and predict the nature of solute (associated or dissociated).
(Given: Molar mass of benzoic acid = 𝟏𝟐𝟐𝐠𝐦−𝟏, 𝐊𝐟 for benzene = 4.9 K Kg 𝐦𝐨𝐥−𝟏)
OR
A solution containing15gurea (molar mass = 60g𝐦𝐨𝐥−𝟏) per litreof solution inwaterhas the
same osmotic pressure (isotonic)as a solutionofglucose (molar mass =180 g𝐦𝐨𝐥−𝟏) in water.
Calculate the mass of glucose present in one litre of its solution.
17. Predict the state of the solute in the solution in the following situations:
a)When ‘i’ is found to be0·3.
b)When ‘i’ is found to be 4.
SECTION- C

18. .Give reasons:

a)An increase in temperature is observed on mixing chloroform and acetone.
b)Aquatic animals are more comfortable in cold water than in warm water.

c)At higher altitudes people suffer from anoxia resulting in inability to think.

19. Write two differences between an ideal solution and a non-ideal solution.
20. Give reasons :
(a) Cooking is faster in pressure cooker than in cooking pan.
(b)Red Blood Cells (RBC) shrink when placed in saline water but swell in distilledwater.
(c) What are hyperttonic solutions?
OR
A solution containing 1·9 g per 100 mL of KCl (M = 74·5 g mol–1) is isotonic with a
 solutioncontaining 3 g per 100 mL of urea (M = 60 g mol–1). Calculate the degree of
dissociation of KCl solution. Assume that both the solutions have same temperature.
SECTION-D
21. Boiling point or freezing point of liquid solution would be affected by the dissolved solids
in the liquid phase. A soluble solid in solution has the effect of raising its boiling point
and depressing its freezing point. The addition of non-volatile substances to a solvent
decreases the vapor pressure and the added solute particles affect the formation of pure
solvent crystals. According to many researches the decrease in freezing point directly
correlated to the concentration of solutes dissolved in the solvent. This phenomenon is
expressed as freezing point depression and it is useful for several applications such as
freeze concentration of liquid food and to find the molar mass of an unknown solute in
the solution. Freeze concentration is a high quality liquid food concentration method
where water is removed by forming ice crystals. This is done by cooling the liquid food
below the freezing point of the solution. The freezing point depression is referred as a
colligative property and it is proportional to the molar concentration of the solution (m),
along with vapor pressure lowering, boiling point elevation, and osmotic pressure. These
are physical characteristics of solutions that depend only on the identity of the solvent
and the concentration of the solute. The characters are not depending on the solute’s
identity.
a)Why does a solution containing non-volatile solute have higher boiling point than a pure
solvent ?
b)Why is freezing point depression a colligative property ?
c) For a 5% solution of urea (Molar mass = 60 g/mol), calculate the osmotic pressure at 300
K. [R = 0·0821 L atm K–1 mol–1] OR
Visha took two aqueous solutions one containing 7·5 g of urea (Molar mass = 60 g/mol)
and the other containing 42·75 g of substance Z in 100 g of water, respectively. It was
observed that both the solutions froze at the same temperature. Calculate the molar mass of
Z.
SECTION-E
22.
(i) At the same temperature, CO2 gas is more soluble in water than O2 gas. Which one of
them will have higher value of KH and why ?
(ii) (ii) How does the size of blood cells change when placed in an aqueous solution
containing more than 0·9% (mass/volume) sodium chloride ?
(iii) (iii) 1 molal aqueous solution of an electrolyte A2B3 is 60% ionized. Calculate the
boiling point of the solution. 1+1+3=5 (Given : Kb for H2O = 0·52 K kg mol-1 )
OR
(i) The vapour pressures of A and B at 25ºC are 75 mm Hg and 25 mm Hg, respectively. If A
and B are mixed such that the mole fraction of A in the mixture is 0·4, then calculate the
mole fraction of B in vapour phase.
(ii) Define colligative property. Which colligative property is preferred for the molar mass
determination of macromolecules ?
(iii) Why are equimolar solutions of sodium chloride and glucose not isotonic ?