Ways of Representing Molecules

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Ways of Representing

Molecules

General Chemistry 1
Science, Technology, Engineering, and Mathematics
Ever wondered how molecules look like on a
microscopic scale?

2
Compounds can
be represented by
just the ratio of
atoms or the exact
number of atoms
found in each unit.
3
For complicated
molecules, how each
atom is connected
and how they are
positioned are
important in
understanding their
chemistry. 4
How do we represent chemical
substances?

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Learning Competencies
At the end of the lesson, you should be able to do the following:

● Represent compounds using chemical formulas,


structural formulas, and models (STEM_GC11AM-Ic-e-
21).

● Give the similarities and differences between the


empirical formula and molecular formula of a
compound (STEM_GC11AM-Ic-e-22).

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Learning Objectives
At the end of the lesson, you should be able to do the following:

● Differentiate between an empirical and molecular


formula.

● Write the empirical formula if the molecular formula is


given.

● Demonstrate ways to represent compounds using


chemical formulas, structural formulas, and models.
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How important are chemical
formulas for knowing the
composition and structure of a
compound?

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Chemical Formula

Molecular Formula
● most common way to represent molecules

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Chemical Formula

Molecular Formula
● most common way to represent molecules
● symbols of each element are written down with a
subscript indicating how many atoms are in the
compound

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Chemical Formula

Molecular Formula
● most common way to represent molecules
● symbols of each element are written down with a
subscript indicating how many atoms are in the
compound
● example: compound with two atoms of hydrogen and
one atom of oxygen is represented as H2O.

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Chemical Formula

Empirical Formula
● gives the simplest whole-number ratio of each element
in a compound

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Chemical Formula

Empirical Formula
● gives the simplest whole-number ratio of each element
in a compound
● Let us take glucose for example.

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Chemical Formula

Empirical Formula
● gives the simplest whole-number ratio of each element
in a compound
● Let us take glucose for example.
○ molecular formula: C6H12O6

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Chemical Formula

Empirical Formula
● gives the simplest whole-number ratio of each element
in a compound
● Let us take glucose for example.
○ molecular formula: C6H12O6
○ empirical formula: CH2O, wherein for every carbon
atom, there are two two hydrogen atoms and an
oxygen atom.
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Chemical Formula

Empirical Formula
Subscripts: divide each amount of atoms in the formula
by the greatest common factor

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Chemical Formula

Empirical Formula
Take H2C2O4 as an example.
What is the greatest common factor among its subscripts?

2
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Chemical Formula

Empirical Formula
Take H2C2O4 as an example.
What will happen to each subscript if we divide it by 2?

HCO2
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Chemical Formula

Empirical Formula
In some cases, the molecular formula is already in the
lowest number ratio and would automatically be the
empirical formula.
○ C5H12 is both the molecular and empirical formula
of the compound.

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Chemical Formula

Structural Formula
● used for more complex molecules such as organic
compounds - those containing carbon bonds

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Chemical Formula

Structural Formula
● used for more complex molecules such as organic
compounds - those containing carbon bonds
● inorganic compounds - those that lack carbon bonds

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Chemical Formula

Structural Formula
● used for more complex molecules such as organic
compounds - those containing carbon bonds
● inorganic compounds - those that lack carbon bonds
● hydrocarbons - organic compounds made up entirely
of carbons and hydrogens

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Chemical Formula

Structural Formula
● complete structural formula
○ all bonds and atoms are shown

the complete structural formula of n-pentane

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Chemical Formula

Structural Formula
● condensed structural formula
○ atoms connected to a specific carbon are
represented like molecular formula

CH3CH2CH2CH2CH3
the condensed structural formula of n-pentane

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Chemical Formula

Structural Formula
● skeletal or line angle formula
○ hydrogens attached to each carbon will not be
drawn: implicit hydrogens

the line-angle formula of n-pentane

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Molecular Model

Ball-and-Stick Model
● balls - atoms
● stick - bonds between atoms
● shows the geometry of the
molecule and helps us Ball-and-stick model for
predict properties n-pentane

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Molecular Model

Space-Filling Model
● better estimate of actual
molecule shape
● bonds represented by sticks
in previous model is cut short
to give better representation
Space-filling model of n-
pentane

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Why is it important that molecular
models show the correct geometry
of the compound?

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Let’s Sum It Up!

● A chemical formula is a way to represent molecules to convey


information about its composition or structure.

● A molecular formula is the most common chemical formula


wherein symbols of each element are written down with a
subscript indicating how many atoms are in the compound.

● An empirical formula is a chemical formula showing only the


simplest whole-number ratio of each element in a compound.

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Let’s Sum It Up!

● Organic compounds are compounds containing


carbon bonds. Compounds that lack these bonds are
called inorganic compounds. Molecules that contain
only carbon and hydrogen are part of a family of
organic compounds called hydrocarbons.

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Let’s Sum It Up!

● Structural formulas are detailed chemical formulas that show


the structure of a compound.
○ complete structural formula - all bonds and atoms are
shown.
○ condensed structural formula - indicates the number of
attached hydrogens to each carbon
○ skeletal or line-angle formula - the hydrogen and carbon
atoms are implied from the shape of the structure.

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Let’s Sum It Up!

● A molecular model is a 3D model showing how atoms are


connected in a molecule.
○ ball-and-stick model - model where different colored
spheres represent atoms, and sticks represent bonds.
○ space-filling model - model wherein bond lengths are
shortened for better estimation of its length relative to the
size of the atoms.

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