GASES
GASES
GASES
GASES
Miss Rachelle Roberto
Outline of Discussion
•Gases
•Kinetic Molecular Theory of Gases
•Boyle’s Law
•Charles’ Law
•Gay-Lussac’s Law
Gases
• Gas is one of the three fundamental states of matter, with
distinctly different properties from liquid and solid.
• A puregas may be made up of individual atoms, elemental
molecules made from one type of atom, or compound molecules
made from a variety of atoms (e.g. carbon dioxide).
• A gas mixture, such as air, contains a variety of pure gases.
• What distinguishes a gas from liquids and solids is the vast
separation of the individual gas particles. This separation usually
makes a colorless gas invisible to the human observer.
Properties of Gases
•Gases are described as not having a
definite shape and volume, in contrast to
solids and liquids.
•They have much lower density compared
to other phases.
1. Gases have no definite shape and volume. Hence, it assumes the
volume and shape of the containers.
2. Gases have very low densities.
3. Gases can exert pressure and is measured in gauge (tire
pressure) or millimeter (barometer).
4. Gases diffuses easily.
5. Gases expand when heated.
6. Gases are the most compressible of the state of matter.
7. At absolute temperature, the average Kinetic Energy of the
molecules of ALL gases are the same in 0 K (absolute zero),
gases have no energy and therefore are not in motion.
Kinetic Molecular
Theory of Gases
Kinetic Molecular Theory
•The Kinetic Molecular Theory (KMT) of
gases describes the nature of gases and
the behavior of its particles.
•Any gas behaving according to Kinetic
Molecular Theory is called “ideal” or
“perfect gas”.
Kinetic Molecular Theory of Gases
1. The volume occupied by the individual particles of a gas is negligible
compared to the volume of the gas itself.
2. The particles of an ideal gas exert no attractive forces on each other
or on their surroundings.
3. Gas particles are in a constant state of random motion and move in
straight lines until they collide with another body.
4. The collisions exhibited by gas particles are completely elastic; when
two molecules collide, total kinetic energy is conserved.
5. The average kinetic energy of gas molecules is directly proportional
to absolute temperature only; this implies that all molecular motion
ceases if the temperature is reduced to absolute zero.
Variables affecting the
behavior of Gases
Pressure (P)
• Pressure is defined as the perpendicular force exerted on
a unit area.
• The mathematical expression P=F/A defines the
pressure (P) in terms of force (F) acting on an area (A).
• Pressure is commonly measured using a barometer or
manometer.
• A barometer measures atmospheric pressure while a
manometer or pressure gauge measures pressure in a
closed system.
• The pressure of a gas expressed in different units, among
which are atmosphere (atm), Torr, Millimeter Mercury
(mmHg), Pascal (Pa), Pounds per Square inch (psi), and
kilo Pascal (kPa).
Equivalent of Quantity in Terms of Other Units
Millimeter
Standard Pounds per
Unit Atmosphere (atm)
Torr Mercury (mm Pascal (Pa)
Square Inch (psi)
Hg)
atm 1 760 760 101 325 14.7
Torr 1.32x10-3 1 1 133.32 0.0193
mm Hg 1.32x10-3 1 1 133.32 0.0193
Pa 9.87x10-6 7.5x10-3 7.5x10-3 1 1.45x10-4
Psi 0.068 51.7 51.7 6.89x103 1
kPa 0.00987 7.500 7.500 1000 0.1450
Temperature (T)
• Temperature is the property of matter which reflects the quantity
of energy of motion of the component particles.
• It is a comparative measure of how hot or cold a material is.
• The coldest theoretical temperature is called absolute zero. It is
the temperature where the thermal motion of particles is at its
minimum (not the same as motionless).
• Absolute zero is 0 K on the Kelvin scale, −273.15 C on the
Celsius scale, and −459.67 F on the Fahrenheit scale.
• The instrument used to measure temperature is a thermometer.
Volume (V)
• Itis the space that a specific substance occupies.
• Since a gas completely fill its container, the volume
of the gas is equal to the volume of its container.
• It is expressed in different units like Liter (L),
milliliter (mL), cubic centimeters (cm3), cubic
meter (m3), dm3 etc.
Number of moles (n)
•This is the quantity of gas which is
expressed in moles.
• To differentiate it from a previous value
also the same name, its unit is given a
symbol of n.
Standard Temperature and Pressure
• Incalculations involving gas laws, the values of pressure
and temperature are sometimes not stated, meaning the
problem statement will just indicate that the condition of
the gas involved is at STP.
• When a gas is at standard temperature and pressure
(STP), it means that the gas involve in the calculation
has a pressure of 1 atm and is in absolute temperature
which is 273 K.
• The values of STP may vary depending on the required
unit in the problem
Gas Laws
Gas Laws
• Gas laws are scientific laws derived from observation and
experimentation on the properties and behavior of gases
involving the Pressure, Volume, Temperature, and
Number of Moles.
• The principles of these laws are based on how these
variables affect the properties and behavior of gases.
• Since we live in a sea of gas, these gas laws will help us
better understand on how to deal with different activities
and phenomena where gases are involved.
Boyle’s Law
Pressure and Volume are
inversely proportional at a
constant temperature of a gas in
a closed system
Boyle’s Law
• Inmid-1600s, an Irish Scientist Robert
Boyle studied the pressure and volume
relationship of a confined gas held at
constant temperature.
• Hestudied the effects of pressure to the
volume of gas in the sealed end of the tube
by adding mercury on the open end of the
tube.
Boyle's Law states that the pressure (P) of a gas is
inversely proportional to its volume (V) when T and n are
constant.
PV = k
P1V1 = k
(V) P = (V)
P2V2 = k
PV =
PV = k P1V1 = k P2V2 = k
P 1V 1 =
P2V2
Sample Problem
• A balloon with a volume of 2.0 L is filled with a gas at 3.0 atmospheres (atm).
If the pressure is reduced to 0.5 atm without a change in temperature, what
would be the volume of the balloon?
Given Equation Solution
(G)
P1 = 3.0 atm (E) (S) (3.0 atm)(2.0 L)
P1V1 = P2V2
V1 = 2.0 L V2
P2 P2 = 0.5 atm
P2 = 0.5 atm
Answer (A)
Required V2 = P1V1
(R) P2 V2 = 12.000
V2 = ? L
Sample Problem
• A 20.0L gas kept in a movable piston has an initial pressure of 1.5 atm at
25˚C. If the piston is allowed to expand isothermally at 45.0 L at constant
temperature, what will be the resulting pressure of the gas?
Given Equation Solution
(G)
P1 = 1.5 atm (E) (S) (1.5 atm)(20.0 L)
P1V1 = P2V2
V1 = 20.0 L P2 =
V V 45.0 L
V2 = 45.0 L
2 2 Answer (A)
Required P2 = P1V1
(R) V P2 = 0.667 atm
P2 = ?
2
Practice Exercise
1. A gas occupies 12.3 liters at a pressure of 40.0 mmHg.
What is the volume when the pressure is increased to 60.0
mmHg?
2. 500.0 mL of a gas is collected at 745.0 mmHg. What will
the volume be at standard pressure?
3. A gas occupies 11.2 liters at 0.860 atm. What is the
pressure if the volume becomes 15.0 L?
Charles’ Law
Temperature is directly proportional
to the volume it occupies if the
pressure and mass (amount of gas)
remain constant in a closed
container.
Charles’ Law
• Inthe 1800’s, another gas law was
established in an effort to improve the
design of the hot air balloons.
• Frenchscientist Jacques Charles, together
with Gay-Lussac, discovered the volume-
temperature relationship of gases at a
constant pressure.
V∝T
Charles’ Law states that the volume of a fixed amount of
gas maintained at constant pressure is directly
proportional to absolute temperature of the gas.
V
V∝T k=
T
V = kT V1
T T =k
T1
V = kT V2
=k
T T T2
V
k=
T
V1
=k
T1
V2
=k
T2
=
𝑉 1 𝑇 2=𝑉 2 𝑇 1
Sample Problem
• A 600mL sample of nitrogen is heated from 27°C to 77 °C at constant
pressure. What is the final volume?
Given Equation
NOTE: Solution
(G)
V1 = 600 (E) (S) (600 mL)(350 K)
V T =
When1 solving Gas Law
T1 = 27°C 300 K
mL 2 V2
VT2T1 1 dealing
Problem T1 with = 300 K
T2 = 77 °C 350 K
TEMPERATURE as aAnswer (A)
Required V2 = always
variable V1T2 convert it
(R) into KELVIN T1 V2 = 700.000
V2 = ? mL
Sample Problem
• Considera 25.0 L gas in a container initially at 25°C and 1 atm. If this gas is
heated and the volume increases to 30.0 L, what is the increase in temperature
under constant pressure?
Given Equation Solution
(G)
V1 = 25.0 L (E) (S) (30.0 L)(298 K)
V1T2 =
T1 = 25°C 298 K T2 =
VV
2T1 V 25.0 L
V2 = 30.0 L
1 1 Answer (A)
Required T2 = V2T1
(R) V V2 = 357.600 K
T2 = ?
1
Practice Exercise
P = kT P1
T T =k
T1
P = kT P2
=k
T T T2
=
𝑃 1 𝑇 2=𝑃 2 𝑇 1
Sample Problem
• Determine the pressure change when a constant volume of gas at 1.00 atm is
heated from 20.0 ˚C to 30.0 ˚C.
Given Equation
NOTE: Solution
(G)
P1 = 1.00 atm (E) (S) (1.00 atm)(303 K)
P T = P
When1 solving T
2 Gas Law
T1 = 20°C 293 K
2 1 P2 =
T1 dealing
Problem T1 with 293 K
T2 = 30 °C 303 K
TEMPERATURE as a Answer (A)
Required P2 =always
variable P1T2 convert it
(R) into KELVINT1 P2 = 1.034 atm
P2 = ?
Sample Problem
• A gasoccupies a volume of 90.0 mL at 20 ˚C and 680 torr. At what
temperature in ˚C would the pressure be at 770 torr if the volume remains
constant?
Given Equation Solution
(G)
P1 = 680 (E) (S) (770 torr)(293 K)
P1T2 = P2T1
T1 = 20°C 293 K
torr T2 =
P1 P1 680 torr
P2 =770 torr
Answer (A)
Required T2 = P2T1
(R) P1 T2 = 331.779 K
T2 = ?
T2 = 58.779 °C
Practice Exercise
1. A gas has a pressure of 0.370 atm at 50.0 °C. What is the pressure
at standard temperature?
2. If a gas is cooled from 323.0 K to 273.15 K and the volume is
kept constant what final pressure would result if the original
pressure was 750.0 mmHg?
3. A 30.0 L sample of nitrogen inside a metal container at 20.0 °C is
placed inside an oven whose temperature is 50.0 °C. The pressure
inside the container at 20.0 °C was 3.00 atm. What is the pressure
of the nitrogen after its temperature is increased?
Review
Boyle's Law
• This law states that the pressure of a gas is inversely proportional
to its volume when temperature and number of moles are constant
Charles's Law
• This law states that the temperature of a gas is directly
proportional to its volume when pressure and number of moles
are constant.
Gay-Lussac's Law
• This law states that the pressure of a gas is directly proportional to
its temperature when volume and number of moles are constant.
V∝ P∝T
T
Combined Gas Law
• The combined gas law combines the three gas
laws: Boyle's Law, Charles' Law, and Gay-
Lussac's Law.
• The law states that the volume of a certain mass of
gas is inversely proportional to its pressure and
directly proportional to its absolute temperature.
𝑉 𝑃
𝑘=𝑃 𝑉 𝑘= 𝑘=
𝑇 𝑇
𝑃𝑉
𝑘=
𝑇
𝑃𝑉
𝑘= 𝑃1 𝑉 1 𝑃2 𝑉 2
𝑇
=
𝑃1𝑉 1 𝑇1 𝑇2
𝑘=
𝑇1
𝑃 1 𝑉 1 𝑇 2= 𝑃 2 𝑉 2 𝑇 1
𝑃2𝑉 2
𝑘=
𝑇2
Sample Problem
• A gas sample held in a 1.0 L piston at 305 K has a pressure of 0.75 atm. The
piston was heated to 387 K at the same time the volume was expanded to 1.5
L. Will the pressure decrease or increase?
Given Equation Solution
(G)
P1 = 0.75 atm (E) (S) (0.75 atm)(1.0 L)(387 K)
P1V1T2 =
V1 = 1.0L P2 = (1.5 L)(305 K)
PP2VT2 T1 V T
T1 = 305 K 2 1 2
V2 = 1.5 L 1
Answer (A)
T2 = 387 K P2 = P1V1T2
V2 P2 = 0.634 atm
Required T1
(R)
P2 = ?
Sample Problem
• A certain gas occupies a volume of 500 ml at 27˚C and 740 torr. What volume
will it occupy at STP?
Given Equation Solution
(G)
P1 = 740 0.974 atm (E) (S) (0.974 atm)(500 mL)(273 K)
P1V1T2 =
torr
V1 = 500 V2 (1.0 (300 K)
PP2VT T P T
mL
T 1 = 27°C 300 K 2
2 1 1 2 = atm)
P2 = 1.0 atm 1
Answer (A)
T2 = 273 K V2 = P1V1T2
P2T V2 = 443.170
Required mL
1
(R)
V2 = ?
Practice Exercise
V = kn V1
n n =k
n1
V = kn V2
=k
n n n2
=
𝑉 1 𝑛2 =𝑉 2 𝑛1
Sample Problem
• 5.00 L of a gas is known to contain 0.965 mol. If the amount of gas is
increased to 1.80 mol, what will be its new volume (at an unchanged
temperature and pressure)?
Given Equation Solution
(G)
V1 = 5.00 L (E) (S) (5.00 L)(1.80 mol)
V1n2 = V2n1
n1 = 0.965 V2
n n 0.965 mol
mol
n2 = 1.80 1 1 =
mol Answer (A)
Required V2 = V1n2
(R) V2 = 9.326 L
V =? n 1
2
Sample Problem
• 15.0
grams of Oxygen gas has a volume of 10 L. After 3.0 grams is added,
what will be the final volume of oxygen gas?
GIVEN: N2 = 2.70 mol | CO2 = 6.90 mol | H2 = 8.76 mol | SO2 = 2.98 | PT = 1512
torr
REQUIRED: Partial Pressure of each component gas
EQUATION: and
SOLUTION:
DALTON’S LAW OF PARTIAL PRESSURES
SAMPLE PROBLEM
1. A gas sample whose total pressure is 1512 torr, what are the partial pressures if the
following component gases: 2.70 mol N2, 6.90 mol CO2, 8.76 mol H2, and 2.98 mol SO2?
GIVEN: N2 = 2.70 mol | CO2 = 6.90 mol | H2 = 8.76 mol | SO2 = 2.98 | PT = 1512
torr
REQUIRED: Partial Pressure of each component gas
EQUATION: and
SOLUTION:
DALTON’S LAW OF PARTIAL PRESSURES
SAMPLE PROBLEM
1. A gas sample whose total pressure is 1512 torr, what are the partial pressures if the
following component gases: 2.70 mol N2, 6.90 mol CO2, 8.76 mol H2, and 2.98 mol SO2?
SOLUTION:
DALTON’S LAW OF PARTIAL PRESSURES
SAMPLE PROBLEM
1. A gas sample whose total pressure is 1512 torr, what are the partial pressures if the
following component gases: 2.70 mol N2, 6.90 mol CO2, 8.76 mol H2, and 2.98 mol SO2?
SOLUTION:
DALTON’S LAW OF PARTIAL PRESSURES
SAMPLE PROBLEM
1. A gas sample whose total pressure is 1512 torr, what are the partial pressures if the
following component gases: 2.70 mol N2, 6.90 mol CO2, 8.76 mol H2, and 2.98 mol SO2?
SOLUTION:
DALTON’S LAW OF PARTIAL PRESSURES
SAMPLE PROBLEM
1. A gas sample whose total pressure is 1512 torr, what are the partial pressures if the
following component gases: 2.70 mol N2, 6.90 mol CO2, 8.76 mol H2, and 2.98 mol SO2?
SOLUTION:
DALTON’S LAW OF PARTIAL PRESSURES
SAMPLE PROBLEM
1. A gas sample whose total pressure is 1512 torr, what are the partial pressures if the
following component gases: 2.70 mol N2, 6.90 mol CO2, 8.76 mol H2, and 2.98 mol SO2?
SOLUTION:
DALTON’S LAW OF PARTIAL PRESSURES
SAMPLE PROBLEM
1. A gas sample whose total pressure is 1512 torr, what are the partial pressures if the following
component gases: 2.70 mol N2, 6.90 mol CO2, 8.76 mol H2, and 2.98 mol SO2?
SOLUTION:
DALTON’S LAW OF PARTIAL PRESSURES
SAMPLE PROBLEM
1. A gas sample whose total pressure is 1512 torr, what are the partial pressures if the following
component gases: 2.70 mol N2, 6.90 mol CO2, 8.76 mol H2, and 2.98 mol SO2?
SOLUTION:
DALTON’S LAW OF PARTIAL PRESSURES
SAMPLE PROBLEM
1. A gas sample whose total pressure is 1512 torr, what are the partial pressures if the following
component gases: 2.70 mol N2, 6.90 mol CO2, 8.76 mol H2, and 2.98 mol SO2?
SOLUTION:
DALTON’S LAW OF PARTIAL PRESSURES
SAMPLE PROBLEM
1. A gas sample whose total pressure is 1512 torr, what are the partial pressures if the following
component gases: 2.70 mol N2, 6.90 mol CO2, 8.76 mol H2, and 2.98 mol SO2?
SOLUTION:
DALTON’S LAW OF PARTIAL PRESSURES
SAMPLE PROBLEM
1. A gas sample whose total pressure is 1512 torr, what are the partial pressures if the following
component gases: 2.70 mol N2, 6.90 mol CO2, 8.76 mol H2, and 2.98 mol SO2?
SOLUTION:
DALTON’S LAW OF PARTIAL PRESSURES
SAMPLE PROBLEM
1. A gas sample whose total pressure is 1512 torr, what are the partial pressures if the following
component gases: 2.70 mol N2, 6.90 mol CO2, 8.76 mol H2, and 2.98 mol SO2?
ANSWER:
Sample Problem
• A storage tank contains 2 moles of Ar, 3 moles of O2, and 5 moles of N2 at a total
pressure of 1000 torr. Calculate the partial pressure of each gas.
• 56 g of N2 and 96 g of O2 are mixed in a 2.0 L container at 300K. Calculate the
partial pressure of each gas and the total pressure.
• A storage tank contains Nitrogen, Oxygen, and Carbon Dioxide. The partial
pressure of Nitrogen and Oxygen gas are 600 torr and 150 torr. The total pressure
is 825 torr. What is the partial pressure and mole fraction of Carbon Dioxide?