Minamata Mercury Diseases (Presentation)

Download as ppt, pdf, or txt
Download as ppt, pdf, or txt
You are on page 1of 34

The Town of Minamata

• Located on the coast of


the Yatsushiro Sea in
southwestern Japan.
• The village was very
poor.
– Mostly fishermen and
farmers.
• Villagers welcome
Chisso Corporation http://www.jnto.go.jp/tourism/img/map/86.gif
Chisso Corporation
• Chisso = nitrogen
– Produced fertilizer
• 1907: Chisso Corp. builds
a fertilizer plant in the
Minamata.
• Job openings
• 1925: plant begins
dumping untreated
wastewater into http://www.japanfocus.org/images/592-3.jpg

Minamata Bay
– Kills fish
– Fisherman Payoffs
Chisso Corporation
• 1932: Chisso plant begins to
produce acetaldehyde to be
used in the production of
plastic, perfume and drugs.
• Acetaldehyde is made from
acetylene and water with a
mercury catalyst.
• After WWII plastic
production boomed and
Chisso Corp. grew.
• By 1970: Chisso brought
Japan 60% of its income and
owned nearly 70% of the
land in Minamata.
http://www-personal.umich.edu/~tobin/Smith2.jpg
Bizarre Behavior in Animals
• Early 1950’s:
– Dead fish wash ashore
– Crows fall out of sky
– Suicidal dancing cats
• Mercury moves up the
food chain.

http://flickr.com/photos/tropicalrips/127535537/
Mid 1950’s: Behavior Seen in Humans
• Behaviors witnessed:
– Loss of motor control in
hands
– Violent tremors
– Swaggered walk
– Insanity
• “Cat-dancing” disease
• Nobody knew the cause
of the epidemic.
– Many hid for fear of
ridicule
http://www.hamline.edu/personal/amurphy01/es110/eswebsite/Proj
ectsSpring03/ebarker/Minamata%20Web%20Page.htm
Putting the Pieces Together
• 1956: Researchers at
Chisso Corp. Hospital
experiment on cats with
wastewater from the
Chisso plant.
• They warn Chisso corp.
• Chisso corp. redirects the
flow of wastewater to
avoid being caught.
– A larger geographical area
contaminated.
– Children born with http://www.nimd.go.jp/archives/english/tenji/a_corner/image/hasseimap.gif

horrifying deformities.
Putting the Pieces Together
• 1968: Government ran
Public Health service traces
the contamination to the
Minamata Chisso plant.
• Government halts the
production of acetaldehyde
• 1972: Government
publically announces Chisso http://www.icett.or.jp/lpca_jp.nsf/505b1fe895fd2a8c492567ca000d587d/e
35dc782654b21d7492567ca000d8c50?OpenDocument
Corp’s part in the Minamata
epidemic and orders Chisso
Corp to pay compensation
to the families that were
affected.
The Aftermath
• 30-70 tons of methyl
mercury was dumped
into the Bay
• 10,000 people affected by
Minamata disease.
– 3,000 died
• Compensation has been
given to families as http://www.physorg.com/news110359851.html

recently as 1990.
– Highest compensation for
the disaster was just under
$3,000.
Centers for Disease Control and Prevention
Methylmercury :
In the Body
• Methylmercury exposure in
humans is from
consumption of fish, marine
mammals, and crustaceans
• 95% of fish-derived
methylmercury is absorbed
into the gastrointestinal
tract and distributed
throughout the body
– Highest in concentration in
hair

www.mercury.utah.gov/images/health_effects.jpg
Minamata Disease in the
Nervous System
Areas in red show areas typically affected
by the presence of methylmercury in
the system . The lesions show
characteristic signs and symptoms in
Minamata disease.
1. Gait disturbance, loss of balance
(ataxia), speech disturbance
(Dysarthria)
2. Sight disturbance of peripheral areas
in the visual fields (constriction of
visual fields)
3. Stereo anesthesia (Disturbance of
sensation)
4. Muscle weakness, muscle cramp
(disturbance of movement)
5. Hardness of hearing (hearing
disturbance)
6. Disturbance of sense of pain, touch or
temperature (Disturbance of
sensation)

National institute of Minamata Disease Archives


Symptoms of the Disease
• Mild
– Ataxia
– Muscle weakness
– Narrowed field of vision
– Hearing and speech
damage
• Severe cases cause
– Insanity
– Paralysis
– Coma
– Death
W. Eugene Smith
Tomoko Uemura in Her Bath
Minamata, 1972
More Symptoms
• A significant effect of
Minamata is the onset of
symptoms similar to
those of cerebral palsy
• Fetal Minamata Disease
– A pregnant mother ingests
toxic fish and the
methylmercury
concetrates inside the
placenta.
– Harms the fetus while the
mother is relatively
unaffected
http://picasaweb.google.com/jazzyv0504/SA
KURA#5065603192708172658
These are all children with congenital (fetal) Minamata Disease
due to intrauterine methyl mercury poisoning (Harda 1986).
Mercury: The Basics
• Mercury (Hg) is the only metal
that is liquid at room
temperature. It melts at
-38.9oC and boils at 356.6oC.
• Mercury conducts electricity,
expands uniformly with
temperature and easily forms
alloys with other metals (called
amalgams).
– For these reasons, it is used in
many products found in homes
and schools.
Mercury Chemistry
• Mercury exists in three
oxidation states:
– Hg0 (elemental mercury).
– Hg22+ (mercurous).
– Hg2+ (mercuric).
• Mercurous and mercuric
form numerous inorganic
and organic chemical
compounds.
– Organic forms of mercury,
especially methyl mercury,
CH3Hg(II)X, where “X” is a
ligand (typically Cl- or OH-) are
the most toxic forms.
Uses of Mercury
• We use its unique properties to
conduct electricity, measure
temperature and pressure, act
as a biocide, preservative and
disinfectant and catalyze
reactions.
– It is the use of mercury in
catalysis that contributed to the
events in Minamata.
• Other uses include batteries,
pesticides, fungicides, dyes and
pigments, and the scientific
apparati.
Mercury in the Environment
• Upwards of 70% of the mercury in
the environment comes from
anthropogenic sources, including:
– Metal processing, waste
incineration, and coal-powered
plants.
• Natural sources include volcanoes,
natural mercury deposits, and
volatilization from the ocean.
• Estimates are that human sources
have nearly doubled or tripled the
amount of mercury in the
atmosphere.
The Aquatic Mercury Cycle
Cleaning up
• The Minamata Spill
– Dredging
• Other ways of cleaning mercury spill
– United States
• Experimental ways
– Ongoing Research
Minamata Cleanup
• What’s is Dredging?
– Underwater excavation
Minamata Cleanup
• Dredging
– Types
• Mechanical
• Hydraulic
• Airlift Mechanical Hydraulic

Airlift
Minamata Cleanup
• Disposal of Sediment
– Landfills
– Disposal facility
– Ocean placement
– Confined Disposal Recycling
Facilities (CDFs)

Separation
U.S. Mercury Cleanups
• Precipitation/ Co precipitation
• Absorption treatment
• Membrane Filtration
• Biological treatment
Other ways of Clean Up
• Capping of Mercury – contaminated Sediments
w/ sand
• Inhibition of Mercury Methylation by Iron
Sulfides
• Immobilization of Aqueous Hg (II) by Iron
Sulfides
Experimental Research
• Nanotechnology
• Phytoremediation
• Air Stripping
• In Situ Thermal Desorption (ISTD)
Minamata Bay Today

• Eco Park of Minamata Bay has 2 purposes


– A stone memorial
– Landfill for Mercury
Questions???
References
Allchin, Douglas. "The Poisoning of Minamata." SHiPS. 22 Nov 2008
<http://www1.umn.edu/ships/ethics/minamata.htm>.
"Minamata disaster far from over." 30 Sept 2007. CNN. 22 Nov 2008
<http://www.cnn.com/2007/WORLD/asiapcf/09/30/japan.eco
disaster.ap/index.html>.
"Minamata, Japan ." Mercury Technology Services. 22 Nov 2008
<http://www.hgtech.com/Information/Minamata_Japan.html>.
"Minamata: The unfolding mercury disaster." Corrosion Doctors. 22 Nov 2008
<http://corrosion-doctors.org/Elements- Toxic/Minamata-1.htm>.
"Outline of Minamata Disease: 1. Cause and Damage of Minamata Disease."
Minamata Disease Archives. National Institute for Minamata Disease . 22
Nov 2008
<http://www.nimd.go.jp/archives/english/tenji/a_corner/a01.html>.
Thorpe, Thomas. A Dictionary of Applied Chemistry . revised. London,
England: Longmans, Greens and Co., 1921.
The End
Thank you!!

You might also like