Incoming JR Chemistry Worksheet-5 (Day-5) : KOH CO O CO N

INCOMING JR CHEMISTRY WORKSHEET-5(DAY-5)
1. 50 vol of a gas X is mixed with 70 vol of oxygen. After explosion the gas is
passed through KOH , 45 vol. of oxygen is left. What is the gas X?
(A) CO2 (B) O2 (C) CO (D) N2
2. 10 mL of gaseous organic compound consisting C, H and O only was mixed

with 100 mL of O2 and exploded under identical conditions and then cooled.
The volume left after cooling was 90 mL. On treatment with KOH a
contraction of 20 mL was observed. If vapour density of compound is 23,
derive molecular formula of the compound.
(A) C3H6O (B) C2H4O (C) C2H6O (D) C3H8O
3. 5 mL of a gaseous hydrocarbon was exploded with 30 mL of oxygen. The

resultant gases on cooling is found to measure 25 mL of which 10 mL are
absorbed by KOH and remaining gas by pyrogallol. Molecular formula of
hydrocarbon is
(A) C 3H8 (B) C 2H4 (C) C 2H6 (D) C 3H6
4. A sample of coal gas contained H2, CH4, and CO. 20 mL of this mixture was
exploded with 80 mL of oxygen. On cooling, the volume of gases was 68 mL.
There was a contraction of 10 mL when treated with KOH. Volume of O 2
consumed in explosion is
(A) 40 mL (B) 15 mL (C) 22 mL (D) 32mL
5. 25 mL of a mixture of hydrogen, methane and carbon dioxide were exploded

with 25 mL of oxygen and the total volume decreased to 17.5 mL. On
treatment with potash solution, the volume further decreased to 7.5 mL.
Volume of CO2 in the original mixture is
(A) 10 mL (B) 5 mL (C) 15 mL (D) 20 mL
6. The percentage by volume of C3H8 in a mixture of C3H8, CH4 and CO is 36.5.

The volume of CO2 produced when 100 mL of the mixture is burnt in excess
of O2 is
(A) 173 mL (B) 200 mL (C) 152 mL (D) 132 mL
7. 15 mL of an oxide of nitrogen was taken in eudiometer tube and mixed with

H2 till the volume was 42 mL. After sparking, to the resulting mixture10 mL
of O2 was added and exploded again to consume unreacted H2 . The volume
fell to 19mL. The formula of oxide is (both explosions led to the formation of
H2O only)
(A) NO2 (B) N2O5 (C) N2O (D) N2O3
8. 50 mL of a mixture of NH3 and H2 was completely decomposed by sparking
into nitrogen and hydrogen. 40 mL of oxygen was then added and the mixture
was sparked again. After cooling to the room temperature, the mixture was
shaken with alkaline pyrogallol and a contraction of 6 mL was observed. The
percentage of ammonia in the original mixture is
(A) 72% (B) 60% (C) 45% (D) 28%
9. A mixture of 20 ml of methane and 20 ml of O2 is exploded and cooled to

room temperature. If the reaction between the two substances is written as
CH4 + 2O2 ⎯⎯→ CO2 + 2H2O
Final volume of gaseous mixture is
(A) 10 ml (B) 20 ml (C) 30 ml (D) 60 ml
10. A mixture is made equal volume of CO and air. A spark passed through so
that all the oxygen is converted to carbon dioxide. What will be fractional
decrease in the total volume of system assuming pressure and temperature
remain constant? (air contains 20 % oxygen by volume.)
A) 0.1 B) 0.2 C) 0.15 D) 0.3
11. 30 mL of CO was exploded with V mL of oxygen and 35 mL of gases

remained. What is the value of V?
A) 5 B) 50 C) 20 D) 30
12. 60 mL of a mixture of nitrous oxide and nitric oxide was exploded with
excess hydrogen. If 38 mL of N2 was formed, the volume of nitrous oxide
in the original mixture is
A) 16 mL B) 44 mL C) 27 mL D) 33 mL
13. When a 12 g mixture of carbon and sulphur is burnt in air, then a mixture of
CO2 and SO2 is produced, in which the number of moles of SO2 is half that of
CO2 . The mass of the carbon in the mixture is :
A) 4.08 g B) 5.14 g C) 8.74 g D) 1.54 g
PASSAGE-1
18 mL of a gaseous mixture consisting of a gaseous organic compound, A,
and just sufficient amount of oxygen required for complete combustion
yielding on burning 8 mL of CO2 , 12 mL of water vapour and 4 mL of N2 .
All volumes are measured at the same temperature and pressure. The
compound A consists only carbon, hydrogen and nitrogen.
14. How many volumes of oxygen are required for complete combustion?
A) 4 mL B) 14 mL C) 7 mL D) 11 mL
15. What is the molecular formula of the compound?

A) CH5N B) C2H5N C) C2H6N2 D) C 4H10 N2
16. What volume of H2 gas, measured at the same temperature and pressure, is
needed for complete reduction of the same volume of compound A?
A) 4 mL B) 8 mL C) 28 mL D) 14 mL
17. The volume in litre of CO2 liberated at STP when 10 g of 90% pure
limestone is heated completely is
(A) 2.016 (B) 20.16 (C) 2.24 (D) 22.4
18. What is the volume of oxygen obtained at STP when 24.52 gram of KClO3 is
strongly heated?
(A) 22.4 lit (B) 44.8 lit (C) 6.72 lit (D) 2.24 lit
19. How much of Sulphur is present in an organic compound, if 0.53 g
compound gave 1.158 g of BaSO4 on analysis? (In estimation of Sulphur in
the organic compound it is completely converted to BaSO 4) (At wt. Of Ba is
137)
(1) 10% (2) 15% (3) 20% (4) 30%
20. How many moles of lead (II) chloride will be formed from a reaction
between 6.5 g of PbO and 3.2 g of HCl? (Atomic mass of lead is 207)
(1) 0.011 (2) 0.029 (3) 0.044 (4) 0.333
21. 254g of iodine and 142g of chlorine are made to react completely to give a
mixture of ICl and ICl3 . The moles of each one formed is
(1) 0.1 ICl and 0.1 mol ICl3 (2) 1.0 mol ICl and 1.0 mol ICl3
(3) 0.5 ICl and 0.1 mol ICl3 (4) 0.5 mol ICl and 1.0 mol ICl3
22. 0.1mole of a compound containing Sulphur and chlorine is subjected to a
number of chemical reactions, which resulted in the precipitation of 0.1mole
of PbCl2 and 0.2 mole of PbSO4. The molecular formula of the compound is
(1) S2Cl2 (2) SCl2 (3) SCl4 (4) S2Cl
23. In the reaction, 4 NH3 + 5O2 → 4 NO + 6H 2O , when one mole of ammonia and
one mole of oxygen are made to react to completion, then
(1) 1.0 mole of H 2O is produced
(2) All the oxygen is consumed
(3) 1.5 mole of NO is formed
(4) All the ammonia is consumed
24. A sample of a mixture of CaCl2 and NaCl weighing 4.22 g was treated to
precipitate all the Ca as CaCO3 . This CaCO3 is then heated and quantitatively
converted into 0.959 g of CaO. Calculate the percentage of CaCl2 in the
mixture. (atomic mass of Ca=40, O=16, C=12, and Cl=35.5)
1)31.5% 2)21.5% 3)45.04% 4)68.48%
25. The volume of air needed to burning 12g carbon completely at STP is
(volume of O2 in air is 20%):
1)22.4 litre 2)112 litre 3)44.8litre 4)50litre
26. The maximum amount of BaSO4 that can be obtained on mixing 0.5 mole
BaCl2 with 1 mole of H2SO4 is :
(A) 0.5 mol (B) 0.1 mol (C) 0.15 mol
(D) 0.2 mol
27. Phosphine (PH3) decomposes to produce vapours of phosphorus and H2
gas. What will be the change in volume when 100 mL of phophine is
decomposed.
(A) + 50 mL (B) +500 mL (C) +75 mL
(D) –500 mL
28. In the reaction , 4 A + 2B + 3C → A4 B2C3 . What will be the number of moles of
product formed, starting from
one mole of A, 0.6 mole of B and 0.72 mole of C.
(A) 0.25 (B) 0.3 (C) 0.24 (D) 2.32
COMPREHENSION TYPE
10 mol of SO2 and 4 mol of O2 are mixed in a closed vessel of volume 2 L.

The mixture is heated in presence of Pt catalyst, following reaction takes
place. 2SO2 ( g ) + O2 ( g ) → 2SO3 ( g ) Assuming the reaction proceeds to
completion
29. Select the correct statement

(A) SO2 is the limiting reagent (B) O2 is the limiting reagent
(C) Both SO2 and O2 are limiting (D) cannot be predicted
30. Number of moles of SO3 formed in the reaction will be

(A) 10 (B) 4 (C) 8 (D) 14
31. Number of moles of excess reactant remaining

(A) 4 (B) 2 (C) 6 (D) 8
32. A mixture of HCOOH and H2C2O4 is heated with conc. H2SO4 . The gas
produced is collected and on treating with KOH solution the volume of gas
decreases by 1/6th. The molar ratio of HCOOH and H2C2O4 in the original
mixture is
(HCOOH ⎯⎯⎯⎯⎯→CO, H C O
con H2SO4
− H2O 2 2 4
con H2SO4
⎯⎯⎯⎯⎯
−H2O
→ CO + CO2 )
(A) 4:1 (B) 1:4 (C) 3:1 (D) 2:1
Key
1 2 3 4 5 6 7 8 9 10
C C B C B A C A B A
11 12 13 14 15 16 17 18 19 20
C A B B C A A C 4 2
21 22 23 24 25 26 27 28 29 30
2 1 2 3 2 A C C B C
31 32
B A

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INCOMING JR CHEMISTRY WORKSHEET-5(DAY-5)

2. 10 mL of gaseous organic compound consisting C, H and O only was mixed

3. 5 mL of a gaseous hydrocarbon was exploded with 30 mL of oxygen. The

5. 25 mL of a mixture of hydrogen, methane and carbon dioxide were exploded

6. The percentage by volume of C3H8 in a mixture of C3H8, CH4 and CO is 36.5.

7. 15 mL of an oxide of nitrogen was taken in eudiometer tube and mixed with

9. A mixture of 20 ml of methane and 20 ml of O2 is exploded and cooled to

11. 30 mL of CO was exploded with V mL of oxygen and 35 mL of gases

15. What is the molecular formula of the compound?

19. How much of Sulphur is present in an organic compound, if 0.53 g

compound gave 1.158 g of BaSO4 on analysis? (In estimation of Sulphur in

the organic compound it is completely converted to BaSO 4) (At wt. Of Ba is

(1) 10% (2) 15% (3) 20% (4) 30%

10 mol of SO2 and 4 mol of O2 are mixed in a closed vessel of volume 2 L.

29. Select the correct statement

30. Number of moles of SO3 formed in the reaction will be

31. Number of moles of excess reactant remaining

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