FIRST YEAR WORKSHEET

` KKP / MYP CEN TRE

SINGLE CORRECT:

1. The empirical formula of an organic compound containing carbon and hydrogen is CH2. The mass of one
litre of this organic gas is exactly equal to that of one litre of N2. Therefore the molecular formula of the
organic gas is
(A) C2H4 (B) C3H6 (C) C6H12 (D) C4H8

2. 4.4g of CO2 and 2.24 litre of H2 at STP are mixed in a container, the total number of molecules present in
the container will be
(A) 6.022  1023 (B) 1.2044  1023 (C) 2 mole (D) 6.022  1024

3. 1.8 litre of a mixture of CO and CO2 was passed through red hot charcoal. The volume of the gas mixture
after complete reaction became 2.4 litre. How many litre of CO was present in the mixture?
Charcoal
CO2 CO
CO 
Cha
rco
al Noreaction

(A) 0.8 L (B) 1.2 L (C) 0.6 L (D) 1.8 L

4. Find the ratio of no of molecules contained in 1gm of NH3 and 1 gm N2

(A) 20 : 17 (B) 28 : 17 (C) 17 : 28 (D) 14 : 17

5. A sample of lime stone contain 20% water. On partial drying it lost 10 gms of water and now the sample
contained 10% of water. What would be the total volume of CO2 liberated at STP if partially dried sample is
decomposed by heat completely (assume sample contain water and CaCO3 only) ?
(A) 16.13 lit (B) 28.9 lit (C) 10.4 lit (D) 7.08 lit

ONE OR MORE THAN ONE CORRECT:

6. P and Q are two elements which forms P2Q3 and PQ2 . If 0.15 mole of P2Q3 weighs 15.9g and 0.15 mole
of PQ2 weighs 9.3g
(A) atomic weight of P is 18 (B) atomic weight of P is 26
(C) atomic weight of Q is 18 (D) atomic weight of Q is 26

7. Which of the following gases of 11.2 L volume at STP , will weigh 14g?
(A) N2O (B) NO2 (C) N2 (D) CO

8. Which of the following sample has same number of atoms as in 1 mole of hydrogen gas?
(A) 0.5 mole SO3 (B) 2  6.023 1023 He atoms
(C) 22.42 L of nitrogen gas (D) 10 L of hydrogen gas

9. Which of the following statement is correct for decomposition of NaHCO3 ?

NaHCO3 

Na2 CO3  CO2  H2O
(A) 84g of NaHCO3 gives 106g of Na2CO3
(B) 16.8g of NaHCO3 gives 0.1 mole of Na2CO3
(C) 0.1 mole of NaHCO3 gives 1.12L of CO2 at STP
(D) 84g of NaHCO3 gives 22.4L of CO2 at STP
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10. How many of the following samples have same number of oxygen atoms as in 56 g of CO
(A) 40.83g of KClO3 (B) 44g of CO2 (C) 64g of SO2 (D) 32g of O2

11. How many of the following samples have 2 gram atoms of oxygen.
(A) 32g of oxygen (B) 44.8L of oxygen at STP
(C) 16g of oxygen (D) 22.4L of oxygen at STP

12. How many of the following statement is/are incorrect?

(A) Gram atomic weight of oxygen is 16 amu
(B) Gram molecular weight of oxygen is 16g
(C) Relative atomic weight of oxygen is 16 amu
(D) Relative molecular weight of oxygen is 32 amu

13. How many of the following reactions require more than 67.2L of oxygen at STP per one mole of reactant.
(A) CH4  O2  CO2  H2O (B) C2H6  O2  CO2  H2O
(C) N2  O2  NO (D) C4H8  O2  CO2  H2O

14. From 440g of CO2 sample, 24.092 1023 molecules were removed. Identify the correct statement?
(A) The number of moles of CO2 left is 6
(B) The mass of CO2 left is 264g
(C) 178g of CO2 is removed from the sample
(D) In the original sample, 20N0 oxygen atoms were present

15. In a container 1.6g. of CH4 , 1.7g. of NH3 and 1.8g. of H2O are present.
Select correct the statement
(A) There are equal number of moles of each reactant
(B) The order of total number of atoms is CH4  NH3  H2O
(C) Total number of H atoms are in the ratio of 4 : 3 : 2
(D) The number of C, N,O atoms in above sample is in the increasing order

NUMERICAL: 
16. The average molar mass of a mixture of methane CH4  and ethane C2H6  present in the ratio of a:b
found to be 20 g. mol1 . If the ratio reversed what would be the molar mass of the mixture

17. The vapour density of a mixture of NO2 and N2O4 is 38.3 at 26.7 C . Calculate the number of moles of
NO2 in 100 gram of the mixture?

18. In a container, 88g of CO2 gas, 44.8 L of N2 gas at STP and 12.046  1023 molecules are present. Total

number of molecules in the container are x  10  . The value of x4 is

23

19. The number of oxygen molecules in 96 amu sample is _.

20. When 4.9g of 100% pure KClO3 is decomposed according to the following equation.
KClO3  KCl  O2
The number of moles of O2 formed is A 102 . The value of A is

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 21. The number of milli moles in 0.088g of CO2 is

22. 5L of ozone is converted to oxygen. At the end of reaction, the volume of mixture becomes 7L . The
volume of ozone, left at the end (in L)
O3g  O2g 


23. How many of the following samples have more than (or) equal to 2N0 atoms.
(i) 28g of N2 (ii) 22.4L of He gas (iii) 32g of O2
(iv) 44.8L of Ar (v) 22g of CO2 (vi) 11.22g of CO
(vii) 106g of Na2CO3 (viii) 1g of hydrogen (ix) 98g of H2SO4

24. The volume of O2 (in L) required at STP to completely oxidise 4L of CO is .

25. The measured density at NTP of He is 0.1784 gL1 . Calculate the weight of 1 mole of He .

26. An element has atomic mass 31u. 6.2 g. vapours of this element occupy 1.12 L at STP. The atomicity of
element is

27. A gaseous alkane CnH2n2  is reacted with oxygen. The volume of O2 for complete combustion to
CO2 formed is in the ratio of 7 : 4 . Find the value of n .

PARAGRAPH-1

A 4.925 g sample of a mixture of CuCl2 and CuBr2 was dissolved in water and mixed thoroughly with a
5.74g protion of AgCl. After the reaction the solid, a mixture of AgCl, and AgBr, was filtered, washed, and
dried. Its mass was found to be 6.63 g.

28. % By mass of CuBr2 in original mixture is

(A) 2.24 (B) 74.5 (C) 45.3 (D) None

29. No. of moles of Cl ion present in the solution after precipitation are
(A) 0.06 (B) 0.02 (C) 0.04 (D) None

MATRIX MACTH

30. Bunty & Bubby have two separate containers one having N2 gas & other H2 gas: It is known that N2 & H2
react to give N2H2 𝑙 and/or N2H4 g depending upon the ratio in which N2 & H2 are taken & that N2H2
reacts with H2 to give N2H4 . Formation of 1 mole of N2H4 requires 30 units of energy & formation of 1 mole
of N2H2 𝑙 release 30 units of energy. From this information match Column-I (representing composition of
gases taken) with Column-II (representing the observation)
Column-I (Composition of gases) Column-II (Observation)
(A) 40 lit N2 & 30 lit H2 (same temperature & pressure) (P) Contraction by 22.4 lit
(B) 11.2 lit of N2 & H2 taken at 1 atm & 273 K in a ratio such that (Q) Contraction by 20 lit
max. release of energy is observed
(C) 11.2 lit of N2 & 30 lit of H2 (same temperature & pressure) (R) Contraction by 60 lit

(D) 10 lit of N2 & more than 22.4 lit of H2 (same temperature & (S) Contraction by 11.2 lit
pressure)

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