Scribd Logo
Upload

Welcome to Scribd!

  • 13 views

    Descriptive Paper 403

    Uploaded by

    Abid Ali
    This document contains a chemistry exam with multiple questions covering various thermodynamics topics: 1. Calculating heat, work, and changes in internal energy and enthalpy for the compression of air along two paths. 2. Determining the final temperature of ethylene undergoing heating at constant pressure. 3. Calculating the standard heat of reaction for a combustion reaction. The exam also includes questions on differentiating reversible and irreversible processes, deriving the sensible heat integral expression, justifying the path dependence of work, and calculating heat and work for a multi-step thermodynamic process. The final question involves calculating the heat removal required for an exothermic catalytic

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd

    Descriptive Paper 403

    Uploaded by

    Abid Ali
    13 views2 pages
    This document contains a chemistry exam with multiple questions covering various thermodynamics topics: 1. Calculating heat, work, and changes in internal energy and enthalpy for the compression of air along two paths. 2. Determining the final temperature of ethylene undergoing heating at constant pressure. 3. Calculating the standard heat of reaction for a combustion reaction. The exam also includes questions on differentiating reversible and irreversible processes, deriving the sensible heat integral expression, justifying the path dependence of work, and calculating heat and work for a multi-step thermodynamic process. The final question involves calculating the heat removal required for an exothermic catalytic

    Original Description:

    Applied Chemistry 403 Model paper

    Original Title

    descriptive paper 403

    Copyright

    © © All Rights Reserved

    Available Formats

    DOCX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    This document contains a chemistry exam with multiple questions covering various thermodynamics topics: 1. Calculating heat, work, and changes in internal energy and enthalpy for the compression of air along two paths. 2. Determining the final temperature of ethylene undergoing heating at constant pressure. 3. Calculating the standard heat of reaction for a combustion reaction. The exam also includes questions on differentiating reversible and irreversible processes, deriving the sensible heat integral expression, justifying the path dependence of work, and calculating heat and work for a multi-step thermodynamic process. The final question involves calculating the heat removal required for an exothermic catalytic

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    13 views2 pages

    Descriptive Paper 403

    Uploaded by

    Abid Ali
    This document contains a chemistry exam with multiple questions covering various thermodynamics topics: 1. Calculating heat, work, and changes in internal energy and enthalpy for the compression of air along two paths. 2. Determining the final temperature of ethylene undergoing heating at constant pressure. 3. Calculating the standard heat of reaction for a combustion reaction. The exam also includes questions on differentiating reversible and irreversible processes, deriving the sensible heat integral expression, justifying the path dependence of work, and calculating heat and work for a multi-step thermodynamic process. The final question involves calculating the heat removal required for an exothermic catalytic

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 2

    DEPARTMENT OF APPLIED CHEMISTRY AND CHEMICAL TECHNOLOGY

    UNIVERSITY OF KARACHI

    Total Marks: 30 Course # 403 Total Time: 2hr 30min

    Note: Return this question paper along with answer sheet; otherwise it will not be evaluated.

    Name :__________________________ Father Name: ______________________________

    Roll #: __________________________

    1. (i) Air at 1 bar and 298.15 K (25°C) is compressed to 5 bar and 298.15 K by two different
    mechanically reversible processes:.

    (a) Cooling at constant pressure followed by heating at constant volume.

    Calculate the heat and work requirements and ΔU and ΔH of the air for each path. The following
    heat capacities for air may be assumed independent of temperature:

    Cv=20.78 J mol-1 K-1 and Cp=29.10 J mol-1 K-1

    Assume also for air that PV/T is a constant, regardless of the changes it undergoes. At 298.15 K and 1
    bar the molar volume of air is 0.02479 m 3 mol-1. (3)

    (ii) For steady flow through a heat exchanger at approximately atmospheric pressure, what is the
    final temperature when heat in the amount of 800KJ is added to 10 mol of ethylene initially at
    200°C? (7)

    (iii) Calculate the standard heat of the following reaction at 25°C:

    4NH3(g) + 5O2(g) 4NO(g) + 6H2O(g) (2)

    2. (i) Differentiate reversible and irreversible process. (any 2 points) (2)

    (ii) Derive the expression of the Sensible-Heat Integral. (4)

    (iv) “Work done depend on the nature of the process. It is path dependent”. Justify the statement
    graphically. (2)

    (iii) When a system is taken from a to b along path acb, 100 J of heat flows into the system and the
    system does 40 J of work.

    C b

    P d

    a e

    (a) How much heat flows into the system along path aeb if the work done by the system is 20 J?
    (b) The system returns from b to a along path bda. If the work done on the system is 30 J, does
    the system absorb or liberate heat? How much? (4)

    3. (i) If reversible process is an imaginary process than why we give so much importance to this
    process? (2)

    (ii) When liquid water in equilibrium with a mixture of water vapour and nitrogen, calculate the
    degree of freedom of the system? (2)

    (III) The gas stream from a sulfur burner consists of 15 mol% SO 2, 20 mol% O2, and 65 mol% N2. The
    gas stream at atmospheric pressure and 400°C enters a catalytic converter where 86% of the SO 2 is
    further oxidized to SO3. On the basis of 1mol of gas entering, how much heat must be removed from
    the converter so that the product gasesleave at 500°C? (8)

    All the best 

    You might also like