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Article History
Received: 27 October 2021; Received in Revision: 10 March 2022; Accepted: 7 April 2022
Abstract
The metallurgical testings to treat the Kenyan artisanal gold mining samples were performed
with several processes such as gravity concentration (i.e., Knelson Concentrator and panning),
flotation, and cyanidation or leaching. These tests were conducted to find the best processing
stages to improve the Kenyan artisanal mining recovery. Of the three categories of samples
treated, sample A, which was processed through gravity concentration and flotation, produced
95.64% of gold recovery. Meanwhile, sample B could produce 98.74% of gold recovery with the
cyanidation test. The results from sample A and sample B confirmed that the combination of
the Knelson concentrator and flotation, which the Processing Center should handle, was the
perfect combination to reduce the use of cyanide during the leaching process. On the other
hand, the study also showed that the tailing sample (sample C) could still be recovered through
flotation. With the results obtained, the best scenario was proposed. The government played a
critical role in facilitating both the artisanal miners and the Processing Center for both cases in
Kenya or Aceh.
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Izzan Nur Aslam et al. / Jurnal Rekayasa Kimia dan Lingkungan, Vol. 17, No. 1, January - June 2022
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Total 25540.1
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A Gravity Recoverable Gold (GRG) testing The leaching or cyanidation process was
process conducted consisted of two methods: conducted only for sample B. This was to
(1) primary gravity concentration and (2) extract, purify, and recover more gold from
secondary gravity concentration. According to the flotation tailing. The pH condition set up
Dominy (2014), an ore sample's recovery for the leaching test was 11 to prevent the
from Gravity Recoverable Gold (GRG) production of HCN gas and another reaction if
indicates the ore sample's amenability to the the pH was below nine and higher than 11.5,
gravity concentration method. In this study, respectively. The leaching process was done
the primary gravity concentration was inside the beaker glass equipped with the
performed using Knelson Concentrator Model agitator to increase the reaction kinetics and
KC-MD3 manufactured in Langley, British improve the extraction. The tailing product
Columbia. This is due to its high-mass yield obtained was sent for fire assay. By using the
recovery (McLeavy et al., 2001). head grade, the result was back-calculated to
get the concentrate grade. The operating
In addition, to improve the recovery to over condition for the cyanidation test is
50%, the secondary gravity concentration was summarized in Table 5.
done by panning. For sample C, as it was
considered tailing material before the sample Table 5. Cyanidation test condition
was received, the gravity concentration would
not give a better recovery. Thus, the GRG test Variables Value Unit
was skipped for this sample, and the step
directly proceeded to the flotation test. Solids 300 g
Solution 450 g
Percent Solids 40 %
2.3. Flotation Test Slurry Wt 750 g
pH 8
The tailings from first and secondary gravity Bottle Wt 336.7 g
concentrations were mixed and concentrated
in the Metso flotation cell. More recovery was Figure 3 shows the treatment for Sample B in
expected to be achieved through this flotation which a leaching test was involved. The feed
test. For sample B, the flotation tailing was for the leaching test was obtained from the
sent for the leaching process to improve the tailings discharged from both gravity
recovery further. concentration processes.
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This additional procedure has made Sample recovery in the metallurgical balancing of
B's treatment different from the other two every test conducted.
samples (A and C), ( Figure 2 and Figure 4).
3. Results and Discussion
2.5. Drying
3.1. Testing Result for Sample A
The moisture content of the testing product
was filtered using Peterson Filters. To further As previously explained, there were two
reduce the moisture content as preparation for gravity concentration processes followed with
fire assay, Micropack Drying Oven was used to flotation conducted for sample A. The gravity
dry the materials. concentration tests used the Knelson
Concentrator and the panning method. The
2.6. Assaying & Metallurgical Balancing combined metallurgical balancing result of
gravity concentration and flotation tests for
During the project, 13 products were sent for sample A is summarized in Table 6.
fire assays. Fire assay is still a widely accepted
method for analyzing Platinum Group Metal After carrying out the metallurgical balance of
(PGE) and gold elements from low to medium sample A as shown in Table 6, it was found
grades. The fire assay procedure generally that the recovery for the gravity concentration
consists of fluxing and fusion, slag separation, concentrate was 71.72%, concerning the
cupellation, and complex analyses, which highest amount of concentrate grade. This
usually include gravimetric and instrumental number was considered amenable as using the
analysis. In this study, the result obtained Knelson Concentrator combined with panning
from the fire assay was used to calculate the should at least recover 57% of gold (Chen et
al., 2020).
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This number was considered amenable as The overall result for gravity concentration
using the Knelson Concentrator combined with and flotation obtained for sample B was
panning should at least recover 57% of gold 94.76%. When leaching was conducted, the
(Chen et al., 2020). improvement for the recovery only increased
by almost 4%. In this case, it can be said that
In terms of fire, the assay result compared sample B contains more free gold, which was
with the initial assay before the sample was already liberated since the gravity separation
received, as shown in Table 6 anda Table 2, process and is quite difficult to be recovered
the gravity concentration feed had almost during flotation and leaching.
similar percentages, 54.43 and 51.35 g/t. This
grade increased as there were more minerals 3.3. Testing Result for Sample C
liberated after the comminution process
conducted before the gravity concentration The result for sample C was only obtained
process. In this case, the total recovery of the from the flotation process as this was thought
gravity concentration produced from the as the only process appropriate due to the
metallurgical balance for sample A above least grade of the sample (< 2 g/t). From the
could be accepted. flotation test, it was obtained that the overall
recovery achieved was 82.74% (see Table 7).
Meanwhile, the recovery for only the flotation It is interesting to see in sample C that the
test obtained for sample A was 23.93% and sample grade increases dramatically from
4.36% for flotation concentrate and tailings, 3.43% to 18.49%. This proves that the tailing
respectively. This produced the final recovery still contains many valuable products, and it is
for the whole stages, including the gravity unfortunate if the miners do not process the
separation of sample A, which was 95.64%. It tailing and only discharge it as waste.
can be inferred from this result that panning
as the second treatment of the gravity 3.4. Comparison between Samples
separation could not give a significant result
as there was only a 4.35% of recovery Comparison made between the three samples
improvement from the tailing of both gravity shows interesting findings. First, sample A
separations to the concentration of the seems less liberated or less free gold than
flotation process. sample B. This is proved by the result obtained
for sample B that the recovery for only the
3.2. Testing Result for Sample B gravity concentration concentrate obtained
was 91.81%, which is significantly higher than
The result of the metallurgical balance for sample A of 71.72%. It is important to note
sample B is also shown in Table 6. According that before the treatment, the initial grade for
to Table 6, the recovery for only the gravity sample B before the test was conducted was
concentration concentrate obtained was roughly 10 – 17% lower than sample B (see e
91.81%. However, after being passed to the and Table 3).
flotation test, the results for sample B were
only 2.94 and 5.24% for concentrate and When the flotation tests between sample A
tailing, respectively. and B were compared, the results obtained
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were in line with the result of gravity devices, particularly for more disseminated
separation. This recovery for sample B was far gold or tailing. In the fair mechanism, as it is
lower than for sample A. Even though the quite costly to obtain a flotation device for the
Particle Size Distribution (PSD) shows an artisanal miners, the processing center should
insignificant difference in size, sample B was be in charge more.
finer than sample A. The flotation result
achieved for the concentrate of sample B was The ideal scenario proposed for Kenyan
only 2.94% compared to 23.94% of sample A. artisanal mining is that the government as the
Even if the leaching was conducted, the regulator should act as a mediator and clear
recovery only improved by 3.1%. the roles between the artisanal miners and the
processing center. At this point, artisanal
Additionally, for the three sample categories, miners can only process the ore through
the pH for the flotation process was panning and/or sell the unprocessed material
maintained between 9.1 to 9.6, and the limes (i.e., medium grade) and the tailing from the
added for samples A, B, and C were 0.7, 0.5, panning to the processing center in the
and 0.8, respectively. For sample A, due to the medium to high price range.
high grade of silver (>10 g/t) indicating the
presence of electrum, the greater reactivity of From this scenario, the artisanal miners can
silver may affect flotation (Marsden and double their incomes. At the same time, the
House, 2006). Hence, the flotation had to be processing center can gain more from the
controlled very well. Meanwhile, a comparison medium-grade and tailing using the flotation,
between sample C and the other sample could particularly as they own more capital and
not be made as the initial grade for sample C resources (i.e., cost, supporting equipment).
was far lower than both other samples. Even though deeper economic analysis is
needed, from the results presented in the
Table 7. Metallurgical balance for sample C. previous section, it is believed that the
processing center will not lose.
Weight Grade Yield Recovery
(g) (g/t) (%) (%)
With the scenario, the use of mercury for the
Feed 987.10 3.43 100.00 100
artisanal miners can be eliminated, and the
Conc.* 151.60 18.49 15.36 82.74
Tail* 835.50 0.70 84.64 17.26 cyanide usage (only for the processing center)
*Conc. = Concentrate, Tail = Tailing can be minimized due to the insignificant
improvement after being leached. This is in
3.5. Selecting the Best Processes line with the statement that the flotation
process could improve the process and reduce
From the discussion made in the previous the use of cyanide for the leaching process
sections, some suggestions can be proposed (Chen et al., 2020). As a result, the damage
for the Kenyan artisanal miners. Firstly, no to the environment can be reduced
processes can be chosen as a single significantly.
permanent solution. Every process depends
on the characteristic of the sample itself. Thus, 3.5. Lesson Learned for Acehnese Miners
to achieve the best mineral processing routes,
involvement, and cooperation of both the Regarding the deposit characteristic, the gold
artisanal miners and the processing center are samples used in this study originated from
needed. Nyanza, Kenya. The deposit is predominantly
from quartz veins and a few impregnations
Secondly, gravity concentration is more with a high proportion of alluvial gold (Pulfrey,
effective in processing medium to high-grade 1969). The gold is present in the electrum that
samples. If the miners could crush the sample contains silver, as shown in e and Table 3.
into the average size, e.g., over 100 microns,
their recovery will be significantly improved. The Nyanza site is located very close to Lake
However, this seems impossible as crushing Victoria in Kisumu. The area near Lake Victoria
and concentrating the ore can only be handled is a productive greenstones area, which lies
by the processing center, highly mechanized along the Migori Belt as part of a gold-enriched
equipment. In this case, the artisanal miners Archaean Tanzanian craton (Mshiu et al.,
still choose the panning process even though 2015). A study conducted showed that most
it is less effective. gold attachment is sulfide minerals in the form
of iron-sulfide also bounded with pyrrhotite,
The third suggestion that can be made is that molybdenite, sphalerite, and a small amount
the processing center should also have of arsenopyrite (Baris and Mutua, 2019; Mshiu
flotation equipment. The processing center et al., 2015).
can gain more gold by installing flotation
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This mineralization proves why more gold can as well as a safe and healthy living
be recovered just only with gravity environment around the mine site.
concentration and leaching. The existence of
most quartz, a harder rock, correlates with the References
PSD analysis of high-grade and tailing
samples. It took almost 25 – 30 minutes to Anyona, S., Rop, B., 2015. The character and
grind the material to liberate the ore. profile of artisanal and small-scale
gemstone mining community in Taita
In the case of Aceh, Indonesia, there is not Taveta county, Kenya, Proceedings of
much literature discussing the Acehnese gold Sustainable Research and Innovation
deposits. Some types of deposits mined Conference. Nairobi, Kenya, pp. 109-
traditionally, which the researchers 125.
highlighted, are epithermal, breccia, and
placer deposits, as stated by Maryono et al. Baris, G., Mutua, J., 2019. Validation of GIS
(2014), Mulja et al. (2003), dan Van Leeuwen Based Approach of Optimally Locating
(2014). In these cases, it is fair to say that the Exploration Targets during Gold
Acehnese artisanal mining activities and Exploration in Kakamega, Western
management should learn from the Kenyan Kenya, 2nd International Conference.
case. This can be at least by implementing a Machakos, Kenya.
centralized processing site (Processing
Chen, Q., Yang, H.-y., Tong, L.-l., Niu, H.-q.,
Center) to accommodate the miners.
Zhang, F.-s., Chen, G.-m., 2020.
Research and application of a Knelson
Suppose both optimizations on processing and
concentrator: A review. Miner. Eng.
implementation of centralized processing sites
152(2020), 106339. https://dx.doi.org/
are successfully applied in the future. Cyanide
10.1016/j.mineng.2020.106339.
consumption is reduced, and even zero
mercury can be achieved, as in the UN Hinton, J.J., Veiga, M.M., Veiga, A.T.C., 2003.
International Guidelines on Mercury Clean artisanal gold mining: a utopian
Management in Small-Scale Gold Mining approach? J. Clean. Prod. 11(2), 99-115.
(Spiegel and Veiga, 2010). However, those https://dx.doi.org/10.1016/ s0959-
suggestions indeed depend on the good 6526(02)00031-8.
intentions of the policymakers, miners, and
civil society to continue giving their best McLeavy, M., Klein, B., Grewal, I., 2001.
solutions in tackling the artisanal mining issue Knelson continuous variable discharge
(Putra, 2018). concentrator: Analysis of operating
variables, International Heavy Minerals
4. Conclusion Conference. Fremantle, Perth, Western
Australia, pp. 119-125.
From the study conducted, it can be learned
that gravity concentration, particularly Marsden, J., House, I., 2006. The chemistry of
panning, still shows very promising results if gold extraction, 2nd Edition ed. The
the scenario proposed is performed. Society for Mining, Metallurgy, and
Meanwhile, the combination of a highly Exploration, Inc., Littleton, Colorado,
mechanized Knelson concentrator and USA.
flotation is considered suitable to be applied Maryono, A., Natawidjaja, D.H., van Leeuwen,
by the Processing Centers due to the high T.M., Harrison, R.L., Santoso, B., 2014.
capital cost and more complex equipment. Sumatra, an emerging world-class
This also becomes the best solution to partially magmatic gold belt, Proceedings of
replace the cyanidation process as the process Sundaland Resources, 2014 MGEI Annual
can still recover some gold. The Processing Convention. Palembang, pp. 17-18.
Center can also recover more gold from the
tailing (sample C). Although the similarity Mshiu, E.E., Gläßer, C., Borg, G., 2015.
between the Acehnese and Kenyan artisanal Identification of hydrothermal paleofluid
mining cannot be made, mainly because there pathways, the pathfinders in the
is not much information related to the deposit exploration of mineral deposits: A case
characteristic, the Acehnese artisanal mining study from the Sukumaland Greenstone
should learn from the scenario proposed by Belt, Lake Victoria Gold Field, Tanzania.
Kenyan artisanal mining. In this case, if the Adv. Space Res. 55(4), 1117-1133.
government can maximize their roles, the https://dx.doi.org/10.1016/j.asr.2014.1
artisanal gold mining activities, in both cases, 1.024.
will lead to the economic welfare of the miners
51
Izzan Nur Aslam et al. / Jurnal Rekayasa Kimia dan Lingkungan, Vol. 17, No. 1, January - June 2022
Mulja, T., Collins, M., Wong, H.H., Rizal, R., Spiegel, S.J., Veiga, M.M., 2010. International
Brown, T., Zainuddin, M., 2003. An guidelines on mercury management in
integrated mineral exploration small-scale gold mining. J. Clean. Prod.
programme in the Takengon tenement, 18(4), 375-385.
Aceh magmatic arc, north Sumatra. https://dx.doi.org/10.1016/j.jclepro.200
Geochem.: Explor. Environ. Anal. 3(4), 9.10.020.
321-335. https://dx.doi.org/10.1144/
1467-7873/03-017. Van Leeuwen, T., 2014. A brief history of
mineral exploration and mining in
Mutono, N.R., 2016. Environmental and health Sumatra, Proceedings of Sundaland
problems associated with artisanal Resources, 2014 MGEI Annual
mining in kenya: a case study of Convention. Palembang, 17-18.
macalder mines in Migori. University of
Nairobi. Veiga, M.M., 2020. A Critical Review of
Suitable Methods to Eliminate Mercury in
Ngure, V., Lelo, F., Obwanga, B., 2017. Heavy Indonesia’s Artisanal Gold Mining: Co-
Metal Pollution from Migori Gold Mining Existence is the Solution. United Nations
Area, Kenya: Health Implications for for Development Programme Indonesia,
Consumers of Fish and Water. J. Nat. Sci. Vancouver, 1-48.
Res. 7(6), 46-53. https://doi.org/
10.7176/. Veiga, M.M., Angeloci, G., Hitch, M., Colon
Velasquez-Lopez, P., 2014. Processing
Pulfrey, W., 1969. The geology and mineral centres in artisanal gold mining. J. Clean.
resources of Kenya. Government Printer. Prod. 64, 535-544.
https://dx.doi.org/10.1016/j.jclepro.201
Putra, T.A.R., 2018. Zero mercury 3.08.015.
implementation management of artisanal
gold mining at Geumpang Mountain, Veiga, M.M., Metcalf, S., Baker, R.F., Klein, B.,
Pidie-Aceh, Indonesia, 31st National Davis, G., Bamber, A., Siegel, S., Singo,
Geoscience Conference & Exhibition - P., Investments, G.L., 2006. Manual for
NGC 2018. Geological Society of training artisanal and small-scale gold
Malaysia, p. 203. miners. Global Mercury Project. UNIDO.,
Vienna, Austria.
Santos, G.A., 2013. Myths and realities in
artisanal gold mining mercury Veiga, M.M., Nunes, D., Klein, B., Shandro,
contamination. University of British J.A., Velasquez, P.C., Sousa, R.N., 2009.
Columbia. Mill leaching: a viable substitute for
mercury amalgamation in the artisanal
Sousa, R.N., Veiga, M.M., Klein, B., Telmer, gold mining sector? J. Clean. Prod.
K., Gunson, A.J., Bernaudat, L., 2010. 17(15), 1373-1381.
Strategies for reducing the https://dx.doi.org/10.1016/j.jclepro.200
environmental impact of reprocessing 9.03.012.
mercury-contaminated tailings in the
artisanal and small-scale gold mining Wills, B.A., Finch, J.A., 2016. Sampling,
sector: insights from Tapajos River Control, and Mass Balancing, in: Wills,
Basin, Brazil. J. Clean. Prod. 18(16-17), B.A., Finch, J.A. (Eds.), Wills' Mineral
1757-1766. https://dx.doi.org/10.1016/ Processing Technology. Butterworth-
j.jclepro.2010.06.016. Heinemann, Boston, pp. 41-90.
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