Flashcards - Topic 16 Redox Equilibria - Edexcel IAL Chemistry A-Level
Flashcards - Topic 16 Redox Equilibria - Edexcel IAL Chemistry A-Level
Flashcards - Topic 16 Redox Equilibria - Edexcel IAL Chemistry A-Level
A-Level
Topic 16 - Redox Equilibria
Flashcards
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What is an oxidation number?
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What is an oxidation number?
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What is oxidation?
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What is oxidation?
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What is reduction?
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What is reduction?
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What is standard electrode potential?
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What is standard electrode potential?
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What conditions are required for
measuring the standard electrode
potential?
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What conditions are required for measuring the
standard electrode potential?
- 298 K temperature
- 100 kPa pressure
- 1.00 mol dm-3 concentration of ions
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Why is a hydrogen half-cell needed as a
reference?
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Why is a hydrogen half-cell needed as a reference?
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What is the experimental setup to calculate the
standard electrode potential for zinc?
The hydrogen standard cell is always placed on the left.
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Why must metal electrodes be cleaned
with sandpaper before creating an
electrochemical cell?
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Why must metal electrodes be cleaned with
sandpaper before creating an electrochemical cell?
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Describe the movement of electrons in
an electrochemical cell
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Describe the movement of electrons in an
electrochemical cell
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Why is a salt bridge used in an
electrochemical cell?
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Why is a salt bridge used in an electrochemical cell?
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Why must an inert salt be used in the salt bridge?
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What moves across the salt bridge?
Ions.
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What must the cell potential value be, for
a process to be feasible?
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What must the cell potential value be, for a process
to be feasible?
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How can cell potential be calculated?
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How can cell potential be calculated?
Eᶿcell =
Eᶿ(positive terminal) - Eᶿ(negative terminal)
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Why might theoretical cell potential
values be different to values obtained
experimentally?
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Why might theoretical cell potential values be
different to values obtained experimentally?
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Draw a diagram showing a standard
2+ 3+
Fe /Fe cell
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Draw a diagram showing a standard Fe2+/Fe3+ cell
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A cell is made up of the following half cells:
Ag+(aq) + e- ⇌ Ag(s) Eᶿ = +0.80V
Cu2+(aq) + 2e- ⇌ Cu(s) Eᶿ = +0.34V
Write the overall cell equation and
calculate the standard cell potential
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A cell is made up of the following half cells:
Ag+(aq) + e- ⇋ Ag(s) Eᶿ = +0.80V
Cu2+(aq) + 2e- ⇋ Cu(s) Eᶿ = +0.34V
Write the overall cell equation and calculate the
standard cell potential
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In an electrochemical cell, is the more negative half
cell oxidised or reduced?
Oxidised
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What is the relationship between EcellӨ
and lnK?
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What is the relationship between EcellӨ and lnK?
Ө
Ecell is directly proportional to lnK where
K is the equilibrium constant of the
reaction.
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What is the relationship between EcellӨ
and the entropy change of the reaction?
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What is the relationship between EcellӨ and the
entropy change of the reaction?
Ө
Ecell is directly proportional to the
entropy change of the reaction.
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What is uncertainty in measurement?
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What is uncertainty in measurement?
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What is a fuel cell?
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What is a fuel cell?
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What is the only product of a
hydrogen-oxygen fuel cell?
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What is the only product of a hydrogen-oxygen fuel
cell?
Water.
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How does a hydrogen-oxygen fuel cell
work?
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How does a hydrogen-oxygen fuel cell work?
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What are the two half equations taking place in a
hydrogen-oxygen fuel cell?
- -
2H2+ 4OH ⇌ 4H2O + 4e
O2 + 2H2O + 4e- ⇌ 4OH-
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Write an equation for the overall reaction
that takes place in a hydrogen-oxygen
fuel cell
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Write an equation for the overall reaction that takes
place in a hydrogen-oxygen fuel cell
2H2 + O2 → 2H2O
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What are the advantages of fuel cells?
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What are the advantages of using fuel cells?
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What are the disadvantages of fuel
cells?
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What are the disadvantages of using fuel cells?
- The materials used to make them are
expensive.
- High pressure tanks are required to store
oxygen and fuels like hydrogen.
- Hydrogen is expensive and hard to store.
- Efficiency is affected by temperature.
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Name another fuel which could be used
in a fuel cell
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Name another fuel which could be used in a fuel cell
- Methanol
- Any other hydrogen rich fuel
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