4.2 - Reaction Types & Net Ionic Equations - Student

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Reaction Types &

Predicting Products
Lecture 4.2
Reaction Types

1) Double Replacement

2) Single Replacement
3) Combustion (more with thermochemistry & thermodynamics)

4) Combination (Synthesis)

5) Decomposition
Solving Strategy

On the new AP exam, you will often be given chemical equations.


However, if you are not, you will need to be able to get a
chemical equation to work with.

1)

2) Sketch out molecular equation

3)
Double Replacement (Metathesis) – (AX + BY AY + BX)

1)

2) Neutralization Reactions
Double Replacement (Metathesis) – (AX + BY AY + BX)

1) Precipitate Reactions
-
- check solubility rules!
- Precipitate =

Ex: NaCl (aq) + AgNO3 (aq)


Double Replacement (Metathesis) – (AX + BY AY + BX)

2) Neutralization Reactions
- acid + base
-
- check solubility rules for salt, acid, and base!

Ex: NaOH (aq) + HCl (aq)


Single Replacement– (A + BX AX + B)
- more active elements replace less active elements
- check activity series!

Ex: Cl2 (g) + KBr (aq)

Ex: Na (s) + BeBr2 (aq)

Ex: Ca (s) + HCl (aq)

Ex: Ca (s) + H2O (l)


Combustion (net ionic normally not required b/c no H2O!)
- Make oxides of every element in the compound
- Make sure to follow charge on ionic compounds when needed

Ex: CH4 (g) + O2 (g)

Ex: Mg (s) + O2 (g)


Combination (net ionic normally not required b/c no H2O!)
- Typically going to be the formation of an ionic compound from a
metal and a nonmetal

- If for some reason you are given a combination reaction that is not
a simple ionic compound, just put everything together creating
polyatomic ions

Ex: Li + N2

Ex: MgO + CO2


Decomposition (net ionic normally not required b/c no H2O!)

- There are a lot of decomposition reactions… I am nearly certain you


will be given any of the reactions below, but I have provided
examples in case you ever needed to predict

1) Metal Carbonates

2) Metal Hydrogen Carbonates (bicarbonates)


With heat
3) Metal Halates

4) Metal Sulfites

5) Hydrogen Peroxide With catalyst


Decomposition (net ionic normally not required b/c no H2O!)

1) Metal Carbonates
HEAT
Metal Carbonates Metal Oxide + CO 2

Ex:

CaCO3 CaO + CO2


Decomposition (net ionic normally not required b/c no H2O!)

2) Metal Hydrogen Carbonates (bicarbonates)


HEAT
Metal Hydrogen Carbonates Metal Carbonate +

CO2 + H2O
Ex:

2NaHCO3 Na2CO3 + CO2 + H2O


Decomposition (net ionic normally not required b/c no H2O!)

3) Metal Halates
HEAT
Metal Halates Metal Halide + O2

Ex:

2KClO3 2KCl + 3O2


Decomposition (net ionic normally not required b/c no H2O!)

4) Metal Sulfites
HEAT
Metal Sulfites Metal Oxide + SO 2

Ex:

CaSO3 CaO + SO2


Decomposition (net ionic normally not required b/c no H2O!)

5) Hydrogen Peroxide
Catalyst
Hydrogen Peroxide Water + O2

Ex:

2H2O2 2H2O + O2
Writing Chemical Equations
3 Ways:

1) Molecular Form

Ex: NaCl (aq) + AgNO3 (aq) AgCl (s) + NaNO3 (aq)

(s) = solid

(l) = liquid

(g) = gas

(aq) = aqueous

- Make sure to balance the equation!


Writing Chemical Equations
3 Ways:

2) Complete Ionic

Ex: Na+ (aq) + Cl- (aq) + Ag+ + NO3- (aq) AgCl (s) + Na+ (aq) + NO3- (aq)
Writing Chemical Equations
3 Ways:

3) Net Ionic
- Remove spectator ions

- Spectator Ions = substances that do not change during the


reaction

Ex: Na+ (aq) + Cl- (aq) + Ag+ + NO3- (aq) AgCl (s) + Na+ (aq) + NO3- (aq)

Net Ionic: Cl- (aq) + Ag+ (aq) AgCl (s)

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