Syllabus of B.SC Hons Chemistry in Jmi
Syllabus of B.SC Hons Chemistry in Jmi
Syllabus of B.SC Hons Chemistry in Jmi
B.Sc.Hons CHEMISTRY
Effective from Academic Year 2017-2018
1
Table of Contents
Semester Paper/Practical Paper title Page
No.
Course Outline 03
Theory (Core) Inorganic Chemistry-I 05
Practical (Core) Inorganic Chemistry Practical-I 06
Theory (Core) Physical Chemistry-I 07
Semester-I Practical (Core) Physical Chemistry Practical-I 08
Theory (Elective) Industrial Chemicals and Environment 09
Practical(Elective) Industrial Chemicals and Environment Practical 10
Semester-II Theory (Core) Organic Chemistry-I 13
Practical (Core) Organic Chemistry Practical-I 14
Theory (Core) Physical Chemistry-II 15
Practical (Core) Physical Chemistry Practical-II 16
Theory (Elective) Polymer Chemistry 17
Practical(Elective) Polymer Chemistry Practical 18
Theory (Core) Inorganic Chemistry-II 19
Semester-III Practical (Core) Inorganic Chemistry Practical-II 20
Theory (Core) Organic Chemistry-II 21
Practical (Core) Organic Chemistry Practical-II 22
Theory (Core) Physical Chemistry-III 23
Practical(Core) Physical Chemistry Practical-III 24
Theory Inorganic Materials of Industrial Importance 25
(Ability Enhancement )
Theory (Core) Inorganic Chemistry-III 26
Practical (Core) Inorganic Chemistry Practical-III 27
Semester-IV Theory (Core) Organic Chemistry-III 28
Practical (Core) Organic Chemistry Practical-III 29
Theory (Core) Physical Chemistry-IV 30
Practical (Core) Physical Chemistry Practical-IV 31
Theory (Elective) Green Chemistry 32
Practical (Elective) Green Chemistry Practical 33
Theory (Core) Inorganic Chemistry-IV 34
Practical (Core) Inorganic ChemistryPractical-IV 35
Semester-V Theory (Core) Organic Chemistry-IV 36
Practical (Core) Organic Chemistry Practical-IV 37
Theory (Core) Physical Chemistry-V
Practical (Core) Physical Chemistry Practical-V
Theory (Elective) Molecular Modeling and Drug Design 38
Practical (Elective) Molecular Modeling and Drug Design Practical 39
Theory (Core) Inorganic Chemistry-V 40
Semester-VI Practical (Core) Inorganic Chemistry Practical-V 41
Theory (Core) Organic Chemistry-V 42
Practical (Core) Organic Chemistry Practical-V 43
Theory (Core) Physical Chemistry-VI 44
Practical (Core) Physical Chemistry Practical-VI 45
2
Course Outline
Semester Paper/ Paper Paper Paper Total
Practical No Code Title Credits
Paper code – 1st letter for semester, 2nd and 3rd for subject as mentioned below:-
01- Inorganic Chemistry,02-Organic Chemistry,03-Physical Chemistry,04- Elective, 05-Ability
Enhancement
3
Semester-I
Paper No: I-H
Paper Code: BCH-101 UE= 75 marks
IA = 25 Marks
Inorganic Chemistry-I
Unit I Atomic Structure
Bohr’s theory; its limitations and atomic spectrum of hydrogen atom; Wave mechanics: de
Broglie equation, Heisenberg’s Uncertainty Principle and its significance, Schrödinger’s wave
equation, significance of ψ and ψ2.Quantum numbers and their significance. Sign of wave
functions. Radial and angular wave functions for hydrogen atom; Radial and angular
distribution curves; Shapes of s, p, d and f orbitals. Contour boundary and probability
diagrams; Pauli’s Exclusion Principle, Hund’s rule of maximum multiplicity, Aufbau’s
principle and its limitations, Variation of orbital energy with atomic number.
Unit II Periodicity of Elements
s, p, d, f block elements, the long form of periodic table; Discussion of followingproperties
with reference to s and p-blockelements: Effective nuclear charge, shielding or screening
effect, Slater rules, variation of effective nuclear charge in periodic table.; Atomic radii (van
der Waals) Ionic and crystal radii; Covalent radii (octahedral and tetrahedral; Ionization
enthalpy; Successive ionization enthalpies and factors affecting ionization energy;
Applications of ionization enthalpy; Electron gain enthalpy; trends of electron gain enthalpy.
Electronegativity, Pauling’s/Mulliken’s/AllredRachow’s and Mulliken-Jaffé’s
electronegativity scales; Variation of electronegativity with bond order, partial charge,
hybridization, group electronegativity; Sanderson’s electron density ratio.
Unit III Chemical Bonding and Molecular Structure
Ionic bond: General characteristics, types of ions, size effects, radius ratio rule and
itslimitations. Packing of ions in crystals. Born-Landé equation with derivation and
importance of Kapustinskii expression for lattice energy.Madelung constant, Born-Haber
cycle and its application, Solvation energy.Covalent bond: Lewis structure, Valence Bond
theory (Heitler-London approach).Energetics of hybridization, equivalent and non-equivalent
hybrid orbitals.Bent’s rule, Resonance and resonance energy, Molecular orbital theory.
Molecular orbital diagrams of diatomic and simple polyatomic molecules N2, O2, C2, B2, F2,
CO, NO, and their ions; HCl, BeF2, CO2, (idea of s-p mixing and orbital interaction to be
given). Formal charge, Valence shell electron pair repulsion theory (VSEPR), shapes of
simple molecules and ions containing lone pairs and bond pairs of electrons, multiple bonding
(σ and π bond approach) and bond lengths. Covalent character in ionic compounds, polarizing
power and polarizability.Fajan’s rules and consequences of polarization.Ionic character in
covalent compounds: Bond moment and dipole moment. Percentage ionic character from
dipole moment and electronegativity difference.Metallic Bond: Qualitative idea of valence
bond and band theories. Semiconductors andinsulators, defects in solids.
Unit IV Oxidation-Reduction
Redox reactions, Standard Electrode Potential and its application to inorganic reactions,
Oxidation state, rules for the determination of oxidation states, electrochemical series,
applications of electrochemical series.
Reference Books
1. Lee, J.D., Concise Inorganic Chemistry, 5th edn., Blackwell Science, London.
2. Douglas, B.E. and McDaniel, D.H., Concepts & Models of Inorganic Chemistry,Oxford, 1970
3. Atkins, P.W. & Paula, J. Physical Chemistry, 10th Ed., Oxford University Press, 2014.
4. Day, M.C. and Selbin, J. Theoretical Inorganic Chemistry, ACS Publications, 1962.
5. Rodger, G.E., Inorganic and Solid State Chemistry, Cengage Learning India Edition, 2002.
4
Practical Code: BCH-101L
UE =25 Marks
IA = 25 Marks
A. Titrimetric Analysis
i. Calibration and use of apparatus
ii. Preparation of solutions of different Molarity/Normality of titrants
B. Acid-Base Titrations
i. Estimation of carbonate and hydroxide present together in mixture.
ii. Estimation of carbonate and bicarbonate present together in a mixture.
iii. Estimation of free alkali present in different soaps/detergents
C. Oxidation-Reduction Titrimetry
i. Estimation of Fe(II) and oxalic acid using standardized KMnO4 solution.
ii. Estimation of oxalic acid and sodium oxalate in a given mixture.
iii. Estimation of Fe(II) with K2Cr2O7 using internal (diphenylamine, anthranilic acid) and
external indicator.
Reference Books
5
Semester-I
Paper No: II-H
Paper Code: BCH-103 UE= 75Marks
IA=25 Marks
Physical Chemistry-I
Books Recommended:
1. Essentials of Physical Chemistry, B.S. Bahl, G.D.Tuli and Arun Bahl, S. Chand &
Company Ltd.
2. A Text Book of Physical Chemistry, A.S. Negi and S.C. Anand, New Age International
Publishers.
3. Physical Chemistry, G. M. Barrow, International Student Edition, McGraw Hill.
4. Physical Chemistry through Problems, S. K. Dogra and S. Dogra Wiley Eastern Ltd.
5. Physical Chemistry, P. W. Atkins, & J. de Paula, 10th Ed., Oxford University Press (2014).
6
Practical Code: BCH-103L
UE =25Marks
IA = 25 Marks
4. pH metry
a) Study the effect on pH of addition of HCl/NaOH to solutions of acetic acid, sodium
acetate and their mixtures.
b) Preparation of buffer solutions of different pH
(i). Sodium acetate-acetic acid
(ii). Ammonium chloride-ammonium hydroxide
c) pH metric titration of (i) strong acid vs. strong base, (ii) weak acid vs. strong base.
d) Determination of dissociation constant of a weak acid.
Reference Books
1. O.P. Pandey, D.N. Bajpai & S. Giri, Practical Chemistry, S. Chand & Company Ltd.
2. B. D. Khosla, V. C. Garg & A. Gulati, Senior Practical Physical Chemistry, S. Chand & Co.:
New Delhi (2011).
3. C. W. Garland, J.W. Nibler, & D.P. Shoemaker, Experiments in Physical Chemistry 8th Ed.;
McGraw-Hill: New York (2003).
4. A.M. Halpern & G.C. McBane, Experimental Physical Chemistry 3rd Ed.; W.H. Freeman &
Co.: New York (2003).
7
Semester-I
Paper No: III-H
Paper Code: BCH-104
UE=75Marks
IA=25 Marks
Industrial Chemicals and Environment
8
Practical Code: BCH-104L
UE=25Marks
IA=25 Marks
Reference Books
9
Semester-II
Paper No: IV-H UE = 75 marks
Paper Code: BCH-202 IA = 25 marks
Organic Chemistry-I
Unit-I Basic Concepts of Organic Chemistry
Physical Effects, Electronic Displacements: Inductive Effect, ElectromericEffect,Resonance
and Hyperconjugation. Cleavage of Bonds: Homolysis and Heterolysis.Structure, shape and
reactivity of organic molecules: Nucleophiles and electrophiles.Reactive Intermediates:
Carbocations, Carbanions and free radicals. Strength of organic acids and bases: Comparative
study with emphasis on factors affecting pK values.
Unit-II Stereochemistry
Fischer Projection, Newmann and Sawhorse Projection formulae and their interconversions;
Geometrical isomerism: cis–trans and, syn-anti isomerism E/Z notations with C.I.P rules.
Optical Isomerism: Optical Activity, Specific Rotation, Chirality/Asymmetry, Enantiomers,
Molecules with two or more chiral-centres, Distereoisomers, meso structures, Racemic
mixture and resolution. Relative and absolute configuration: D/L and R/S designations.
Unit-III Chemistry of Aliphatic Hydrocarbons
Carbon-Carbon sigma bonds: Chemistry of alkanes: Formation of alkanes, Wurtz Reaction,
Wurtz-Fittig Reactions, Free radical substitutions: Halogenation -relative reactivity and
selectivity. Carbon-Carbon pi bonds: Formation of alkenes and alkynes by elimination
reactions, Mechanism of E1, E2, E1cb reactions. Saytzeff and Hofmann eliminations.
Reactions of alkenes: Electrophilic additions their mechanisms (Markownikoff/ Anti
Markownikoff addition), mechanism of oxymercuration-demercuration,
hydroborationoxidation, ozonolysis, reduction (catalytic and chemical), syn and anti-
hydroxylation (oxidation). 1,2-and 1,4-addition reactions in conjugated dienes and, Diels-
Alder reaction; Allylic and benzylicbromination and mechanism, e.g. propene, 1-butene,
toluene, ethyl benzene. Reactions of alkynes: Acidity, Electrophilic and Nucleophilic
additions. Hydration to form carbonyl compounds, Alkylation of terminal alkynes.
Unit-IV Cycloalkanes and Aromatic Hydrocarbons
Types of cycloalkanes and their relative stability, Baeyer strain theory, Conformation analysis
of alkanes: Relative stability: Energy diagrams of cyclohexane: Chair, Boat and Twist boat
forms; Relative stability with energy diagrams.
Hückel’s rule; aromatic character of arenes; cyclic carbocations/carbanions and heterocyclic
compounds with suitable examples; Electrophilic aromatic substitution: halogenation;
nitration;sulphonation and Friedel-Craft’s alkylation/acylation with their mechanism;
Directing effects of the groups.
Reference Books
1. Morrison, R. N. & Boyd, R. N. Organic Chemistry, Dorling Kindersley (India) Pvt. Ltd. (Pearson
Education).
2. Finar, I. L. Organic Chemistry (Volume 1), Dorling Kindersley (India) Pvt. Ltd. (Pearson Education)
3. Finar, I. L. Organic Chemistry (Volume 2: Stereochemistry and the Chemistry of Natural Products), Dorling
Kindersley (India) Pvt. Ltd. (Pearson Education).
4. Eliel, E. L. &Wilen, S. H. Stereochemistry of Organic Compounds, Wiley: London, 1994.
5. Kalsi, P. S. Stereochemistry Conformation and Mechanism, New Age International, 2005.
6. McMurry, J.E. Fundamentals of Organic Chemistry, 7th Ed. Cengage Learning India Edition,
10
UE = 25 marks
Practical Code: BCH-202L IA = 25 marks
Reference Books
1. Mann, F.G. & Saunders, B.C. Practical Organic Chemistry, Pearson Education (2009)
2. Furniss, B.S.; Hannaford, A.J.; Smith, P.W.G.; Tatchell, A.R. Practical Organic Chemistry,
5th Ed., Pearson (2012)
11
Semester-II
Paper No: V-H
Paper Code: BCH-203
UE = 75 marks
IA = 25 marks
Physical Chemistry-II
Unit I. Thermochemistry
Exothermic and endothermic reactions, Heats of reactions, standard states, relation between
heat of reaction at contant volume (qv) and at contant pressure (qp), Heat capacity, relation
between Cp and Cv, laws of thermochemistry, enthalpy of formation, heat of solution and
dilution, heat of neutralization, bond dissociation energy, bond energy and its calculation,
concept of lattice energy, effect of temperature (Kirchhoff’s equations) and pressure on
enthalpy of reactions.
Books Recommended
2. Essentials of Physical Chemistry, B.S. Bahl, G.D.Tuli and Arun Bahl, S. Chand & Company Ltd.
6. A Text Book of Physical Chemistry, A.S. Negi and S.C. Anand, New Age International Publishers.
7. Physical Chemistry, G. M. Barrow, International Student Edition, McGraw Hill.
8. Physical Chemistry through Problems, S. K. Dogra and S. Dogra Wiley Eastern Ltd.
9. Physical Chemistry, P. W. Atkins, & J. de Paula, 10th Ed., Oxford University Press (2014).
12
Practical Code: BCH-203L
UE = 25 marks
IA = 25 marks
Physical Chemistry Practical-II
Reference Books
1. O.P. Pandey, D.N. Bajpai & S. Giri, Practical Chemistry, S. Chand & Company Ltd.
2. B. D. Khosla, V. C. Garg & A. Gulati, Senior Practical Physical Chemistry, S. Chand & Co.: New
Delhi (2011).
1. C. W. Garland, J.W. Nibler, & D.P. Shoemaker, Experiments in Physical Chemistry 8th Ed.; McGraw-
Hill: New York (2003).
2. A.M. Halpern & G.C. McBane, Experimental Physical Chemistry 3rd Ed.; W.H. Freeman & Co.: New
York (2003).
13
Semester-II
Paper No: VI-H
Paper Code: BCH-204 E = 75 marks
IA = 25 marks
Polymer Chemistry
Reference Books
1. R.B. Seymour & C.E. Carraher: Polymer Chemistry: An Introduction, Marcel Dekker, Inc.
New York, 1981.
2. G. Odian: Principles of Polymerization, 4th Ed. Wiley, 2004.
3. F.W. Billmeyer: Textbook of Polymer Science, 2nd Ed. Wiley Interscience, 1971.
4. P. Ghosh: Polymer Science & Technology, Tata McGraw-Hill Education, 1991.
5. R.W. Lenz: Organic Chemistry of Synthetic High Polymers.Interscience Publishers, New
York, 1967.
14
Practical Code: BCH-204L
UE = 25 marks
IA = 25 marks
A. Polymer synthesis
B. Polymer characterization
1. Determination of molecular weight by viscometry: Polyacrylamide-aq. NaNO2
solution (Poly vinyl proplylidine (PVP) in water.
2. Determination of the viscosity-average molecular weight of poly(vinyl alcohol)
(PVOH) and the fraction of “head-to-head” monomer linkages in the polymer.
3. Determination of molecular weight by end group analysis: Polyethylene glycol (PEG)
(OH group).
4. Testing of mechanical properties of polymers.
5. Determination of hydroxyl number of a polymer using colorimetric method.
C. Polymer analysis
1. Estimation of the amount of HCHO in the given solution by sodium sulphite method
2. Instrumental Techniques
3. IR studies of polymers
4. DSC analysis of polymers
5. Preparation of polyacrylamide and its electrophoresis
Reference Books
1. M.P. Stevens, Polymer Chemistry: An Introduction, 3rd Ed., Oxford University Press,1999.
2. H.R. Allcock, F.W. Lampe & J.E. Mark, Contemporary Polymer Chemistry, 3rd ed. Prentice-Hall (2003)
3. F.W. Billmeyer, Textbook of Polymer Science, 3rd ed. Wiley-Interscience (1984)
nd
4. J.R. Fried, Polymer Science and Technology, 2 ed. Prentice-Hall (2003)
15
Semester-II
Paper No: VII-H
Paper Code: BCH-301 UE = 75 marks
IA = 25 marks
Inorganic Chemistry- II
Reference Books
16
Practical Code: BCH-310L
UE = 25 marks
IA = 25 marks
B. Inorganic preparations
i. Cuprous chloride, Cu2Cl2
ii. Preparation of Manganese(III) phosphate, MnPO4.H2O.
iii. Preparation of Aluminium potassium sulphate K2SO4.Al(SO4)2.12H2O (Potash alum)
or Chrome alum.
Reference Books
17
2.
Semester-III
Paper No: VIII-H
Paper Code: BCH-302 UE = 75 marks
IA = 25 marks
Organic Chemistry-II
Reference Books
1. Morrison, R. T. & Boyd, R. N. Organic Chemistry, Dorling Kindersley (India) Pvt. Ltd. (Pearson
Education)
2. Finar, I. L. Organic Chemistry (Volume 1), Dorling Kindersley (India) Pvt. Ltd. Pearson
Education).
3. Graham Solomons, T.W. Organic Chemistry, John Wiley & Sons, Inc.
4. McMurry, J.E. Fundamentals of Organic Chemistry, 7th Ed. Cengage Learning India
Edition, 2013.
18
Practical Code: BCH-302L
UE = 25 marks
IA = 25 marks
1. Functional group tests for alcohols, phenols, carbonyl and carboxylic acid group.
2. Organic preparations:
a. Acetylation of one of the following compounds: amines (aniline, o-, m-,
ptoluidines and o-, m-, p-anisidine) and phenols (β-naphthol, vanillin, salicylic
acid) by any one method:
b. Using conventional method.
c. Using green approach
3. Benzolyation of one of the following amines (aniline, o-, m-, p- toluidines and o-,m-, p
anisidine) and one of the following phenols (β-naphthol, resorcinol, pcresol)by Schotten-
Baumann reaction.
iii. Oxidation of ethanol/ isopropanol (Iodoform reaction).
iv. Bromination of any one of the following:
a. Acetanilide by conventional methods
b. Acetanilide using green approach (Bromate-bromide method)
v. Nitration of any one of the following:
a. Acetanilide/nitrobenzene by conventional method
b. Salicylic acid by green approach (using ceric ammonium nitrate).
vi. Selective reduction of metadinitrobenzene to m-nitroaniline.
vii. Reduction of p-nitrobenzaldehyde by sodium borohydride.
viii. Hydrolysis of amides and esters.
ix. Semicarbazone of any one of the following compounds: acetone, ethyl methyl
ketone, cyclohexanone, benzaldehyde.
x. S-Benzylisothiouronium salt of one each of water soluble and water insoluble acids
(benzoic acid, oxalic acid, phenyl acetic acid and phthalic acid).
xi. Aldol condensation using either conventional or green method.
xii. Benzil-Benzilic acid rearrangement.
The above derivatives should be prepared using 0.5-1g of the organic compound. The solid
samples must be collected and may be used for recrystallization, melting point and TLC.
Reference Books
1. Mann, F.G. & Saunders, B.C. Practical Organic Chemistry, Pearson Education
(2009)
Furniss, B.S., Hannaford, A.J., Smith, P.W.G. &Tatchell, A.R. Practical Organic
Chemistry, 5th Ed. Pearson (2012)
3.Ahluwalia, V.K. &Aggarwal, R. Comprehensive Practical Organic Chemistry:
Preparation and Quantitative Analysis, University Press (2000).
4. Ahluwalia, V.K. &Dhingra, S. Comprehensive Practical Organic Chemistry: Qualitative
Analysis, University Press (2000).
19
Semester-III
Paper No: IX-H
Paper Code: BCH-303
UE = 75 marks
IA = 25 marks
Physical Chemistry-III
Unit-IV Catalysis
Types of catalyst, specificity and selectivity, mechanisms of catalyzed reactions at solid
surfaces; effect of particle size and efficiency of nanoparticles as catalysts. Enzyme catalysis,
Michaelis- Menten mechanism, acid-base catalysis.
Reference Books
1. Peter Atkins & Julio De Paula, Physical chemistry 10th Ed., Oxford University Press (2014)
2. Castellan, G. W. Physical chemistry, 4th Ed., Narosa (2004)
3. McQuarrie, D. A. & Simon, J. D., Molecular Thermodynamics, Viva Books Pvt. Ltd.: New Delhi
(2004).
4. Engel, T. & Reid, P. Physical chemistry, 3th Ed., Prentice-Hall (2012)
5. Maron, Samuel H., Principles of Physical chemistry, 4th Ed., Macmillan company, New York (1970)
6. Rastogi, R. P. & Mishra, R. R. An Introduction to chemical Thermodynamics.
20
UE = 25 marks
Practical Code: BCH-303L IA = 25 marks
Chemical Kinetics
1. To determine the order of the reaction between thiosulphate and HCl w.r.t.
thiosulphate.
2. To determine the order of the reaction between thiosulphate and HCl w.r.t. HCl.
3. To study the kinetics of the reaction between thiosulphate and HCl at moderate
concentration of [H+] by using initial rate method.
4. To determine the order of reaction for acid hydrolysis of methyl acetate at room
temperature.
5. To determine the kinetics of the hydrolysis of ethyl acetate catalyzed by hydrogen ions
at room temperature.
6. To study the effect of acid strength on the hydrolysis of an ester.
7. To study the kinetics of alkaline hydrolysis of M/40 methyl acetate by providing M/40
HCl and M/40 NaOH.
8. To study the kinetics of the saponification of ethyl acetate by integrated rate method.
Ionic Equilibria
Reference Books
1. O.P. Pandey, D.N. Bajpai & S. Giri, Practical Chemistry, S. Chand & Company Ltd.
2. B. D. Khosla, V. C. Garg & A. Gulati, Senior Practical Physical Chemistry, S. Chand & Co.: New
Delhi (2011).
3. C. W. Garland, J.W. Nibler, & D.P. Shoemaker, Experiments in Physical Chemistry 8th Ed.; McGraw-
Hill: New York (2003).
4. R.C. Das and B. Behra, Experiments in Physical Chemistry,; Tata McGraw Hill.
21
Semester-III
Paper No: X-H
Paper Code: BCH-304 UE = 75 marks
IA = 25 marks
Unit II Fertilizers
Different types of fertilizers. Manufacture of the following fertilizers: Urea, ammonium
nitrate, calcium ammonium nitrate, ammonium phosphates; polyphosphate, superphosphate,
compound and mixed fertilizers, potassium chloride, potassium sulphate.
Unit III Surface Coatings
Objectives of coatings surfaces, preliminary treatment of surface, classification of surface
coatings.Paints and pigments-formulation, composition and related properties. Oil paint,
Vehicle, modified oils, Pigments, toners and lakes pigments, Fillers, Thinners, Enamels,
emulsifying agents. Special paints (Heat retardant, Fire retardant, Eco-friendly paint, Plastic
paint), Dyes, Wax polishing, Water and Oil paints, additives, Metallic coatings (electrolytic
and electroless), metal spraying and anodizing.
Unit IV Alloys
Classification of alloys, ferrous and non-ferrous alloys, Specific properties of elements in
alloys. Manufacture of Steel (removal of silicon decarbonization, demanganization,
desulphurization dephosphorisation) and surface treatment (argon treatment, heat treatment,
nitriding, carburizing). Composition and properties of different types of steels.
Chemical explosives: Origin of explosive properties in organic compounds, preparation and
explosive properties of lead azide, PETN, cyclonite (RDX). Introduction to rocket propellants.
Reference Books
1. E. Stocchi: Industrial Chemistry, Vol-I, Ellis Horwood Ltd. UK.
2. R.M. Felder, R. W. Rousseau: Elementary Principles of Chemical Processes, Wiley Publishers, New
Delhi.
3. W. D. Kingery, H. K. Bowen, D. R. Uhlmann: Introduction to Ceramics, Wiley Publishers, New
Delhi.
4. J. A. Kent: Riegel’sHandbook of Industrial Chemistry, CBS Publishers, New Delhi. P. C. Jain, M. Jain:
Engineering Chemistry,DhanpatRai& Sons, Delhi.
5. R. Gopalan, D. Venkappayya, S. Nagarajan: Engineering Chemistry,Vikas Publications, New
Delhi.
6. Sharma, B.K. & Gaur, H. Industrial Chemistry,Goel Publishing House, Meerut (1996).
22
Semester-IV
Paper No: XI-H
Paper Code: BCH-401 UE = 75 marks
IA = 25 marks
Reference Books
23
Practical Code: BCH-401L
UE = 25 marks
IA = 25 marks
A. Gravimetric Analysis:
B. Inorganic Preparations
i. Cisand trans K[Cr(C2O4)2(H2O)2] Potassium dioxalatodiaquachromate(III)
ii. Tetraamminecarbonatocobalt(III) ion
iii. Potassium tris(oxalato)ferrate(III)
Reference Book
24
Semester-IV
Paper No: XII-H
Paper Code: BCH-402 UE = 75 marks
IA = 25 marks
Unit-II Amines: Effect of substituent and solvent on basicity; Preparation and properties of
1°, 2° and 3°amines Gabriel phthalimide synthesis, Carbylamine reaction, Mannich reaction,
Hofmann-elimination reaction; Distinction between 1°, 2° and 3°amines with Hinsberg
reagent and nitrous acid.Diazonium Salts: Preparation and their synthetic applications.
Reference Books
1. Morrison, R. T. & Boyd, R. N. Organic Chemistry, Dorling Kindersley (India)Pvt. Ltd. (Pearson
Education).
2. Finar, I. L. Organic Chemistry (Volume 1), Dorling Kindersley (India) Pvt. Ltd.(Pearson
Education).
3. Acheson, R.M. Introduction to the Chemistry of Heterocyclic compounds, JohnWiley& Sons
(1976).
4. Graham Solomons, T.W. Organic Chemistry, John Wiley & Sons, Inc.
25
Practical Code: BCH-402L
UE = 25 marks
IA = 25 marks
Reference Books
1. Mann, F.G. & Saunders, B.C. Practical Organic Chemistry, Pearson Education(2009)
2. Furniss, B.S.; Hannaford, A.J.; Smith, P.W.G.; Tatchell, A.R. Practical OrganicChemistry, 5th
Ed., Pearson (2012)
3. Ahluwalia, V.K. &Aggarwal, R. Comprehensive Practical Organic Chemistry:Preparation and
Quantitative Analysis, University Press (2000)
4. Ahluwalia, V.K. &Dhingra, S. Comprehensive Practical Organic Chemistry:Qualitative Analysis,
University Press (2000
26
Semester-IV
UE = 75 marks
Paper No: XIII-H
IA = 25 marks
Paper Code: BCH-403
Physical Chemistry-IV
Unit-I Conductance
Arrhenius theory of electrolytic dissociation. Conductivity, equivalent and molar conductivity
and their variation with dilution for weak and strong electrolytes. Molar conductivity at
infinite dilution. Kohlrausch law of independent migration of ions. Debye-Huckel-Onsager
equation. Ionic velocities, mobilities and their determinations, transference numbers and their
relation to ionic mobilities, determination of transference numbers using Hittorf and Moving
Boundary methods. Applications of conductance measurement: (i) degree of dissociation of
weak electrolytes, (ii) ionic product of water (iii) solubility and solubility product of
spraringly soluble salts, (iv) conductometric titrations, and (v) hydrolysis constants of salts.
Unit-II Electrochemistry
Chemical cells, reversible and irreversible cells with examples. Electromotive force of a cell
and its measurement, Nernst equation; Standard electrode (reduction) potential and its
application to different kinds of half-cells. Application of EMF measurements in determining
(i) free energy, enthalpy and entropy of a cell reaction, (ii) equilibrium constants, and (iii) pH
values, using hydrogen, quinone-hydroquinone, glass electrodes.
Reference Books
1. Peter Atkins & Julio De Paula, Physical chemistry 10th Ed., Oxford University Press (2014)
2. Castellan, G. W. Physical chemistry, 4th Ed., Narosa (2004)
3. McQuarrie, D. A. & Simon, J. D., Molecular Thermodynamics, Viva Books Pvt. Ltd.: New Delhi
(2004).
4. Engel, T. & Reid, P. Physical chemistry, 3th Ed., Prentice-Hall (2012)
5. Maron, Samuel H., Principles of Physical chemistry, 4th Ed., Macmillan company, New York (1970)
6. Rastogi, R. P. & Mishra, R. R. An Introduction to chemical Thermodynamics.
27
Practical Code: BCH-403L UE = 25 marks
IA = 25 marks
Conductometry
Potentiometry
Books Recommended:
1. Khosla, B. D.; Garg, V. C. & Gulati, A., Senior Practical Physical Chemistry, R. Chand &
Co.: New Delhi (2011).
28
Semester-IV
Paper No: XIV-H
Paper Code: BCH-404 UE = 75 marks
IA = 25 marks
Green Chemistry
29
Reference Books
1. Ahluwalia, V.K. &Kidwai, M.R. New Trends in Green Chemistry, Anamalaya Publishers
(2005).
2. Anastas, P.T. & Warner, J.K.: Green Chemistry - Theory and Practical, Oxford University
Press (1998).
3. Matlack, A.S. Introduction to Green Chemistry, Marcel Dekker (2001).
4. Cann, M.C. &Connely, M.E. Real-World cases in Green Chemistry, American Chemical
Society, Washington (2000).
5. Ryan, M.A. &Tinnesand, M. Introduction to Green Chemistry, American Chemical Society,
Washington (2002).
nd
6. Lancaster, M. Green Chemistry: An Introductory Text RSC Publishing, 2 Edition, 2010.
30
Practical Code: BCH-404L
UE = 25 marks
IA = 25 marks
Green Chemistry Practical
Reference Books
1. Anastas, P.T & Warner, J.C. Green Chemistry: Theory and Practice, Oxford University Press
(1998).
2. Kirchoff, M. & Ryan, M.A. Greener approaches to undergraduate chemistryexperiment.
American Chemical Society, Washington DC (2002).
3. Sharma, R.K.; Sidhwani, I.T. &Chaudhari, M.K. I.K. Green Chemistry Experiment:A
monograph International Publishing House Pvt Ltd. New Delhi. Bangalore CISBN978-93-
81141-55-7 (2013).
4. Cann, M.C. & Connelly, M. E., Real world cases in Green Chemistry, American Chemical
Society (2008).
31
Semester-V
Paper No: XV-H
Paper Code: BCH-501 UE = 75 marks
IA = 25 marks
Reference Books
1. Huheey, J. E.; Keiter, E.A. &Keiter, R.L. Inorganic Chemistry, Principles of Structure and
Reactivity 4th Ed., Harper Collins 1993, Pearson, 2006.
2. Sharpe, A.G. Inorganic Chemistry, 4th Indian Reprint (Pearson Education) 2005.
3. Lee, J.D. Concise Inorganic Chemistry 5th Ed., John Wiley and sons 2008.
4. Powell, P. Principles of Organometallic Chemistry, Chapman and Hall, 1988.
5. Miessler, G. L. &Tarr, D.A. Inorganic Chemistry 4th Ed., Pearson, 2010.
6. Crabtree, R. H., The Organometallic Chemistry of the Transition Metals, New
York, NY: John Wiley, 2000.
32
Practical Code: BCH-501L
UE = 25 marks
IA = 25 marks
A. Gravimetric Analysis:
i. Determination of aluminium as aluminum oxide.
ii. Determination of sulphate ions as barium sulphate.
iii. Determination of copper and nickel involving volumetric and gravimetric methods.
iv. Determination of copper and barium involving volumetric and gravimetric methods.
B. Inorganic Preparation
i. Preparation of acetylacetanato complexes of Cu2+/Fe3+. Find the λmax of the complex.
ii. Synthesis of ammine complexes of Ni(II) and its ligand exchange reactions (e.g.
bidentate ligands like acetylacetone, DMG, glycine) by substitution method.
C. Spectrophotometric Determination:
i. Determination of copper in brass sample by spectrophotometric method.
ii. Determination of the composition of the iron-salicylic acid complex by Job’s method.
Reference Books
33
Semester-V
Paper No: XVI-H
Paper Code: BCH-502 UE = 75 marks
IA = 25 marks
Organic Chemistry-IV
Unit-I Amino Acids, Peptides and Proteins Amino acids
Peptides and their classification:α-Amino Acids – stereochemistry, Synthesis,
chromatographic separation, ionic properties and reactions. Zwitterions, pKa values,
isoelectric point and electrophoresis. Resolution of racemic aminoacids, Study of peptides:
determination of their primary structures-end group analysis, methods of peptide synthesis.
Synthesis of peptides using N-protecting, C-protecting and C-activating groups -Solid-phase
synthesis.Primary Secondary and tertiary structure of proteins.
Unit-III Carbohydrates
Occurrence, classification and their biological importance;Monosaccharides: Constitution and
absolute configuration of glucose and fructose, epimers and anomers, mutarotation,
determination of ring size of glucose and fructose, Haworth projections and conformational
structures; Interconversions of aldoses and ketoses; KillianiFischer synthesis and Ruff
degradation; Disaccharides – Structure elucidation of maltose, lactose and sucrose.;
Polysaccharides – Elementary treatment of starch, cellulose and glycogen.
Unit-IV Lipids
Introduction to oils and fats; common fatty acids present in oils and fats,
Saturated and unsaturated fatty acids.Classification of unsaturated fatty acids. Melting and
boiling point of fatty acids. Hydrogenntion and Freeradicalreactions of fats and oils;
Saponification value, acid value, iodine number; Reversion and rancidity.
Reference Books
1. Finar, I. L. Organic Chemistry (Volume 1& ll), Dorling Kindersley (India) Pvt. Ltd.(Pearson
Education).
34
Practical Code: BCH-502L
UE = 25 marks
IA = 25 marks
Reference Books
35
Semester-V B.Sc. (Hons.) Chemistry: Semester – V UE = 75 marks
Paper No: XVI-H Physical Chemistry – IV IA = 25 marks
Paper Code: BCH-503 (Quantum Chemistry)
Paper No. – XIII
Qualitative treatment of hydrogen atom and hydrogen like ions: setting up of Schrödinger
equation in spherical polar coordinates, radial part,quantization of energy (only final energy
expression).Average and most probable distancesof electron from the nucleus.Setting up of
Schrödinger equation for many electron atoms (He,Li).Need for approximate methods.
Books Recommended:
1. Physical Chemistry by KL Kapoor, Vol. 4, MacMillan India Ltd.
2. Introductory Quantum Chemistry by AK Chandra, Tata McGraw Hill.
3. Physical chemistry, 8th Edition, Peter Atkins, Julio de Paula, Oxford University Press.
36
UE = 25 marks
Practical Code: BCH-503L IA = 25 marks
1. Khosla, B. D.; Garg, V. C. & Gulati, A., Senior Practical Physical Chemistry, R. Chand &
Co.: New Delhi (2011).
2. Garland, C. W.; Nibler, J. W. & Shoemaker, D. P. Experiments in Physical Chemistry 8th
Ed.;
McGraw-Hill: New York (2003).
3. Halpern, A. M. & McBane, G. C. Experimental Physical Chemistry 3rd Ed.; W.H.
Freeman & Co.:
New York (2003).
4. Jurs, Peter C., Isenhour, Thomas L. and Wilkins, Charles L. BASIC Programming for
Chemists: An Introduction, Wiley-Blackwell (1987).
5. Balagurusamy, E. Numerical Methods, Tata McGraw Hill (2000).
37
Semester-V
Paper No: XVII-H
Paper Code: BCH-504
B.Sc. (H) Chemistry V Semester
Molecular Modeling and Drug Design (CBCS -IV)
Paper XVIII
IA = 25, UE = 75
Reference Books:
1. A.R. Leach, Molecular Modelling Principles and Application, Longman, 2001.
2. J.M. Haile, Molecular Dynamics Simulation Elementary Methods, John Wiley and Sons,
1997.
3. Satya Prakash Gupta, QSAR and Molecular Modeling, Springer - Anamaya Publishers,
2008.
38
Practical Code: BCH-504L
B.Sc. (Hons.) V Semester
Lab: Molecular Modeling and Drug Design
IA = 25, UE = 25
i. Compare the optimized C-C bond lengths in ethane, ethene, ethyne and benzene.
Visualize the molecular orbitals of the ethane σ bonds and ethene, ethyne, benzene and
pyridine π bonds.
ii. (a) Perform a conformational analysis of butane. (b) Determine the enthalpy of
isomerization of cis and trans 2-butene.
iii. Visualize the electron density and electrostatic potential maps for LiH, HF, N2, NO and
CO and comment. Relate to the dipole moments. Animate the vibrations of these
molecules.
iv. (a) Relate the charge on the hydrogen atom in hydrogen halides with their acid character.
(b) Compare the basicities of the nitrogen atoms in ammonia, methylamine,
dimethylamine and trimethylamine.
v. (a) Compare the shapes of the molecules: 1-butanol, 2-butanol, 2-methyl-1-propanol,
and 2-methyl-2-propanol. Note the dipole moment of each molecule. (b) Show how the
shapes affect the trend in boiling points: (118 ºC, 100 ºC, 108 ºC, 82 ºC, respectively).
vi. Build and minimize organic compounds of your choice containing the following functional
groups. Note the dipole moment of each compound: (a) alkyl halide (b) aldehyde (c) ketone
(d) amine (e) ether (f) nitrile (g) thiol (h) carboxylic acid (i) ester (j) amide.
vii. (a) Determine the heat of hydration of ethylene. (b) Compute the resonance energy of
benzene by comparison of its enthalpy of hydrogenation with that of cyclohexene.
ix. (a) Compare the optimized bond angles H2O, H2S, H2Se. (b) Compare the HAH bond
angles for the second row dihydrides and compare with the results from qualitative MO
theory.
Reference Books:
39
Semester-VI
Paper No: XVIII-H UE = 75 marks
Paper Code: BCH-601 IA = 25 marks
Inorganic Chemistry-V
Unit-I Organometallic Compounds
Definition and classification of organometallic compounds on the basis of bond type. Concept
of hapticity of organic ligands.Metal carbonyls: 18 electron rule, electron count of
mononuclear, polynuclear and substituted metal carbonyls of 3d series. General methods of
preparation (direct combination, reductive carbonylation, thermal and photochemical
decomposition) of mono and binuclear carbonyls of 3d series.Structures of mononuclear and
binuclear carbonyls of Cr, Mn, Fe, Co and Ni using VBT.π-acceptorbehaviour of CO (MO
diagram of CO to be discussed), synergic effect and use of IR data to explain extent of back
bonding.Zeise’s salt: Preparation and structure, evidences of synergic effect and comparison
of synergic effect with that in carbonyls.
Reference Books
1. Huheey, J. E.; Keiter, E.A. &Keiter, R.L. Inorganic Chemistry, Principles of Structure and
Reactivity, 4th Ed., Harper Collins 1993, Pearson, 2006.
2. Sharpe, A.G., Inorganic Chemistry, 4th Indian Reprint (Pearson Education) 2005.
3. Lee, J.D. Concise Inorganic Chemistry 5th Ed., John Wiley and sons 2008.
4. Powell, P. Principles of Organometallic Chemistry, Chapman and Hall, 1988.
5. Shriver, D.D. & P. Atkins, Inorganic Chemistry 2nd Ed., Oxford University Press,1994.
6. Purcell, K.F. &Kotz, J.C., Inorganic Chemistry, W.B. Saunders Co. 1977.
7. Miessler, G. L. &Tarr, D.A. Inorganic Chemistry 4th Ed., Pearson, 2010.
8. S.J. Lippard and J.M. Berg, Principles of Bioinorganic Chemistry, University Science Books.
40
Practical Code: BCH-601L UE = 25 marks
IA = 25 marks
B. Mixtures should preferably contain one interfering anion, or insoluble component (BaSO4,
SrSO4, PbSO4, CaF2 or Al2O3) or combination of anions e.g. CO32- and SO32-, NO2 - and
NO3-, Cl- and Br-, Cl- and I-, Br- and I-, NO3 - and Br-, NO3 - and I-. Spot tests should be
done whenever possible.
Reference Books
41
Semester-VI
Paper No: XIX-H
Paper Code: BCH-602 UE = 75 marks
IA = 25 marks
Organic Chemistry-V
Unit-II IR Spectroscopy
Fundamental and non-fundamental molecular vibrations; IR absorptionpositions of O, N and
S containing functional groups; Effect of H-bonding, conjugation,resonance and ring size on
IR absorptions; Fingerprint region and its significance; applicationin functional group
analysis.
Unit-IV Dyes
Classification, Colour and constitution; Mordant and Vat Dyes; Chemistry of
dyeing;Synthesis and applications of: Azo dyes – Methyl Orange and Congo Red (mechanism
of Diazo Coupling); Triphenyl Methane Dyes -Malachite Green, Rosaniline and Crystal
Violet; Phthalein Dyes – Phenolphthalein and Fluorescein; Natural dyes –structure elucidation
and synthesis of Alizarin and Indigotin; Edible Dyes with examples.
Reference Books
1. Kemp, W. Organic Spectroscopy, Palgrave.
2. Pavia, D. L. et al. Introduction to Spectroscopy 5th Ed. Cengage Learning IndiaEd. (2015).
3. Kalsi, P. S., Spectroscopy of Organic Compounds., New Age International (P)
Ltd. Pub.
4. Clayden, J.; Greeves, N.; Warren, S.; Wothers, P.; Organic Chemistry, Oxford University Press.
5. Finar, I. L. Organic Chemistry (Volume 1), Dorling Kindersley (India) Pvt. Ltd.(Pearson Education).
42
Practical Code: BCH-602L
UE = 25 marks
IA = 25 marks
Reference Books:
2. Mann, F.G. & Saunders, B.C. Practical Organic Chemistry, Pearson Education (2009)
3. Furniss, B.S.; Hannaford, A.J.; Smith, P.W.G.; Tatchell, A.R. Practical Organic Chemistry,
5th Ed., Pearson (2012)
43
Semester-VI
Paper No: XX-H
Paper Code: BCH-603 UE = 75 marks
IA = 25 marks
B.Sc. (Hons.) Chemistry: Semester – VI
Physical Chemistry – VI
(Spectroscopy)
Paper No. – XX-H
Unit I: Introduction
Interaction of electromagnetic radiation with molecules and various types of spectra; Born
Oppenheimer Approximation.
Unit II: Rotational, Vibrational and Raman spectroscopy
Rotational spectroscopy: Selection rules, Intensities of spectral lines, determination of bond
lengths of diatomic and linear triatomic molecules, isotopic substitution.
Vibrational spectroscopy: Classical equation of vibration, computation of force constant,
amplitude of diatomic molecular vibration, Anharmonicity, Morse potential, dissociation
energies, fundamental frequencies, overtones, hot bands, degree of freedom for polyatomic
molecules, Normal modes of vibration,concept of group frequencies.
Raman spectroscopy: Qualitative treatment of rotational Raman effect; effect of nuclear spin,
vibrational Raman spectra, Stokes and Anti –stokes lines; their intensity difference, rule of
mutual exclusion.
Unit IV: Nuclear Magnetic Resonance (NMR) Spectroscopy and Electron Spin
Resonance (ESR) Spectroscopy
Principles of NMR spectroscopy, larmor precession, chemical shift and low resolution
spectra, different scales (δ and T), spin–spin coupling and high resolution spectra,
interpretation of PMR spectra of organic molecules.
Electron Spin Resonance (ESR) spectroscopy: Its principle, hyperfine structure, ESR of
simple radicals
Books Recommended:
1. Physical chemistry by KL Kapoor, Macmillan India Ltd.
2. Fundamentals of Molecular Spectroscopy by CNBanwell and EM McCash,Tata Mc Graw
Hill.
44
Practical Code: BCH-603L UE = 25 marks
IA = 25 marks
B.Sc. (Hons.) Chemistry: Semester –VI
Physical Chemistry Practical Lab –VI
UV/Visible spectroscopy
I. Study the 200-500 nm absorbance spectra of KMnO4 and K2Cr2O7 (in 0.1 M H2SO4) and
determine the λmax values. Calculate the energies of the two transitions in different units (J
molecule-1, kJ mol-1,
-1
cm , eV).
II. Study the pH-dependence of the UV-Vis spectrum (200-500 nm) of K2Cr2O7.
III. Record the 200-350 nm UV spectra of the given compounds (acetone, acetaldehyde, 2-
propanol, acetic acid) in water. Comment on the effect of structure on the UV spectra of
organic compounds.
Colourimetry
1. Khosla, B. D.; Garg, V. C. & Gulati, A., Senior Practical Physical Chemistry, R. Chand &
Co.: New Delhi (2011).
2. Garland, C. W.; Nibler, J. W. & Shoemaker, D. P. Experiments in Physical Chemistry 8th
Ed.;
McGraw-Hill: New York (2003).
3. Halpern, A. M. & McBane, G. C. Experimental Physical Chemistry 3rd Ed.; W.H. Freeman
& Co.:
New York (2003).
45