Coating Failures and Defects
Coating Failures and Defects
Coating Failures and Defects
Fig. 4 Staining of a paint film by diffusion of a soluble colored substance from the
underlying paint to give undesirable discoloration or staining. Often seen where
bituminous- or tar-based products are overcoated with topcoats in which the tar or
bitumen is soluble. Also occurs with emulsion paints.
Coating Failures and Defects
Blistering
Probable Causes: Many mechanisms can be involved,
including osmotic gradients associated with soluble
salts, soluble pigments, corrosion products, retained
solvents, and solvents from cargoes. Nonosmotic
blistering is associated with cathodic disbonding,
thermal gradients related to cold-wall effects, and
compressive stress.
Fig. 6 A hazy deposit on the surface of the paint film resembling the bloom on a grape,
resulting in a loss of gloss and a dulling of color.
Coating Failures and Defects
Bridging
Probable Causes: Poor application. High-viscosity
paint system. Failure to brush paint into corners and
over welds.
Fig. 7 The covering over of unfilled gaps such as cracks or corners with a film of coating
material. This introduces a weakness in the paint film, which may crack or flake off.
Coating Failures and Defects
Bubbles or Bubbling
Probable Causes: Trapped air/solvent within the
coating that is not released before the surface dries.
Air entrainment during mixing. High ambient
temperature during application. Also seen when
overcoating antifouling without removal of the
leached layer and zinc silicates. Can be found with
factory-applied coatings where application is by
dipping, electrodeposition, or roller coating.
Fig. 10 A friable, powdery layer on the surface of a paint film. A change of color or fading is
also seen. Chalking rates vary with pigment concentration and choice of binder. Chalking is
a known characteristic of certain paints, for example, epoxy paints.
Coating Failures and Defects
Checking
Probable Causes: Typically a formulation and/or a
specification problem. As with cracking, stresses are
developed that cause the surface of the paint film to
become brittle and crack. Limited paint flexibility.
Fig. 11 Fine cracks that do not penetrate the topcoat of a paint system. Some checking can
be so minute that it is impossible to see without magnification.
Coating Failures and Defects
Cissing
Probable Causes: Surface contamination by either
moisture or foreign matter such as oil, grease, or
silicone. Also known to happen when incorrect
solvent blends have been used.
Fig. 12 Surface breaks in a wet paint film, where the paint has receded to expose the
underlying substrate. The paint is unable to wet–out the substrate. Can be very large.
Coating Failures and Defects
Cobwebbing
Probable Causes: Too high a viscosity with some types
of polymer solutions. Will occur with chlorinated
rubber at almost any viscosity.
Fig. 13 The production of fine filaments instead of normal atomized particles when some
solutions of high-molecular-weight polymers are sprayed. Traditionally when applying
chlorinated rubber coatings by conventional spray.
Coating Failures and Defects
Cracking
Probable Causes: Cracking is generally a stress-related
failure and can be attributed to surface movement,
aging, absorption and desorption of moisture, and
general lack of flexibility of the coating. The thicker
the paint film, the greater the possibility it will
crack.
Fig. 15 The formation of small bowl-shaped depressions in the paint film. Not to be
confused with cissing.
Coating Failures and Defects
Crazing
Probable Causes: Application temperature too low,
incompatibility with previous coating, aging, or high
film thickness.
Fig. 16 Similar to checking but the cracks are generally wider and penetrate deeper into
the film.
Coating Failures and Defects
Crowsfooting
Probable Causes: Usually due to the surface drying
rapidly to form a skin, which then wrinkles as solvent
slowly evaporates from the soft underlying paint.
Fig. 17 The development of small wrinkles in the paint film in a pattern resembling a crow’s
foot.
Coating Failures and Defects
Delamination
Probable Causes: Provided that compatible paint
materials have been used, delamination defects are
generally related to poor surface preparation and
application defects, such as contamination between
coats, exceeding overcoat times, or application to a
glossy surface.
Fig. 21 The underlying surface is visible through the paint film due to inadequate hiding
power of the coating material. This is sometimes called grinning-through. Often seen
where dark colors are overcoated with lighter colors.
Coating Failures and Defects
Heat Damage
Probable Causes: Effect of high temperature often
applied to the reverse side of a steel plate from
burning, welding, or fire.
Fig. 25 The dried paint film has the appearance of a dried-out mud flat. The cracks appear
as a network that can vary in size and amount.
Coating Failures and Defects
Orange Peeling
Probable Causes: Failure of the paint film to flow out.
Usually caused by poor application techniques,
incorrect solvent blend, or too-high thixotropy.
Fig. 27 Similar to flaking, although peeling tends to be associated with soft and pliable
fresh coatings that can be pulled away from or spontaneously flake away from the
substrate or from between coats, due to loss of adhesion.
Coating Failures and Defects
Pinholes
Probable Causes: Solvent or air entrapment within a
paint film. A common problem when coating porous
substrate such as zinc-filled primers, zinc silicates,
and metal-sprayed coatings. Pinholes can also be
caused by incorrect spray application or incorrect
solvent blend.
Fig. 31 Fine spots of rust that appear on a paint film, often a thin primer coat. The initial
spots rapidly spread over the surface, resulting in a film of rust through which the
individual spots are difficult to discern. Also from holidays.
Coating Failures and Defects
Rust Spotting
Probable Causes: Low film thickness (more likely
creating rust rashing), voids and holidays (more likely
creating rust rashing), but also defects in the steel,
such as laminations and inclusions. Too high a
surface profile may cause penetration of peaks
through a paint film and cause rust spotting. May
also occur from metallic contamination of a coated
surface by grinding dust and so on.
Fig. 34 Sags are caused by the downward movement of a coat of paint that appear soon
after application and before setting, resulting in an uneven area with a thick lower edge.
They are usually apparent on local areas of a vertical surface and, in severe situations, may
be described as curtains.
Coating Failures and Defects
Settlement
Probable Causes: Old stock, heavily pigmented paint,
and incorrect formulation of product. Can be a
problem with zinc-rich primers.
Fig. 35 The sedimentation of the solid constituents comprising pigments and extenders
from the binder and solvent while standing in a container. Settlement that occurs after
mixing and during application can result in different shades and performance in different
areas.
Coating Failures and Defects
Skinning
Probable Causes: Absence of antiskinning agent, use
of nonairtight container, hot storage conditions.
Often occurs in partly-used cans.
Fig. 37 Eruption of the surface of the paint film. Wrinkling and blistering, which lead to a
weak surface and ultimate coating breakdown.
Coating Failures and Defects
Solvent Popping
Probable Causes: Incorrect solvent blends, porous
surfaces, incorrect environmental conditions, or high
surface temperature.
Fig. 38 Solvent (clear) bubbles on the surface of the paint film soon after application.
Coating Failures and Defects
Staining
Probable Causes: Contact with a solid or liquid that
imparts a discoloration or stain to the coating.