Chemistry Worksheets Class 12 On Chapter 2 Solutions Set 5

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Chemistry Worksheets Class 12 on Chapter 2 Solutions-

Set 5
Q-1: Which of the following is/are correct for an ideal binary solution of two volatile liquids(e.g. benzene
and toluene)?

a) Its vapour is always richer in the more volatile component (compared to the liquid).
b) The liquid will gradually become richer in the less volatile component if such a mixture is
boiled(distilled).
c) The PT (i.e, the total pressure) above the solution will be the sum of the vapour pressures of the
two pure components.
d) The boiling point of the solution will be less than the boiling points of the two components.

Q-2: 0.7g of solute (molar mass=96 g/mol) is dissolved in 42 g of water.The percentage association of
solute in water assuming dimerization is (ΔTf=0.2K and Kf= 1.86 KKg/mol)

Q-3: The graph below depicts the vapour pressure-temperature curves for several liquids-diethyl ether,
acetone, water and ethyl alcohol. P,Q,R, and S are liquids, respectively

Q-4: Two liquids A and B follow Raoult’s law over the entire range of concentration. If a solution of A
and B has a mole fraction of A as 0.3. Then y A=x/17. The value of x is:
(PoA= 50 Torr, PoB= 100 Torr)

Q-5: A 0.5g organic sample containing Br yields 0.4g of AgBr in a specific reaction. What is the
approximate percentage weight of Br in the sample? (Atomic weight of Ag= 108 g/mol; Br= 80g/mol)
Q-6: When 20 g of naphthoic acid (C11H8O2) is dissolved in 50 g benzene(Kf=1.72 K Kg/mol), a freezing
point depression of 2K is observed. The van’t Hoff factor(i) is
a) 0.5
b) 1
c) 2
d) 3

Q-7: Toluene and benzene form an ideal solution at room temperature. The true statement(s) for this
process is (are)
a) ΔG is positive
b) ΔSsystem is positive
c) ΔSsurrounding = 0
d) ΔH = 0

Q-8: Which of the following curves best represents Henry's law?

Q-9: Which of the following solutions will have the maximum lowering of vapour pressure?

a) 0.1 M fructose
b) 0.1 M toluene
c) 0.1 M MgCl2
d) 0.1 M KCl
Q-10: When liquids A and B are mixed, they form a warm solution. What kind of deviation does this
solution exhibit?
Q-11: Why can't water be completely separated from an ethyl alcohol aqueous solution?
Q-12: What happens when the applied external pressure exceeds the osmotic pressure of the solution?
Q-13: 2.5 g of protein taken and made 500 mL of solution. The osmotic pressure of the solution is
0.410 atm at 300 K. Find the number of glycine units.

Q-14: Which of the following statement(s) is true?

a) Mass percentage(W/W) is a unit commonly used in industrial chemical applications.


b) Mass of the solute dissolved in 100 g of the solution gives mass by mass percentage.
c) Mass of solute dissolved give mass by volume percentage
d) Both (a) and (b)

Q-15: When a solid solute is added to a solvent, some of it dissolves and its concentration in solution
increases. This is referred to as
a) Unsaturation
b) Saturation
c) Crystallisation
d) Dissolution

Q-16: The osmotic pressure of blood is 7.47 bar at 300 K. To inject glucose to a patient intravenously, it
has to be isotonic with blood. The concentration of glucose in g/L is ______.(Molar mass of glucose =
180g/mol, R=0.083Lbar/K mol) (Nearest integer)
Q-17: Which of the following has a higher boiling point: 1 M glucose or 2 M glucose, and why?
Q-18: Which of the following statements is false?

a) Units of osmotic pressure and atmospheric pressure are the same.


b) Solvent molecules move through a semipermeable membrane from a region of lower solute
concentration to a region of higher concentration in reverse osmosis.
c) The nature of the solvent influences the value of the Ebullioscopic Constant.
d) Mole fraction is a dimensionless quantity

Q-19: Copper ferrocyanide is used as a semipermeable membrane in Berkely Hartley method? How
many electrons are present in the t2g orbital of the central metal?
Q-20: Solubility of sodium sulphate in water

a) rises as the temperature rises


b) decreases as temperature rises
c) Unpredictable
d) temperature insensitive

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